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Table A.2.

Wave function composition (up to three LS components with a contribution >0.02 of the total wave function) in LS-coupling and energy levels (in cm−1) for Cl III.

No. State LS-composition ERCI(CV) ENIST τl τv
1 0.94 + 0.03 0 0
2 0.93 18 286 18 052.46 1.82e+02 1.83e+02
3 0.93 18 345 18 118.43 1.27e+03 1.35e+03
4 0.92 + 0.02 3p52P° 30 117 29 813.92 1.38e+00 1.41e+00
5 0.91 + 0.02 3p52P° 30 200 29 906.45 6.91e−01 6.96e−01
6 0.83 + 0.12 98 508 98 520.34 7.47e−09 7.17e−09
7 0.83 + 0.13 99 114 99 131.4 7.37e−09 7.10e−09
8 0.83 + 0.13 99 462 99 475.22 7.31e−09 7.05e−09
9 0.67 + 0.23 + 0.03 122 392 122 131.66 4.37e−09 4.21e−09
10 0.67 + 0.23 + 0.03 122 443 122 179.8 4.48e−09 4.32e−09
11 0.60 + 0.26 + 0.07 137 180 2.62e−09 2.55e−09
12 0.60 + 0.26 + 0.07 137 920 2.52e−09 2.46e−09
13 0.94 146 611 146 521.72 1.12e−06 1.08e−06
14 0.94 146 835 146 746.99 1.28e−06 1.29e−06
15 0.94 147 165 147 069.57 1.94e−06 1.99e−06
16 0.94 147 600 147 494.54 3.10e−01 2.98e−01
17 0.67 + 0.27 150 041 1.27e−09 1.23e−09
18 0.58 + 0.20 + 0.15 151 972 151 846.4 1.55e−07 1.54e−07
19 0.93 151 979 151 944.55 4.10e−07 4.03e−07
20 0.93 152 038 151 878.06 2.62e−07 2.59e−07
21 0.71 + 0.13 + 0.09 152 072 151 951.64 1.22e−06 1.16e−06
22 0.33 + 0.35 + 0.25 152 458 9.59e−08 9.52e−08
23 0.41 + 0.30 + 0.22 153 210 1.57e−07 1.53e−07
24 0.93 169 142 3.48e−07 3.50e−07
25 0.93 169 202 2.05e−01 2.06e−01
26 0.84 + 0.08 173 576 173 735.28 1.42e−10 1.41e−10
27 0.82 + 0.10 173 935 174 093.02 1.28e−10 1.28e−10
28 0.78 + 0.13 174 478 174 611.76 1.08e−10 1.08e−10
29 0.87 + 0.02 + 0.02 178 291 178 369.14 1.14e−10 1.12e−10
30 0.84 + 0.04 + 0.03 179 006 179 075.2 1.05e−10 1.04e−10
31 0.67 + 0.15 + 0.10 179 918 179 493.96 7.06e−11 7.02e−11
32 0.70 + 0.11 + 0.10 180 105 179 662.15 6.38e−11 6.34e−11
33 0.72 + 0.11 + 0.09 180 253 179 780.84 6.05e−11 6.01e−11
34 0.50 + 0.38 182 507 182 075.74 4.32e−10 4.29e−10
35 0.51 + 0.38 + 0.02 183 470 183 041.91 3.77e−10 3.73e−10
36 0.49 + 0.33 + 0.07 186 809 185 837.68 1.03e−10 1.01e−10
37 0.54 + 0.32 + 0.05 187 208 186 219.67 1.00e−10 9.91e−11
38 0.83 + 0.07 188 428 188 389.53 1.25e−10 1.24e−10
39 0.82 + 0.06 188 490 188 447.52 1.27e−10 1.27e−10
40 0.49 + 0.13 + 0.09 195 683 194 958.79 8.41e−11 8.33e−11
41 0.54 + 0.15 + 0.09 196 011 195 267.76 8.02e−11 7.94e−11
42 0.48 + 0.36 + 0.03 196 688 196 137.22 4.24e−11 4.23e−11
43 0.50 + 0.37 + 0.03 196 724 196 153.36 4.18e−11 4.18e−11
44 0.92 197 580 2.85e−09 2.87e−09
45 0.27 + 0.30 + 0.27 199 748 198 835.25 5.00e−11 4.94e−11
46 0.25 + 0.31 + 0.30 199 855 198 983.79 5.08e−11 5.02e−11
47 0.92 200 890 201 072.41 1.77e−09 1.80e−09
48 0.92 201 139 201 330.92 1.77e−09 1.79e−09
49 0.45 + 0.26 + 0.15 201 480 5.29e−11 5.24e−11
50 0.92 201 568 201 763.86 1.76e−09 1.78e−09
51 0.92 202 176 202 366.62 1.75e−09 1.78e−09
52 0.92 203 807 204 021.26 1.67e−09 1.69e−09
53 0.85 + 0.04 + 0.03 203 902 204 124.04 1.68e−09 1.70e−09
54 0.84 + 0.06 204 320 204 540.95 1.72e−09 1.74e−09
55 0.76 + 0.14 + 0.03 204 903 205 036.99 2.59e−09 2.59e−09
56 0.87 + 0.05 205 705 205 938.06 1.49e−09 1.51e−09
57 0.72 + 0.12 + 0.08 205 802 205 946.9 ? 2.52e−09 2.53e−09
58 0.40 + 0.28 + 0.09 206 010 4.67e−11 4.65e−11
59 0.42 + 0.29 + 0.08 206 251 4.73e−11 4.71e−11
60 0.80 + 0.10 208 929 209 042.8 ? 2.18e−09 2.19e−09
61 0.78 + 0.12 209 054 209 182.8 ? 2.18e−09 2.19e−09
62 0.65 + 0.17 + 0.09 210 651 1.81e−09 1.75e−09
63 0.97 212 608 3.79e−06 3.63e−06
64 0.97 212 608 5.48e−06 5.56e−06
65 0.97 212 616 3.24e−06 3.06e−06
66 0.97 212 620 1.07e−05 1.14e−05
67 0.97 212 654 3.05e−05 2.52e−05
68 0.91 + 0.02 216 534 216 524.6 ? 1.96e−09 1.98e−09
69 0.92 + 0.02 216 726 216 710.4 ? 1.95e−09 1.96e−09
70 0.77 + 0.14 217 852 217 850.2 ? 2.04e−09 2.06e−09
71 0.77 + 0.14 217 923 217 913.1 ? 2.04e−09 2.06e−09
72 0.79 + 0.10 221 952 221 862.9 ? 1.86e−09 1.88e−09
73 0.75 + 0.12 222 175 222 100.7 ? 1.93e−09 1.96e−09
74 0.40 + 0.35 + 0.06 230 878 292 470 [] 1.71e−09 1.66e−09
75 0.39 + 0.35 + 0.06 231 746 293 540 [] 1.86e−09 1.81e−09
76 0.45 + 0.40 + 0.04 233 460 8.10e−09 7.93e−09
77 0.45 + 0.40 + 0.04 233 478 7.76e−09 7.61e−09
78 0.45 + 0.40 + 0.04 233 522 7.57e−09 7.45e−09
79 0.45 + 0.40 + 0.04 233 578 7.45e−09 7.35e−09
80 0.91 239 418 239 506.3 ? 1.49e−09 1.58e−09
81 0.90 + 0.03 239 640 239 729.9 ? 1.49e−09 1.58e−09
82 0.89 + 0.03 239 991 240 075.2 ? 1.50e−09 1.58e−09
83 0.93 240 490 240 568.4 ? 1.51e−09 1.60e−09
84 0.88 + 0.04 241 426 241 559.4 ? 1.33e−09 1.38e−09
85 0.80 + 0.06 + 0.06 241 445 241 572.4 ? 1.17e−09 1.21e−09
86 0.76 + 0.14 + 0.03 241 557 241 685.1 ? 1.13e−09 1.16e−09
87 0.88 + 0.03 241 904 242 046.2 ? 1.50e−09 1.57e−09

Notes. Energy levels are given relative to the ground state. (Level in NIST column flagged “?” means that level/line may not be real; “[]” means that level was determined by interpolation or extrapolation of known experimental values or by semiempirical calculation.). The states 45 and 46 are indicated in bold. The labels for these levels were not assigned with largest contribution to the composition.

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