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Table B.3

New gas-phase reactions involved in formation and destruction of new and related species.

# Reaction α β γ Ref.
1 CNC+ + CH4 → HC2NCH+ + H2 2.10E-10 0 0 Osamura et al. (1999)
2 CH3+ + HCN → CH3CNH+ 7.65E-9 −0.5 0 DeFrees et al. (1985)
3 CH3+ + HCN → CH3NCH+ 1.35E-9 −0.5 0 DeFrees et al. (1985)
4 CH3CN+ + CO → CH2NC + HCO+ 3.00E-10 −0.5 0 From analogous -CN reaction
5 CH2OH + C2H4NC → C2H5NC + H2CO 1.00E-11 0 0 From analogous -CN reaction
6 CH2OH + CH3CHNC → C2H5NC + H2CO 1.00E-11 0 0 From analogous -CN reaction
7 CH3O + C2H4NC → C2H5NC + H2CO 1.00E-11 0 0 From analogous -CN reaction
8 CH3O + CH3CHNC → C2H5NC + H2CO 1.00E-11 0 0 From analogous -CN reaction
9 C + HNC → C2N + H 4.00E-11 0 0 Graninger et al. (2014)
10 C + HNC → HCN + C 1.60E-10 0 0 Graninger et al. (2014)
11 C + CH2NH → CH2CN + H 1.00E-10 0 0 Loison et al. (2014)
12 C + CH2NH → HCN + CH2 1.00E-10 0 0 Loison et al. (2014)
13 COOH + C2H4NC → C2H5NC + CO2 1.00E-11 0 0 From analogous -CN reaction
14 COOH + CH3CHNC → C2H5NC + CO2 1.00E-11 0 0 From analogous -CN reaction
15 H + CH3NC → HCN + CH3 1.00E-10 0 0 Graninger et al. (2014)
16 HCO + C2H4NC → C2H5NC + CO 1.00E-11 0 0 From analogous -CN reaction
17 HCO + CH3CHNC → C2H5NC + CO 1.00E-11 0 0 From analogous -CN reaction
18 H + HNC → H + HCN 1.00E-10 0 1200 Graninger et al. (2014)
19 H + C2N → C + HCN 2.00E-10 0 0 Loison et al. (2014)
20 H + H2CN → H2 + HNC 1.20E-11 0 0 Loison et al. (2014)
21 O + HNC → CO + NH 7.64E-10 0 1120 Graninger et al. (2014)

Notes. Dissociative recombination reactions are included for all new species, but are omitted from these tables for brevity.

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