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Table A.1

Lines of CH3NC and HCCNC detected in the EMoCA spectrum of Sgr B2(N2).

Transition(a) Frequency Unc.(b) Eup (c) gup (d) Aul (e) σ(f) τpeak(g) Frequency range(h) Iobs(i) Imod(j) Iall(k)
(MHz) (kHz) (K) (s−1) (mK) (MHz) (MHz) (K km s−1) (K km s−1)
CH3NC
52–42 100 517.433 90 43 22 6.8(− 5) 141 0.109 100 515.3 100 519.2 48.5(6) 42.5 49.3
51–41 100 524.249 90 22 22 7.8(− 5) 141 0.144 100 523.1 100 525.6 66.9(5) 52.7 57.2

HCCNC
109–98 99 354.250 15 26 19 4.6(− 5) 162 0.022 99 352.7 99 356.1 7.1(6) 7.6 7.8
109–99 99 354.250 15 26 19 5.2(− 7)
109–910 99 354.250 15 26 19 1.3(− 9)
1010 – 99 99 354.250 15 26 21 4.6(− 5)
1010 – 910 99 354.250 15 26 21 4.7(− 7)
1011–910 99 354.250 15 26 23 4.7(− 5)
1110 – 10 109 289.095 15 32 21 6.2(− 5) 123 0.026 109 287.6 109 291.0 14.7(4) 9.7 12.6
1110–11 109 289.095 15 32 21 5.7(− 7)
1110–11 109 289.095 15 32 21 1.2(− 9)
1111 – 11 109 289.095 15 32 23 6.2(− 5)
1111 – 11 109 289.095 15 32 23 5.2(− 7)
1112–11 109 289.095 15 32 25 6.2(− 5)

Notes. (a) Quantum numbers of the upper and lower levels. (b)Frequency uncertainty. (c)Upper level energy. (d)Upper level degeneracy. (e) Einstein coefficient for spontaneous emission. X(Y) means X × 10Y. (f) Measured rms noise level. (g) Peak opacity of the synthetic line. (h) Frequency range over which the emission was integrated. (i)Integrated intensity of the observed spectrum in brightness temperature scale. The statistical standard deviation is given in parentheses in unit of the last digit. (j) Integrated intensity of the synthetic spectrum of the selected state. (k)Integrated intensity of the model that contains the contribution of all identified molecules, including CH3NC and HCCNC.

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