Open Access
Table B.1.
Improved rotational and distortion constants for HCCCHCCC.
| Constant | Theoretical1 | Laboratory2 | Lab + TMC-13 |
|---|---|---|---|
| (MHz) | |||
| A | 21399.8 | 21094.10161(25) | 21094.10153(52) |
| B | 1664.0 | 1676.268423(70) | 1676.26835(81) |
| C | 1543.9 | 1550.066623(42) | 1550.066695(60) |
| ΔJ ×103 | 0.579 | 0.6414(77) | 0.64165(44) |
| ΔJK | -0.0662 | -0.075808(14) | -0.075820(25) |
| δJ ×103 | 0.144 | 0.16067(50) | 0.15976(52) |
| Jmax | 7 | 15 | |
| Ka, max | 1 | 2 | |
| Nlines | 24 | 49 | |
| σ (kHz) | 0.5 | 1.5 | |
| νmax (MHz) | 40330 | 48340 | |
(1)
Notes.Ab initio calculation from Sattelmeyer & Stanton (2000).
(2)
Rotational and distortion constants derived from a fit to the laboratory data of McCarthy & Thaddeus (2002).
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