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Fig. 4.

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Grotrian diagram showing the lowest energy levels in Y+. The transitions between energy levels are indicated, with the line transparency set by the transition strength, log gf. The 4d5p–4d2 (28 000 cm−1–14 000 cm−1) transitions are shown with thick lines in blue. Radiative transfer modelling analysis in Vieira et al. (2023) tentatively links the 4d5p–4d2 (28 000 cm−1–8000 cm−1) transitions to absorption at λ < 450 nm in the epoch 1 spectrum; other notable transitions are around 300 nm, too short to be observed by X-shooter (4d5p–4d5s, 28 000 cm−1–1000 cm−1), and signatures of the 5s5p–4d2 transitions (24 000 cm−1–14 000 cm−1) at 1 μm, which are much weaker than the Sr+ line transitions at similar wavelengths. The 4d5p–4d2 transitions have lower oscillator strength than several of the Y+ lines at shorter wavelengths, but due to the rapid decline of opacity with wavelength for typical r-process elements, these transitions have higher opacity compared to the continuum at 760 nm. When no lines are drawn between levels, the transition is negligible with log gf < −2.

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