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Table A.3.
Wave function composition (up to three LS components with a contribution >0.02 of the total wave function) in LS-coupling and energy levels (in cm−1) for Ar IV.
| No. | State | LS-composition | ERCI(CV) | ENIST | τl | τv |
|---|---|---|---|---|---|---|
| 1 |  |
0.95 + 0.03  |
0 | 0 | ||
| 2 |  |
0.93 | 21 309 | 21 090.6 | 4.27e+01 | 4.28e+01 |
| 3 |  |
0.94 | 21 433 | 21 219.8 | 5.13e+02 | 5.30e+02 |
| 4 |  |
0.93 | 35 210 | 34 854.6 | 6.08e−01 | 6.09e−01 |
| 5 |  |
0.92 | 35 372 | 35 032.4 | 2.73e−01 | 2.73e−01 |
| 6 |  |
0.85 + 0.12  |
118 023 | 117 563.4 | 4.09e−09 | 3.80e−09 |
| 7 |  |
0.84 + 0.12  |
118 971 | 118 515.7 | 4.02e−09 | 3.75e−09 |
| 8 |  |
0.84 + 0.12  |
119 508 | 119 043.1 | 3.98e−09 | 3.71e−09 |
| 9 |  |
0.70 + 0.21  + 0.03  |
146 525 | 145 921.2 | 2.17e−09 | 2.02e−09 |
| 10 |  |
0.70 + 0.21  + 0.03  |
146 603 | 145 999.4 | 2.23e−09 | 2.07e−09 |
| 11 |  |
0.55 + 0.32  + 0.07  |
166 719 | 166 356.4 | 1.01e−09 | 9.54e−10 |
| 12 |  |
0.55 + 0.32  + 0.06  |
167 826 | 167 444.6 | 9.85e−10 | 9.27e−10 |
| 13 |  |
0.72 + 0.23  |
178 782 | 177 832.5 | 6.65e−10 | 6.30e−10 |
| 14 |  |
0.95 | 180 820 | 180 682.5 | 4.56e−07 | 4.37e−07 |
| 15 |  |
0.94 | 181 169 | 181 031.8 | 6.05e−07 | 6.00e−07 |
| 16 |  |
0.94 | 181 686 | 181 533.3 | 1.07e−06 | 1.11e−06 |
| 17 |  |
0.95 | 182 360 | 182 195.6 | 1.40e−01 | 1.36e−01 |
| 18 |  |
0.38 + 0.30  + 0.26  |
187 234 | 1.91e−07 | 1.92e−07 | |
| 19 |  |
0.94 | 187 477 | 187 290.4 | 1.54e−07 | 1.48e−07 |
| 20 |  |
0.59 + 0.21  + 0.14  |
187 506 | 188 824.5 | 5.55e−05 | 4.31e−05 |
| 21 |  |
0.94 | 187 575 | 187 397.5 | 1.19e−07 | 1.17e−07 |
| 22 |  |
0.64 + 0.18  + 0.13  |
188 019 | 187 821.3 | 1.18e−07 | 1.18e−07 |
| 23 |  |
0.35 + 0.35  + 0.24  |
189 057 | 7.89e−07 | 7.76e−07 | |
| 24 |  |
0.94 | 208 246 | 207 760.7 | 1.93e−07 | 1.94e−07 |
| 25 |  |
0.94 | 208 374 | 207 859.3 | 1.26e−01 | 1.24e−01 |
| 26 |  |
0.81 + 0.11  |
221 139 | 220 786.8 | 3.07e−11 | 3.05e−11 |
| 27 |  |
0.80 + 0.11  |
221 654 | 221 300.9 | 3.05e−11 | 3.03e−11 |
| 28 |  |
0.81 + 0.11  |
222 001 | 221 627.4 | 3.03e−11 | 3.01e−11 |
| 29 |  |
0.44 + 0.36  + 0.09  |
223 805 | 222 956.1 | 4.46e−11 | 4.36e−11 |
| 30 |  |
0.43 + 0.41  + 0.08  |
224 891 | 224 019.3 | 4.41e−11 | 4.32e−11 |
| 31 |  |
0.46 + 0.41  + 0.02  |
225 349 | 2.73e−10 | 2.69e−10 | |
| 32 |  |
0.47 + 0.42  + 0.03  |
226 733 | 2.65e−10 | 2.61e−10 | |
| 33 |  |
0.64 + 0.16  + 0.06  |
239 358 | 238 674 | 3.84e−11 | 3.80e−11 |
| 34 |  |
0.65 + 0.17  + 0.05  |
239 738 | 239 050 | 3.69e−11 | 3.65e−11 |
| 35 |  |
0.44 + 0.30  + 0.15  |
246 701 | 3.64e−11 | 3.59e−11 | |
| 36 |  |
0.47 + 0.30  + 0.14  |
247 150 | 3.66e−11 | 3.61e−11 | |
| 37 |  |
0.53 + 0.37  |
247 182 | 246 628 | 2.61e−11 | 2.61e−11 |
| 38 |  |
0.54 + 0.37  |
247 316 | 246 737.6 | 2.61e−11 | 2.61e−11 |
| 39 |  |
0.48 + 0.27  + 0.14  |
250 005 | 5.31e−11 | 5.26e−11 | |
| 40 |  |
0.66 + 0.20  + 0.06  |
250 061 | 250 215.2 | 1.14e−10 | 1.13e−10 |
| 41 |  |
0.92 | 250 721 | 250 902.16 | 4.87e−10 | 4.81e−10 |
| 42 |  |
0.93 | 251 782 | 251 967.35 | 4.85e−10 | 4.79e−10 |
| 43 |  |
0.91 | 255 973 | 256 087.8 | 1.19e−10 | 1.18e−10 |
| 44 |  |
0.91 | 257 213 | 257 343.58 | 1.17e−10 | 1.16e−10 |
| 45 |  |
0.43 + 0.35  + 0.07  |
257 224 | 2.91e−11 | 2.90e−11 | |
| 46 |  |
0.43 + 0.37  + 0.05  |
257 667 | 2.93e−11 | 2.92e−11 | |
| 47 |  |
0.98 | 259 721 | 1.72e−06 | 1.65e−06 | |
| 48 |  |
0.98 | 259 730 | 1.47e−06 | 1.38e−06 | |
| 49 |  |
0.98 | 259 731 | 2.42e−06 | 2.41e−06 | |
| 50 |  |
0.98 | 259 755 | 4.51e−06 | 4.67e−06 | |
| 51 |  |
0.98 | 259 799 | 1.12e−05 | 9.38e−06 | |
| 52 |  |
0.92 + 0.02  |
267 750 | 267 741.3 | 2.31e−10 | 2.29e−10 |
| 53 |  |
0.92 + 0.02  |
267 774 | 267 762 | 2.29e−10 | 2.26e−10 |
| 54 |  |
0.48 + 0.34  + 0.06  |
275 778 | 1.01e−09 | 9.51e−10 | |
| 55 |  |
0.47 + 0.35  + 0.06  |
277 251 | 1.04e−09 | 9.78e−10 | |
| 56 |  |
0.92 | 280 888 | 9.69e−10 | 9.64e−10 | |
| 57 |  |
0.24 + 0.45  + 0.20  |
283 959 | 1.17e−09 | 1.17e−09 | |
| 58 |  |
0.28 + 0.36  + 0.25  |
284 080 | 1.46e−09 | 1.47e−09 | |
| 59 |  |
0.33 + 0.31  + 0.23  |
284 232 | 2.15e−09 | 2.16e−09 | |
| 60 |  |
0.37 + 0.36  + 0.14  |
284 368 | 3.40e−09 | 3.39e−09 | |
| 61 |  |
0.47 + 0.25  + 0.18  |
286 149 | 285 956.2 | 9.93e−10 | 9.90e−10 |
| 62 |  |
0.56 + 0.20  + 0.14  |
286 336 | 286 224.5 | 8.45e−10 | 8.43e−10 |
| 63 |  |
0.68 + 0.14  + 0.08  |
286 778 | 286 747.8 | 7.14e−10 | 7.14e−10 |
| 64 |  |
0.79 + 0.09  + 0.04  |
287 525 | 287 550.8 | 6.38e−10 | 6.38e−10 |
| 65 |  |
0.92 | 289 025 | 289 122.3 | 5.42e−10 | 5.43e−10 |
| 66 |  |
0.80 + 0.06  + 0.04  |
289 132 | 289 233.9 | 5.58e−10 | 5.58e−10 |
| 67 |  |
0.90 + 0.03  |
289 489 | 2.27e−10 | 2.25e−10 | |
| 68 |  |
0.78 + 0.10  + 0.04  |
289 727 | 289 830.5 | 5.70e−10 | 5.70e−10 |
| 69 |  |
0.68 + 0.17  + 0.07  |
290 224 | 290 251.5 | 8.10e−10 | 8.02e−10 |
| 70 |  |
0.70 + 0.15  + 0.11  |
291 322 | 5.69e−09 | 5.36e−09 | |
| 71 |  |
0.69 + 0.14  + 0.11  |
291 519 | 5.02e−09 | 4.76e−09 | |
| 72 |  |
0.62 + 0.14  + 0.14  |
291 628 | 291 663.1 | 7.95e−10 | 7.88e−10 |
| 73 |  |
0.86 + 0.05  + 0.02  |
291 667 | 291 744 | 5.64e−10 | 5.60e−10 |
| 74 |  |
0.71 + 0.14  + 0.11  |
291 804 | 5.87e−09 | 5.52e−09 | |
| 75 |  |
0.72 + 0.14  + 0.11  |
292 173 | 6.02e−09 | 5.66e−09 | |
| 76 |  |
0.75 + 0.14  + 0.02  |
295 743 | 295 670.2 | 6.98e−10 | 6.89e−10 |
| 77 |  |
0.73 + 0.17  |
295 849 | 295 802.2 | 7.03e−10 | 6.94e−10 |
| 78 |  |
0.91 + 0.02  |
303 802 | 303 665.4 | 6.34e−10 | 6.32e−10 |
| 79 |  |
0.92 + 0.02  |
304 125 | 303 989.1 | 6.29e−10 | 6.28e−10 |
| 80 |  |
0.61 + 0.18  + 0.17  |
304 259 | 2.52e−09 | 2.40e−09 | |
| 81 |  |
0.71 + 0.18  |
306 032 | 305 827.4 | 7.72e−10 | 7.52e−10 |
| 82 |  |
0.72 + 0.17  |
306 112 | 305 899.6 | 7.65e−10 | 7.46e−10 |
| 83 |  |
0.88 + 0.07  |
306 552 | 2.17e−09 | 2.04e−09 | |
| 84 |  |
0.88 + 0.07  |
306 623 | 2.19e−09 | 2.06e−09 | |
| 85 |  |
0.88 + 0.07  |
306 732 | 2.21e−09 | 2.08e−09 | |
| 86 |  |
0.88 + 0.07  |
306 871 | 2.23e−09 | 2.09e−09 | |
| 87 |  |
0.76 + 0.14  |
312 019 | 4.92e−10 | 4.85e−10 | |
| 88 |  |
0.71 + 0.17  |
312 497 | 4.95e−10 | 4.88e−10 | |
| 89 |  |
0.80 + 0.15  |
317 986 | 5.06e−09 | 4.74e−09 | |
| 90 |  |
0.80 + 0.14  |
318 047 | 5.29e−09 | 4.93e−09 | |
| 91 |  |
0.37 + 0.30  + 0.18  |
324 720 | 3.76e−10 | 3.72e−10 | |
| 92 |  |
0.35 + 0.29  + 0.18  |
324 958 | 3.72e−10 | 3.68e−10 | |
| 93 |  |
0.33 + 0.28  + 0.17  |
325 417 | 3.66e−10 | 3.61e−10 | |
| 94 |  |
0.73 + 0.12  + 0.11  |
326 067 | 7.89e−10 | 7.72e−10 | |
| 95 |  |
0.36 + 0.30  + 0.19  |
326 249 | 3.40e−10 | 3.36e−10 | |
| 96 |  |
0.69 + 0.11  + 0.08  |
326 277 | 5.84e−10 | 5.73e−10 | |
| 97 |  |
0.48 + 0.14  + 0.08  |
326 678 | 5.25e−10 | 5.16e−10 | |
| 98 |  |
0.41 + 0.13  + 0.11  |
326 881 | 7.97e−10 | 7.78e−10 | |
| 99 |  |
0.87 + 0.03  |
327 235 | 6.24e−10 | 6.21e−10 | |
| 100 |  |
0.87 + 0.03  + 0.02  |
327 351 | 6.18e−10 | 6.14e−10 | |
| 101 |  |
0.30 + 0.28  + 0.09  |
327 371 | 5.88e−10 | 5.76e−10 | |
| 102 |  |
0.77 + 0.15  + 0.03  |
329 302 | 7.89e−10 | 7.52e−10 | |
| 103 |  |
0.76 + 0.16  + 0.03  |
329 535 | 7.53e−10 | 7.19e−10 |
Notes. Energy levels are given relative to the ground state. The states 57 and 58 are indicated in bold. The labels for these levels were not assigned with largest contribution to the composition.
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