Table 1.
Spectroscopic constants for the ground state of succinonitrile.
Constants/units | Present work | Previous work (a) |
---|---|---|
A/MHz | 6918.11131(80) | 6918.113885(151) |
B/MHz | 2376.27544(56) | 2376.262803(90) |
C/MHz | 1896.98617(59) | 1896.993520(43) |
ΔJ/kHz | 3.67233(99) | 3.5175(10) |
ΔJK/kHz | −27.79568(51) | −26.8928(82) |
ΔK/kHz | 70.248(11) | 69.482(20) |
δJ/kHz | 1.264983(27) | −1.26678(57) (b) |
δK/kHz | 5.98372(48) | −74.55(18) (c) |
ΦJ/mHz | 20.71(58) | |
ΦKJ/Hz | −1.0343(28) | |
ΦK/Hz | 2.948(42) | |
ϕJ/mHz | 7.9224(40) | |
ϕK/Hz | 0.7819(13) | |
σfit/kHz | 23.75 | |
Nlines | 459 | 57 |
Jmin/Jmax | 6/70 | 1/18 |
Ka, min/Ka, max | 0/14 | 0/6 |
Notes. Numbers in parentheses represent the derived uncertainty (1σ) of the parameter in units of the last digit.
Previous constants derived by Jahn et al. (2014).
This value is the d1 quartic centrifugal distortion constant since Jahn et al. (2014) used a Watson’s S-reduced Hamiltonian.
This value is the d2 quartic centrifugal distortion constant since Jahn et al. (2014) used a Watson’s S-reduced Hamiltonian.
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