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Table A.3.

Rotational and distortion constants for 1-ECP and 2-ECP.

1-ECPa 1-ECPb 2-ECPc 2-ECPb
Constant (MHz) (MHz) (MHz) (MHz)
A 8374.116845(672) 8374.116982(777) 8262.3702(10) 8262.3708(15)
B 1879.207441(354) 1879.206888(286) 1876.250982(284) 1876.252295(342)
C 1549.116825(323) 1549.117494(236) 1543.195532(187) 1543.194285(305)
ΔJ 10−5 6.862(218) 6.643(162) 4.879(292) 5.646(179)
ΔJK 10−3 2.4044(163) 2.4271(154) 2.5504(205) 2.5219(288)
δJ 10−5 1.815(113) 1.6858(645) 1.082(216) 1.0217(707)
δK 10−4 15.59(145) 13.04(106) 6.98(113)

Nlines 30 44 39 63
νmax (GHz) 24.974 48.420 25.805 46.992
(J, Ka)max 7,3 14,3 8,3 14,3
σ (kHz) 1.3 8.3 3.0 16.0

Notes. Values between parentheses correspond to the uncertainties of the parameters in units of the last significant digits.

(a)

Rotational and distortion constants from a fit to the lines of 1-ECP measured in the laboratory by McCarthy et al. (2020), including the distortion constant δK.

(b)

Merged fit to the laboratory and space frequencies.

(c)

Rotational and distortion constants from a fit to lines of 2-ECP measured in the laboratory by McCarthy et al. (2020) with the uncertainties of 2 kHz changed to 4 kHz.

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