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Fig. 2

image

Section of the rotational spectrum of CPCA showing a-type R-branch rotational transitions for the ground state, and ν27 and ν16 vibrationally excited states of the trans conformer, and b-type Q-branch transitions for the ground state of the cis species. The negative spectral features are produced by the folding of the frequency-switched data and appear at ±50 MHz of each rotational transition.

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