Table 6.

Selected ground state spectroscopic parameters(a) of this work of CH3C(O)CH3, C(O)CH3, and 13CH3C(O)CH3.

Parameter CH3C(O)CH3 C(O)CH3 13CH3C(O)CH3
ρ1 0.0619535 (120) 0.0614858 (41) 0.060458 (57)
ρ2 0.061811 (58)
β1 25.5065 (76) 25.7140 (31) 29.5967 (77)
180 ° −β2 21.2614 (76)
A/MHz 10165.217780 (280) 10164.005782 (145) 10083.03218 (58)
B/MHz 8515.163068 (248) 8516.083092 (104) 8277.50617 (44)
C/MHz 4910.198777 (209) 4910.235399 (107) 4811.468965 (174)
ΔJ/kHz 4.854449 (219) 4.852046 (73) 4.5557 (147)
ΔJK/kHz −3.17067 (60) −3.192449 (194) −2.865 (74)
ΔK/kHz 9.79105 (88) 9.85055 (33) 9.456 (60)
δJ/kHz 2.038605 (99) 2.0381002 (265) 1.8855 (77)
δK/kHz −0.60720 (39) −0.619619 (127) −0.226 (31)
ϵ10/MHz −764.737 (38) −763.9260 (53) −759.25 (81)
ϵ01/MHz −766.18 (79)
ϵ20/MHz 0.77490 (283) 0.76612 (173) 0.574 (45) (b)
ϵ02/MHz 0.574 (45)
ϵ11/MHz 1.0902 (95) 1.1059 (61) 1.0000 (212)
ϵ1 − 1/MHz 0.07346 (262) 0.08853 (176) 0.08630 (143)

No. of transitions fit 2181 9715 110
No. of lines fit 1862 5870 72
Standard deviation (c) 0.95 1.29 0.93

Notes.

(a)

Numbers in parentheses are one standard deviation in units of the least significant figures.

(b)

Parameter of (q, q′) = (q, 0) is fixed to its counterpart equivalent parameter with (0, q).

(c)

Weighted unitless value for the entire fit.

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