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Table 4.

Deuteration enhancement in TMC-1 for detected molecules compared to our gas-phase chemical model.

Observations Model A Model B
Molecule TMC-1 no full
scrambling scrambling
CH3C3N/CH2DC3N 22 (a) 75.8 31.4
CH3CN/CH2DCN 11 (b) 15.0 15.0
H2CCN/HDCCN 20 (b) 23.6 23.6
HC3N/DC3N 62 (c) 54.9 54.5
HNCCC/DNCCC 43 (c) 34.6 34.5
HCCNC/DCCNC 30 (c) 27.2 27.1
HC5N/DC5N (b) 82 (c) 23.3 23.3
c-C3H2/c-C3HD 27 (b) 45.5 45.4
C4H/C4D 118 (b) 55.5 55.3
H2C4/HDC4 83 (b) 49.5 49.4
CH3CCH/CH3CCD 49 (b) 257 264
CH3CCH/CH2DCCH 10 (b) 76 76
CH3C4H/CH2DC4H ≥35 (d) 59 20
CH3C4H/CH3C4D ≥144 (d) 136 55

Notes.

(a)

This work.

(d)

3σ upper limit.

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