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Table A.1.

Comparison of computed Landé g-factors, gγJ, with their LS-coupling values gJ(LS) and experimental values (Exp.).

No. State gJ(LS) gγJ Exp.
C I (1)
2 1.50000 1.50109 1.5010623(50)
3 1.50000 1.50107 1.5010469(50)
10 1.00000 1.00007 0.97
C III (1)
5 1.00000 0.99990 1.01
9 1.00000 0.99991 1.01
P II (2)(3)
7 0.50000 0.49910 0.504
8 1.16667 1.16713 1.16
9 1.33333 1.33399 1.329
10 1.50000 1.48750 1.486
11 1.50000 1.50077 1.5
13 1.00000 1.01330 1.014
15 1.50000 1.49450 1.495
16 1.50000 1.50106 1.499
17 0.66667 0.66594 0.666
18 1.08333 1.08347 1.083
19 1.25000 1.25051 1.25
20 1.00000 1.00644 1.006
21 3s2 3p 2P 4p 1P1 1.00000 0.99420 0.998
22 3s2 3p 2P 4p 3D1 0.50000 0.50942 0.511
23 1.00000 0.99699 1
24 3s2 3p 2P 4p 3D2 1.16667 1.16808 1.166
25 3s2 3p 2P 4p 3D3 1.33333 1.33404 1.334
26 1.50000 1.37568 1.408
27 0.50000 0.89293 0.94
28 1.33333 1.33335 1.326
29 1.50000 1.11039 1.05
31 1.16667 1.29222 1.26
33 3s2 3p 2P 4p 3P1 1.50000 1.53101 1.525
34 3s2 3p 2P 4p 3P2 1.50000 1.49802 1.499
35 3s23p 2P 4p 3S1 2.00000 1.96742 1.968
36 1.00000 1.00063 1.004
37 3s2 3p 2P 4p 1D2 1.00000 1.00189 1.002
40 1.00000 1.00010 0.998
41 1.00000 1.00064 0.99
43 1.50000 1.46648 1.465
44 1.50000 1.50104 1.497
45 1.00000 1.03443 1.036
46 0.66667 0.66790 0.664
47 1.08333 1.08425 1.081
48 1.25000 1.25053 1.25
49 1.50000 1.33882 1.278
50 0.50000 0.89316 0.87
51 1.00000 1.05416 1.098
52 1.33333 1.33185 1.33
54 1.50000 1.10772 1.129
55 1.16667 1.27311 1.284
56 3s2 3p 2P 5p 1P1 1.00000 0.94599 0.94
57 3s2 3p 2P 5p 3D1 0.50000 0.63857 0.62
58 3s2 3p 2P 5p 3D2 1.16667 1.18244 1.187
59 3s2 3p 2P 5p 3D3 1.33333 1.33383 1.34
61 3s2 3p 2P 5p 3P1 1.50000 1.46729 1.473
62 1.00000 1.00138 1
63 3s2 3p 2P 5p 3P2 1.50000 1.47622 1.47
64 3s2 3p 2P 5p 3S1 2.00000 1.95020 1.96
65 3s2 3p 2P 4f 1F3 1.00000 1.02861 1.02
66 3s2 3p 2P 4f 3F2 0.66667 0.69005 0.674
67 3s2 3p 2P 4f 3F3 1.08333 1.02328 1.03
68 3s2 3p 2P 4f 3F4 1.25000 1.21827 1.22
69 3s2 3p 2P 5p 1D2 1.00000 1.00737 1.005
70 3s2 3p 2P 4f 3G3 0.75000 0.79709 0.79
71 3s2 3p 2P 4f 3G4 1.05000 1.07055 1.06
72 3s2 3p 2P 4f 3G5 1.20000 1.20042 1.2
73 1.00000 0.99914 0.999
74 3s2 3p 2P 4f 1G4 1.00000 1.01177 1.01
75 3s2 3p 2P 4f 3D3 1.33333 1.31820 1.32
76 3s2 3p 2P 4f 3D2 1.16667 1.06628 1.063
77 3s2 3p 2P 4f 3D1 0.50000 0.49893 0.5
78 3s2 3p 2P 4f 1D2 1.00000 1.07863 1.083
81 1.50000 1.41849 1.42
85 1.50000 1.50082 1.5
87 1.00000 1.08220 1.08
89 0.66667 0.68597 0.69
90 1.08333 1.09022 1.08
91 1.25000 1.25053 1.25
93 1.00000 1.13551 1.12
94 0.50000 0.70581 0.69
95 1.16667 1.17731 1.18
96 1.33333 1.32274 1.33
97 1.50000 1.33546 1.34
98 1.50000 1.29786 1.3
101 1.00000 1.00454 1.01
Si I (1)
2 1.50000 1.50110 1.52
3 1.50000 1.50095 1.50
4 1.00000 1.00009 1.01
8 1.50000 1.49593 1.52
9 1.50000 1.50110 1.49
10 1.00000 1.00509 0.99
15 1.00000 1.00005 1.02
32 1.00000 0.99476 1.00
Si III (1)
5 1.00000 0.99995 0.98
6 3p2 1D2 1.00000 1.00010 0.98
13 3s 4s 3S1 2.00000 2.00221 2.00
16 3s 3d 1D2 1.00000 0.99996 0.99
18 1.50000 1.50050 1.55
19 1.50000 1.50109 1.49
20 1.00000 1.00054 1.01
27 3s 4d 1D2 1.00000 1.00000 1.00
Si IV (1)
6 4s 2S1/2 2.00000 2.00225 1.98
7 0.670000 0.66583 0.72
8 1.33000 1.33405 1.34
9 4d 2D5/2 1.20000 1.20043 1.16
15 1.33000 1.33407 1.34
Ti II (4)
11 0.800000 0.80900 0.80
15 2.66667 2.58681 2.63
16 1.73333 1.70373 1.74
18 0.666667 0.78123 0.66
19 2.66667 2.63809 2.60
21 1.33333 1.35842 1.33
29 0.666667 0.66607 0.66
30 1.33333 1.33324 1.33
45 0.800000 0.80021 0.92
46 1.20000 1.19159 1.20
48 0.000000 1.02735E-04 0.00
49 1.20000 1.18881 1.20
50 1.37143 1.36075 1.37
56 2.00000 1.99657 2.09
57 0.800000 0.98131 1.21
Sn II (5)
3 5s 5p2 4P1/2 2.66667 2.65984 2.6609

References. (1) Lott et al. (1966); (2) Li (1972); (3) Martin et al. (1985); (4) Moore (1949); (5) David et al. (1980).

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