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Table B.1

Physical quantities of new and related chemical species.

Species Binding energy (K) Enthalpy of formation, ΔHf(298K) (kcal mol−1) Notes
HCN 2050 +32.30
HNC 2050 +32.30
CH3CN 6150 +17.70 Binding energy from Bertin et al. (2017)
CH3NC 5686 +17.70 Binding energy from Bertin et al. (2017)
CH2CN 4230 +59.00 Based on CH3CN-H
CH2NC 4230 +74.00 Based on CH2CN
C2H2CN 4187 +105.84 Based on C2H2+CN
C2H2NC 4187 +105.84 Based on C2H2CN
C2H3CN 4637 +42.95 Based on C2H2CN+H
C2H3NC 4637 +63.20 Based on C2H3CN
C2H4CN 5087 +55.13 Based on C2H3CN+H
C2H4NC 5087 +55.13 Based on C2H4CN
CH3CHCN 5087 +53.23 Based on C2H4CN
CH3CHNC 5087 +53.23 Based on C2H4CN
C2H5CN 5537 +12.71 Based on C2H4CN+H
C2H5NC 5537 +31.69 Based on C2H5CN
HC3N 4580 +84.63 Based on HCCN+C
HCNC2 4580 +84.60 Based on HC3N
HCCNC 4580 +84.60 Based on HC3N
HNC3 4580 +84.60 Based on HC3N

Notes. Binding energies are representative of physisorption on amorphous water ice. Enthalpies of formation are taken from the NIST WebBook database where available; otherwise estimates are made as described in the Notes column.

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