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Table 3.

Spectroscopic constants for the ground state and vibrationally excited states of succinonitrile.

Constants/units Ground state ν13 ν12 2ν13 ν13 + ν12 ν24
A/MHz 6918.11131(80) 6987.0714(22) 6874.9947(28) 7060.6476(31) 6943.203(14) 6958.8496(72)
B/MHz 2376.27544(56) 2373.8628(12) 2386.2675(17) 2370.4265(15) 2384.1652(36) 2376.8526(18)
C/MHz 1896.98617(59) 1894.1505(11) 1901.5608(14) 1891.0205(13) 1898.6948(18) 1898.7786(18)
ΔJ/kHz 3.67233(99) 3.6617(19) 3.7191(23) 3.6781(23) 3.7132(33) 3.7020(28)
ΔJK/kHz −27.79568(51) −28.5334(10) −27.5273(14) −29.4602(15) −28.2720(62) −28.4086(28)
ΔK/kHz 70.248(11) 75.279(18) 67.087(21) 81.358(27) 72.61(12) 73.332(66)
δJ/kHz 1.264983(27) 1.271132(73) 1.28738(30) 1.28068(14) 1.2990(13) 1.27704(22)
δK/kHz 5.98372(48) 6.5624(22) 5.9509(25) 7.2189(33) 6.5426(65) 6.1714(38)
ΦJ/mHz 20.71(58) 13.1(10) 20.8(12) 14.0(12) 17.2(16) 19.4(15)
ΦJK/mHz 9.68(85) 4.15(16)
ΦKJ/Hz −1.0343(28) −1.1824(53) −0.9278(52) −1.4840(85) −0.942(22) −0.986(13)
ΦK/Hz 2.948(42) 3.628(62) 2.751(69) 4.542(88) 5.26(36) 2.50(21)
ϕJ/mHz 7.9224(40) 7.192(11) 8.580(75) 6.506(33) 10.94(54) 7.941(35)
ϕK/Hz 0.7819(13) 0.685(12) 0.6942(68) 0.827(24) 0.469(43) 0.922(15)
σrms/kHz 23.75 24.56 25.32 26.99 31.64 33.94
σwrms (b) 0.79 (c) 0.82 (c) 0.51 (d) 0.54 (d) 0.63 (d) 0.68 (d)
Nlines 459 351 251 293 140 189
Jmin/Jmax 6/70 6/66 13/46 11/58 15/44 14/54
Ka, min/Ka, max 0/14 0/13 0/12 0/12 0/12 0/13

Constants/units 3ν13 4ν13 2ν12 2ν13 + ν12 ν13 + ν24 ν23

A/MHz 7139.926(91) 7215.1(33) 6782.8(31) 7015.635(74) 7028.739(79) 6776.0(61)
B/MHz 2365.777(11) 2359.11(49) 2413.60(29) 2381.0733(47) 2374.0520(56) 2381.77(61)
C/MHz 1887.5285(13) 1883.697(16) 1906.0535(32) 1895.60422(87) 1895.78252(92) 1898.585(14)
ΔJ/kHz 3.698(17) 3.6657(40) 3.6885(24) 3.65579(67) 3.67139(73) −3.6590(38)
ΔJK/kHz −30.64(24) −27.79568 (a) −20.18(40) −29.934(74) −30.096(85) −27.79568 (a)
ΔK/kHz 93.8(69) 70.248 (a) 70.248 (a) 105.3(17) 103.2(19) 70.248 (a)
δJ/kHz 1.2881(85) 1.264983 (a) 1.264983 (a) 1.264983 (a) 1.264983 (a) 1.264983 (a)
δK/kHz 7.78(28) 5.98372 (a) 5.98372 (a) 5.98372 (a) 5.98372 (a) 5.98372 (a)
ΦJ/mHz 20.71 (a) 20.71 (a) 20.71 (a) 20.71 (a) 20.71 (a) 20.71 (a)
ΦJK/mHz
ΦKJ/Hz −1.0343 (a) −1.0343 (a) −1.0343 (a) −1.0343 (a) −1.0343 (a) −1.0343 (a)
ΦK/Hz 2.948 (a) 2.948 (a) 2.948 (a) 2.948 (a) 2.948 (a) 2.948 (a)
ϕJ/mHz 7.9224 (a) 7.9224 (a) 7.9224 (a) 7.9224 (a) 7.9224 (a) 7.9224 (a)
ϕK/Hz 0.7819 (a) 0.7819 (a) 0.7819 (a) 0.7819 (a) 0.7819 (a) 0.7819 (a)
σfit/kHz 32.10 26.36 36.62 28.38 31.68 36.15
σwrms (b) 0.64 (d) 0.53 (d) 0.73 (d) 0.57 (d) 0.63 (d) 0.72 (d)
Nlines 53 15 22 45 52 20
Jmin/Jmax 20/29 20/30 18/30 18/30 18/30 19/30
Ka, min/Ka, max 0/3 0/1 0/2 0/3 0/3 0/1

Notes. Numbers in parentheses represent the derived uncertainty (1σ) of the parameter in units of the last digit.

(a)

Fixed to the ground state value.

(b)

Weighted standard deviation of the fit.

(c)

The uncertainty associated to the lines is 30 kHz.

(d)

The uncertainty associated to the lines is 50 kHz.

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