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Table B.3
New gas-phase reactions involved in formation and destruction of new and related species.
# | Reaction | α | β | γ | Ref. |
---|---|---|---|---|---|
1 | CNC+ + CH4 → HC2NCH+ + H2 | 2.10E-10 | 0 | 0 | Osamura et al. (1999) |
2 | CH3+ + HCN → CH3CNH+ | 7.65E-9 | −0.5 | 0 | DeFrees et al. (1985) |
3 | CH3+ + HCN → CH3NCH+ | 1.35E-9 | −0.5 | 0 | DeFrees et al. (1985) |
4 | CH3CN+ + CO → CH2NC + HCO+ | 3.00E-10 | −0.5 | 0 | From analogous -CN reaction |
5 | CH2OH + C2H4NC → C2H5NC + H2CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
6 | CH2OH + CH3CHNC → C2H5NC + H2CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
7 | CH3O + C2H4NC → C2H5NC + H2CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
8 | CH3O + CH3CHNC → C2H5NC + H2CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
9 | C + HNC → C2N + H | 4.00E-11 | 0 | 0 | Graninger et al. (2014) |
10 | C + HNC → HCN + C | 1.60E-10 | 0 | 0 | Graninger et al. (2014) |
11 | C + CH2NH → CH2CN + H | 1.00E-10 | 0 | 0 | Loison et al. (2014) |
12 | C + CH2NH → HCN + CH2 | 1.00E-10 | 0 | 0 | Loison et al. (2014) |
13 | COOH + C2H4NC → C2H5NC + CO2 | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
14 | COOH + CH3CHNC → C2H5NC + CO2 | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
15 | H + CH3NC → HCN + CH3 | 1.00E-10 | 0 | 0 | Graninger et al. (2014) |
16 | HCO + C2H4NC → C2H5NC + CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
17 | HCO + CH3CHNC → C2H5NC + CO | 1.00E-11 | 0 | 0 | From analogous -CN reaction |
18 | H + HNC → H + HCN | 1.00E-10 | 0 | 1200 | Graninger et al. (2014) |
19 | H + C2N → C + HCN | 2.00E-10 | 0 | 0 | Loison et al. (2014) |
20 | H + H2CN → H2 + HNC | 1.20E-11 | 0 | 0 | Loison et al. (2014) |
21 | O + HNC → CO + NH | 7.64E-10 | 0 | 1120 | Graninger et al. (2014) |
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