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Fig. 1

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(a) Absorption spectrum of C60 isolated in a Ne matrix, not corrected for scattering. Band labels according to Leach et al. (1992). (b) Gaussian profiles (thick gray solid curve) fitted to bands of the 11 T1u1Ag transition, including A0 and A1, and to the baseline. (c) Gaussian profiles (thick gray solid curve) fitted, with a common FWHM, to absorptions near the γ0 band. Fittedband positions are 16 431.1 ± 1.2 cm−1, 24 829.04 ± 0.98 cm−1, and 25 087.73 ± 0.65 cm−1 for γ0, A0, and A1, respectively.The wavelength scale of the spectrometer was calibrated with an accuracy of 0.3 nm.

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