Open Access
Table A.3
Peak positions and FWHMs of the CH bend band of pure formamide and formamide in various binary and tertiary mixtures at temperatures from 15–212 K.
| Matrix | T (K) | Peak | FWHM | ||
|---|---|---|---|---|---|
| (cm−1) | (µm) | (cm−1) | (µm) | ||
| 15 | 1388.1 | 7.204 | 27.5 | 0.142 | |
| 49 | 1387.7 | 7.206 | 26.3 | 0.136 | |
| 99 | 1388.1 | 7.204 | 24.6 | 0.127 | |
| Pure | 149 | 1388.9 | 7.200 | 23.4 | 0.121 |
| 170 | 1391.0 | 7.189 | 15.2 | 0.079 | |
| 191 | 1391.3 | 7.188 | 14.2 | 0.074 | |
| 212 | 1391.3 | 7.188 | 13.7 | 0.071 | |
| 15 | 1388.4 | 7.203 | 23.6 | 0.122 | |
| 49 | 1388.1 | 7.204 | 22.9 | 0.119 | |
| H2OM | 99 | 1388.4 | 7.203 | 21.5 | 0.111 |
| 129 | 1388.9 | 7.200 | 20.5 | 0.106 | |
| 149 | 1388.6 | 7.201 | 22.7 | 0.117 | |
| 161 | 1388.9 | 7.200 | 24.1 | 0.125 | |
| 15 | 1398.0 | 7.153 | 12.1 | 0.062 | |
| 1383.7 | 7.227 | – | – | ||
| 34 | 1397.8 | 7.154 | 12.8 | 0.065 | |
| 1383.7 | 7.227 | – | – | ||
| 40 | 1396.1 | 7.163 | 17.4 | 0.089 | |
| 1383.9 | 7.226 | – | – | ||
| CO2 | 49 | 1395.8 | 7.164 | 19.5 | 0.100 |
| 1383.9 | 7.226 | – | – | ||
| 60 | 1393.9 | 7.174 | 23.6 | 0.122 | |
| 1383.9 | 7.226 | – | – | ||
| 90 | 1393.7 | 7.175 | 22.4 | 0.116 | |
| 1384.4 | 7.223 | – | – | ||
| 15 | 1393.9 | 7.174 | 14.2 | 0.073 | |
| CO | 31 | 1393.9 | 7.174 | 17.4 | 0.090 |
| 34 | 1393.9 | 7.174 | 17.6 | 0.091 | |
| 15 | 1390.8 | 7.190 | 15.2 | 0.078 | |
| 51 | 1390.5 | 7.191 | 14.5 | 0.075 | |
| NH3P | 60 | 1390.5 | 7.191 | 14.2 | 0.073 |
| 90 | 1390.3 | 7.193 | 13.5 | 0.070 | |
| 99 | 1389.8 | 7.195 | 14.2 | 0.074 | |
| 108 | 1389.6 | 7.196 | 14.9 | 0.077 | |
| 15 | 1389.9 | 7.195 | 21.9 | 0.114 | |
| 51 | 1389.6 | 7.196 | 21.2 | 0.110 | |
| 101 | 1389.1 | 7.199 | 20.2 | 0.105 | |
| H2O:CO2M | 131 | 1389.6 | 7.196 | 19.3 | 0.100 |
| 149 | 1389.3 | 7.198 | 20.7 | 0.107 | |
| 161 | 1389.6 | 7.196 | 21.2 | 0.110 | |
| 15 | 1387.7 | 7.206 | 19.8 | 0.103 | |
| 51 | 1387.2 | 7.209 | 18.6 | 0.096 | |
| 99 | 1387.7 | 7.206 | 17.1 | 0.089 | |
| H2O:NH3P | 134 | 1388.1 | 7.204 | 16.4 | 0.085 |
| 149 | 1388.9 | 7.200 | 17.6 | 0.091 | |
| 161 | 1389.1 | 7.199 | 18.6 | 0.096 | |
| 15 | 1388.6 | 7.201 | 11.8 | 0.061 | |
| CO:NH3M | 30 | 1387.9 | 7.205 | 11.1 | 0.058 |
| 37 | 1387.9 | 7.205 | 11.6 | 0.060 | |
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