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Table 1.
Spectroscopic parameters of the strongest PH3 transitions between 949 and 959 cm−1, extracted from the GEISA-2015 database.
| Molecule. | Wavenumber | Band identification | Line identification | Intensity | Energy | Broad. coef. |
|---|---|---|---|---|---|---|
| cm−1 | cm molec−1 | cm−1 | cm−1 atm−1 | |||
| PH3 | 954.44508 | 0100 0000 | 3 0 0A+ 4 0 0A+ | 1.343 × 10−20 | 88.9959 | 0.1014 |
| PH3 | 954.64090 | 0100 0000 | 3 1 0E 4 1 0E | 1.262 × 10−20 | 88.4658 | 0.1026 |
| PH3 | 955.23186 | 0100 0000 | 3 2 0E 4 2 0E | 1.02 × 10−20 | 86.8739 | 0.1076 |
| PH3 | 956.2288 | 0100 0000 | 3 3 0A− 4 3 0A− | 6.09 × 10−21 | 84.2149 | 0.1078 |
| PH3 | 956.2288 | 0100 0000 | 3 3 0A− 4 3 0A+ | 6.09 × 10−21 | 84.2149 | 0.1078 |
| CO2 | 955.306951 | 000 11 100 01 | P11E | 6.663 × 10−27 | 1426.0242 | 0.1076 |
Notes. The CO2 transition used in the calculations is also added. The line intensities correspond to a temperature of 296 K. The broadening coefficients (HWHM) refer to the broadening by CO2.
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