Free Access
Table 1
CVT/SCT rate constants (in s−1) for the cis to trans and trans to cis isomerization reactions of thioformic [HC(O)SH] and formic acids [HC(O)OH] and trans/cis ratios.
| T(K) | Thioformic acid [HC(O)SH] | Formic acid [HC(O)OH] | ||||
|---|---|---|---|---|---|---|
| KCVT/SCT [cis to trans] | KCVT/SCT [trans to cis] | K1/K−1 | KCVT/SCT [cis to trans] | KCVT/SCT [trans to cis] | K1/K−1 | |
| 10 | 6.04E−26 | 5.14 E−40 | 1.17E+14 | 3.73E−21 | 1.79E−109 | 2.09E+88 |
| 20 | 3.03E−16 | 2.78E−23 | 1.09E+07 | 1.67E−09 | 1.14E−53 | 1.47E+44 |
| 30 | 7.34E−13 | 1.49E−17 | 4.93E+04 | 1.64E−05 | 5.82E−35 | 2.82E+29 |
| 40 | 4.74E−11 | 1.43E−14 | 3.32E+03 | 1.89E−03 | 1.53E−25 | 1.23E+22 |
| 50 | 7.65E−10 | 1.17E−12 | 6.57E+02 | 3.65E−02 | 7.70E−20 | 4.74E+17 |
| 60 | 7.04E−09 | 3.16E−11 | 2.23E+02 | 2.89E−01 | 5.36E−16 | 5.40E+14 |
| 70 | 6.04E−08 | 5.85E−10 | 1.03E+02 | 1.39E+00 | 3.26E−13 | 4.26E+12 |
| 80 | 7.31E−07 | 1.26E−08 | 5.78E+01 | 4.93E+00 | 4.37E−11 | 1.13E+11 |
| 90 | 1.44E−05 | 3.90E−07 | 3.69E+01 | 1.46E+01 | 2.18E−09 | 6.70E+09 |
| 100 | 3.23E−04 | 1.26E−05 | 2.57E+01 | 3.88E+01 | 5.54E−08 | 7.00E+08 |
| 110 | 5.90E−03 | 3.09E−04 | 1.91E+01 | 9.82E+01 | 8.91E−07 | 1.10E+08 |
| 120 | 7.81E−02 | 5.23E−03 | 1.49E+01 | 2.47E+02 | 1.05E−05 | 2.36E+07 |
| 130 | 7.55E−01 | 6.24E−02 | 1.21E+01 | 6.36E+02 | 9.93E−05 | 6.41E+06 |
| 140 | 5.53E+00 | 5.47E−01 | 1.01E+01 | 1.68E+03 | 8.00E−04 | 2.09E+06 |
| 150 | 3.20E+01 | 3.71E+00 | 8.64E+00 | 4.45E+03 | 5.60E−03 | 7.94E+05 |
| 160 | 1.52E+02 | 2.02E+01 | 7.53E+00 | 1.16E+04 | 3.42E−02 | 3.40E+05 |
| 170 | 6.08E+02 | 9.12E+01 | 6.67E+00 | 2.93E+04 | 1.82E−01 | 1.61E+05 |
| 180 | 2.11E+03 | 3.52E+02 | 5.99E+00 | 7.02E+04 | 8.50E−01 | 8.26E+04 |
| 190 | 6.47E+03 | 1.19E+03 | 5.43E+00 | 1.60E+05 | 3.51E+00 | 4.55E+04 |
| 200 | 1.79E+04 | 3.59E+03 | 4.97E+00 | 3.43E+05 | 1.29E+01 | 2.66E+04 |
| 220 | 1.05E+05 | 2.45E+04 | 4.27E+00 | 1.36E+06 | 1.29E+02 | 1.05E+04 |
| 240 | 4.63E+05 | 1.23E+05 | 3.77E+00 | 4.47E+06 | 9.23E+02 | 4.84E+03 |
| 260 | 1.64E+06 | 4.86E+05 | 3.38E+00 | 1.26E+07 | 5.02E+03 | 2.51E+03 |
| 280 | 4.90E+06 | 1.59E+06 | 3.08E+00 | 3.12E+07 | 2.18E+04 | 1.43E+03 |
| 300 | 1.27E+07 | 4.47E+06 | 2.84E+00 | 6.94E+07 | 7.92E+04 | 8.76E+02 |
| 320 | 2.94E+07 | 1.11E+07 | 2.65E+00 | 1.41E+08 | 2.47E+05 | 5.70E+02 |
| 340 | 6.18E+07 | 2.48E+07 | 2.49E+00 | 2.66E+08 | 6.81E+05 | 3.91E+02 |
| 360 | 1.20E+08 | 5.09E+07 | 2.35E+00 | 4.70E+08 | 1.69E+06 | 2.79E+02 |
| 380 | 2.18E+08 | 9.71E+07 | 2.24E+00 | 7.87E+08 | 3.82E+06 | 2.06E+02 |
| 400 | 3.72E+08 | 1.74E+08 | 2.14E+00 | 1.26E+09 | 8.00E+06 | 1.57E+02 |
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.