Open Access
Table A.1
Peak positions and FWHMs of the C = O stretch and NH2 scissor bands of pure formamide and formamide in various binary mixtures at temperatures from 15–212 K.
| Matrix | T (K) | Peak | FWHM | ||
|---|---|---|---|---|---|
| (cm−1) | (µm) | (cm−1) | (µm) | ||
| 15 | 1700.3 | 5.881 | 58.8 | 0.203 | |
| 1630.4 | 6.133 | – | – | ||
| 49 | 1700.3 | 5.881 | 58.1 | 0.201 | |
| 1632.6 | 6.125 | – | – | ||
| 99 | 1700.3 | 5.881 | 56.6 | 0.196 | |
| 1631.1 | 6.131 | – | – | ||
| 149 | 1699.8 | 5.883 | 55.4 | 0.192 | |
| 1629.4 | 6.137 | – | – | ||
| Pure | 170 | 1704.2 | 5.868 | 44.1 | 0.149 |
| 1749.2 | 5.717 | – | – | ||
| 1647.0 | 6.072 | – | – | ||
| 191 | 1703.4 | 5.870 | 44.8 | 0.152 | |
| 1750.0 | 5.714 | – | – | ||
| 1644.6 | 6.080 | – | – | ||
| 212 | 1704.2 | 5.868 | 45.3 | 0.154 | |
| 1750.4 | 5.713 | – | – | ||
| 1642.2 | 6.089 | – | – | ||
| 15 | 1701.0 | 5.879 | 36.9 | 0.128 | |
| 49 | 1701.0 | 5.879 | 37.4 | 0.129 | |
| H2OM | 99 | 1701.0 | 5.879 | 37.6 | 0.130 |
| 129 | 1701.3 | 5.878 | 38.1 | 0.132 | |
| 149 | 1702.2 | 5.875 | 47.5 | 0.164 | |
| 161 | 1703.0 | 5.872 | 54.0 | 0.187 | |
| 15 | 1703.7 | 5.870 | 17.6 | 0.061 | |
| 1591.6 | 6.283 | – | – | ||
| 34 | 1704.2 | 5.868 | 18.8 | 0.065 | |
| 1591.6 | 6.283 | – | – | ||
| 40 | 1709.5 | 5.850 | 27.2 | 0.093 | |
| 1591.6 | 6.283 | – | – | ||
| CO2 | 49 | 1711.2 | 5.844 | 27.0 | 0.093 |
| 1615.2 | 6.191 | – | – | ||
| 60 | 1710.9 | 5.845 | 29.9 | 0.103 | |
| 1614.0 | 6.196 | – | – | ||
| 90 | 1709.5 | 5.850 | 38.8 | 0.134 | |
| 1613.8 | 6.197 | – | – | ||
| 15 | 1717.2 | 5.824 | 34.7 | 0.119 | |
| 1588.9 | 6.294 | – | – | ||
| 31 | 1717.2 | 5.824 | 36.4 | 0.125 | |
| CO | 1588.7 | 6.294 | – | – | |
| 34 | 1716.9 | 5.824 | 36.6 | 0.126 | |
| 1588.7 | 6.294 | – | – | ||
| 15 | 1696.7 | 5.894 | 25.8 | 0.090 | |
| 1623.5 | 6.159 | – | – | ||
| 50 | 1696.9 | 5.893 | 25.8 | 0.090 | |
| 1623.3 | 6.160 | – | – | ||
| 100 | 1697.4 | 5.891 | 29.9 | 0.104 | |
| CH3OHM | 1621.4 | 6.168 | – | – | |
| 121 | 1700.1 | 5.882 | 32.1 | 0.111 | |
| 1621.4 | 6.168 | – | – | ||
| 139 | 1700.8 | 5.880 | 40.0 | 0.139 | |
| 1621.4 | 6.168 | – | – | ||
| 154 | 1720.1 | 5.814 | 46.5 | 0.156 | |
| 1646.9 | 6.072 | – | – | ||
| 15 | 1698.4 | 5.888 | – | – | |
| 51 | 1698.1 | 5.889 | – | – | |
| 60 | 1697.9 | 5.890 | – | – | |
| NH3N | 90 | 1696.9 | 5.893 | – | – |
| 99 | 1697.7 | 5.890 | – | – | |
| 108 | 1698.9 | 5.886 | – | – | |
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