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Table B.3.

Molecular constants for 1-CCP and 2-CCP.

1-CCPa 1-CCPb 2-CCPa 2-CCPb
Constant (MHz) (MHz) (MHz) (MHz)
A 8352.981(10) 8352.9758(142) 8235.592(14) 8235.599(37)
B 1904.2522(2) 1904.251830(231) 1902.0748(3) 1902.07558(49)
C 1565.3652(2) 1565.365658(197) 1559.6472(2) 1559.64673(38)
ΔJ 10−3 0.0743(11) 0.07280(110) 0.0686(11) 0.07246(240)
ΔJK 10−3 2.354(8) 2.3493(134) 2.287(21) 2.248(37)
ΔK 10−3 0.17561c 0.32391c
δJ 10−5 1.33(5) 1.320(52) 1.34(6) 1.465(82)
δK 10−3 1.48(9) 1.322(81) 1.10(9) 1.299(191)
χaa -4.1810(11) -4.1795 (23) -4.2429(6) -4.2316 (55)
χbb 2.3016(14) 2.3052 (38) 2.2475(16) 2.2347 (74)

Nlines 68 175 38 98
νmax (GHz) 29.9 47.6 18.1 47.0
(J, Ka)max 9,3 14,3 5,2 13,2
σ (kHz) 2.2 9.1 1.9 10.3

Notes. Values between parentheses correspond to the uncertainties of the parameters in units of the last significant digits.

(a)

Rotational and distortion constants from Lee et al. (2021).

(b)

Merged fit to the laboratory data of McCarthy et al. (2020) and space frequencies measured in this work. The laboratory data used by Lee et al. (2021) are not available.

(c)

Fixed value.

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