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Table A.1.

NC​2M – gas-phase reactions.

No. Reaction Notes Ref.
1 H + e → H+ + 2 e 1
2 H+ + e → H Case A 2
3 He + e → He+ + 2 e 1
4a He+ + e → He Case A 3,4
5 He+ + e → He2+ + 2 e 1
6 He+ + e → He+ Case A 2
7 He+ + H → He + H+ 5
8 He + H+ → He+ + H 6
9–14 Cn+ + e → C(n + 1)+ + 2 e n​ = ​0…5 7
15–20a C(n + 1)+ + e → Cn+ n​ = ​0…5 8
21–24 C(n + 1)+ + H → Cn+ + H+ n​ = ​0…3 9
25 C + H+ → C+ + H 9
26,27 C(n + 1)+ + He → Cn+ + He+ n​ = ​2, 3 9
28–34 Nn+ + e → N(n + 1)+ + 2 e n​ = ​0…6 7
35–41a N(n + 1)+ + e → Nn+ n​ = ​0…6 8
42–45 N(n + 1)+ + H → Nn+ + H+ n​ = ​0…3 9
46 N + H+ → N+ + H 9
47–49 N(n + 1)+ + He → Nn+ + He+ n​ = ​1…3 9
50–57 On+ + e → O(n + 1)+ + 2 e n​ = ​0…7 7
58–65a O(n + 1)+ + e → On+ n​ = ​0…7 8
66–69 O(n + 1)+ + H → On+ + H+ n​ = ​0…3 9
70 O + H+ → O+ + H 9
71–73 O(n + 1)+ + He → On+ + He+ n​ = ​1…3 9
74–83 Nen+ + e → Ne(n + 1)+ + 2 e n​ = ​0…9 7
84–93a Ne(n + 1)+ + e → Nen+ n​ = ​0…9 8
94–96 Ne(n + 1)+ + H → Nen+ + H+ n​ = ​1…3 9
97–99 Ne(n + 1)+ + He → Nen+ + He+ n​ = ​1…3 9
100–111 Mgn+ + e → Mg(n + 1)+ + 2 e n​ = ​0…11 7
112–123a Mg(n + 1)+ + e → Mgn+ n​ = ​0…11 8
124–126 Mg(n + 1)+ + H → Mgn+ + H+ n​ = ​1…3 9
127,128 Mgn+ + H+ → Mg(n + 1)+ + H n​ = ​0, 1 9
129,130 Mg(n + 1)+ + He → Mgn+ + He+ n​ = ​2, 3 9
131–144 Sin+ + e → Si(n + 1)+ + 2 e n​ = ​0…13 7
145–158a Si(n + 1)+ + e → Sin+ n​ = ​0…13 8
159–161 Si(n + 1)+ + H → Sin+ + H+ n​ = ​1…3 9
162,163 Sin+ + H+ → Si(n + 1)+ + H n​ = ​0, 1 9
164,165 Si(n + 1)+ + He → Sin+ + He+ n​ = ​2, 3 9
166 Si + He+ → Si+ + He 9
167–192 Fen+ + e → Fe(n + 1)+ + 2 e n​ = ​0…25 7
193–218a Fe(n + 1)+ + e → Fen+ n​ = ​0…25 8,10,11
219–221 Fe(n + 1)+ + H → Fen+ + H+ n​ = ​1…3 9
222,223 Fen+ + H+ → Fe(n + 1)+ + H n​ = ​0, 1 9
224,225 Fe(n + 1)+ + He → Fen+ + He+ n​ = ​2, 3 9
300 H + e → H 12
301 H + H → H2 + e 13
302 H + H+ 14
303 H + → H2 + H+ 15
304 H+ + H2 + H 16
305 H2 + e → 2 H + e 17
306 H2 + H → 3 H 18,19
307 H + e → H + 2 e 1
308 H + H → 2 H + e 1
309 H + H+ → 2 H 20
310 H + H+ + e 21
311 + e → 2 H 22
312 + H → H + H2 23
313 3 H → H2 + H 24,25
314 2 H + H2 → 2 H2 26
315 2 H2 → H2 + 2 H 27,28
316 He+ + H → He + H 29
317 2 H + He → H2 + He 30
318 H2 + He → 2 H + He 31
319 H2 + He+ + He 32
320 H2 + He+ → H+ + H + He 32
321 H2 + H+ 33
322 + e → H2 + H 34
323 + e → 3 H 34
324 + H2 + H 35
325 + H → + H2 36
326 + H → 3 H 23
327 H2 + e → H + H 37
328 He + H → He + H + e 38
350 D + e → D+ + 2 e 1
351 D+ + e → D 2
352 D + He+ → D+ + He 5
353 D+ + He → D + He+ 6
354 D+ + H → D + H+ 39
355 D + H+ → D+ + H 39
356 D+ + H2 → HD + H+ 40
357 HD + H+ → H2 + D+ 40
358 H2 + D → HD + H 41,42
359 HD + H → D + H2 43
400 C + H+ → C + H 29
401 C + H → CH + e 29
402 C + H2 → CH2 + e 29
403 C + O → CO + e 29
404 O + H+ → O + H 29
405 O + H → OH + e 29
406 O + H2 → H2O + e 29
407 O + C → CO + e 29
408 C + e → C 44
409 C + H → CH + e 29
410 C + H → CH 45
411 C + H2 → CH2 45
412 C + H2 → CH + H 46
413 C + → CH+ + H 29
414 C + → CH+ + H2 29
415 2 C → C2 47
416 C + O → CO 48,49
417 C+ + H → CH+ 50
418 C+ + H2 → CH+ + H 51
419 C+ + H2 → C 29
420 C+ + O → CO+ 48
421 O + e → O 29
422 O + H → OH + e 29
423 O + H → OH 29
424 O + H2 → OH + H 52
425 O + → OH+ + H 29
426 O + → OH+ + H2 53
427 2 O → O2 45
428 O+ + H2 → OH+ + H 54,55
429 C2 + He+ → C+ + C + He 29
430 C2 + O → CO + C 56,57
431 C2 + O+ → CO+ + C 29
432 O2 + H → OH + O 29
433 O2 + H++ H 58
434 O2 + He+ + He 59,60
435 O2 + He+ → O+ +O + He 59,60
436 O2 + H2 → 2 OH 61
437 O2 + C → CO + O 62
438 O2 + C+ → CO + O+ 63,64
439 O2 + C+ → CO+ + O 63,64
440 O2 + → HCO+ + OH 63,64
441 + e → 2 O 65
442 + C → O2 + C+ 29
443 + C → CO+ + O 29
444 CH + H → C + H2 66
445 CH + H2 → CH2 + H 29
446 CH + C → C2 + H 62
447 CH + O → CO + H 67,68
448 CH + O → HCO+ + e 69
449 CH + H+ → CH+ + H 29
450 CH+ + e → C + H 70
451 CH+ + H → C+ + H2 71
452 CH+ + H2 → C + H 71
453 CH+ + O → CO+ + H 72
454 CH2 + H → CH + H2 29
455 CH2 + O → CO + 2 H 73
456 CH2 + O → CO + H2 29
457 CH2 + H+ → CH+ + H2 29
458 CH2 + H+ → C + H 29
459 CH2 + He+ → C+ + H2 + He 29
460 C + e → CH + H 74
461 C + e → C + 2 H 74
462 C + e → C + H2 74
463 C + H → CH+ + H2 29
464 C + H2 → C + H 63,64
465 C + O → HCO+ + H 45
466 C + e → CH2 + H 75
467 C + e → CH + H2 75
468 C + e → CH + 2 H 29
469 C + H → C + H2 29
470 C + O → HCO+ + H2 76
471 OH + H → H2O + e 29
472 OH + H → O + 2 H 29
473 OH + H → H2O 77
474 OH + H → O + H2 78
475 OH + H2 → H2O + H 79
476 OH + C → CO + H 62
477 OH + O → O2 + H 29
478 2 OH → O + H2O 62
479 OH + H+ → OH+ + H 29
480 OH + He+ → O+ + H +He 29
481 OH + → H2O+ + H2 29
482 OH + C+ → CO+ + H 80
483 OH + C+ → CO + H+ 80
484 OH+ + e → O + H 81
485 OH+ + H2 → H2O+ + H 82
486 H2O + H → OH + H2 83
487 H2O + H+ → H2O+ + H 58
488 H2O + He+ → OH + H+ + He 84,85
489 H2O + He+ → OH+ + H + He 84,85
490 H2O + He+ → H2O+ + He 84,85
491 H2O + → H3O+ + H2 86,87
492 H2O + C+ → HCO+ + H 88,89
493 H2O + C+ → HOC+ + H 90
494 H2O+ + e → O + 2 H 91
495 H2O+ + e → O + H2 91
496 H2O+ + e → OH + H 91
497 H2O+ + H2 → H3O+ + H 92
498 H3O+ + e → H2O + H 93
499 H3O+ + e → OH + H2 93
500 H3O+ + e → OH + 2 H 93
501 H3O+ + e → O + H +H2 94
502 H3O+ + C → HCO+ + H2 45
503 CO + H → C + OH 95
504 CO + → HOC+ + H2 96
505 CO + → HCO+ + H2 96
506 CO + He+ → C+ + O + He 97
507 CO + He+ → O+ + C + He 97
508 CO+ + e → C + O 98
509 CO+ + H → CO + H+ 99
510 CO+ + H2 → HCO+ + H 100
511 CO+ + H2 → HOC+ + H 100
512 HCO+ + e → OH + C 101
513 HCO+ + e → CO + H 101
514 HCO+ + C → CO + CH+ 45
515 HCO+ + H2O → CO + H3O+ 102
516 HOC+ + e → CO + H 29
517 HOC+ + H2 → HCO+ + H2 103
518 HOC+ + CO → HCO+ + CO 104
519 2 C + He → C2 + He 105
520 2 O + He → O2 + He 106
521 C + O + He → CO + He 97
522 C+ + O + He → CO+ + He 97
523 O+ + C + He → CO+ + He 97
524 O + H + He → OH + He 78
525 OH + H + He → H2O + He 67

Notes.

(a)

Both RR and DR. References. 1:Janev et al. (1987), 2: Ferland et al. (1992), 3: Hummer & Storey (1998), 4: Aldrovandi & Pequignot (1973), 5: Zygelman et al. (1989), 6: Kimura et al. (1993), 7: Voronov (1997), 8: Badnell (2006), 9: Stancil et al. (2015), 10: Shull & van Steenberg (1982), 11: Arnaud & Raymond (1992), 12: Wishart (1979), 13: Bruhns et al. (2010), 14: Ramaker & Peek (1976), 15: Karpas et al. (1979), 16: Savin et al. (2004), 17: Trevisan & Tennyson (2002), 18: MacLow & Shull (1986), 19: Lepp & Shull (1983), 20: Croft et al. (1999), 21: Poulaert et al. (1978), 22: Schneider et al. (1994), 23: Dalgarno & Lepp (1987), 24: Orel (1987), 25: Abel et al. (2002), 26: Cohen & Westberg (1983), 27: Martin et al. (1998), 28: Shapiro & Kang (1987), 29: McElroy et al. (2013), 30: Walkauskas & Kaufman (1975), 31: Dove et al. (1987), 32: Barlow (1984), 33: Gerlich & Horning (1992), 34: Woodall et al. (2007), 35: Linder et al. (1995), 36: Sidhu et al. (1992), 37: Schulz & Asundi (1967), 38: Huq et al. (1982), 39: Savin (2002), 40: Gerlich (1982), 41: Mielke et al. (2003), 42: Glover & Abel (2008), 43: Shavitt (1959), 44: Stancil & Dalgarno (1998), 45: Prasad & Huntress (1980), 46: Dean et al. (1991), 47: Andreazza & Singh (1997), 48: Dalgarno et al. (1990), 49: Singh et al. (1999), 50: Barinovs & van Hemert (2006), 51: Adams et al. (1984), 52: Natarajan & Roth (1987), 53: Milligan & McEwan (2000), 54: Smith et al. (1978), 55: Adams et al. (1980), 56: Mitchell & Deveau (1983), 57: Fairbairn (1969), 58: Smith et al. (1992), 59: Adams & Smith (1976a), 60: Adams & Smith (1976b), 61: Azatyan et al. (1975), 62: Smith et al. (2004), 63: Smith & Adams (1977a), 64: Smith & Adams (1977b), 65: Alge et al. (1983), 66: Harding et al. (1993), 67: Baulch et al. (1992), 68: Murrell & Rodriguez (1986), 69: MacGregor & Berry (1973), 70: Takagi et al. (1991), 71: McEwan et al. (1999), 72: Viggiano et al. (1980), 73: Frank (1986), 74: Larson et al. (1998), 75: Mitchell (1990), 76: Fehsenfeld (1976), 77: Field et al. (1980), 78: Tsang & Hampson (1986), 79: Oldenborg et al. (1992), 80: Dubernet et al. (1992), 81: Guberman (1995), 82: Jones et al. (1981), 83: Cohen & Westberg (1979), 84: Mauclaire et al. (1978a), 85: Mauclaire et al. (1978b), 86: Kim et al. (1974), 87: Anicich et al. (1975), 88: Anicich et al. (1976), 89: Watson et al. (1976), 90: Martinez et al. (2008), 91: Rosén et al. (2000), 92: Raksit & Warneck (1980), 93: Novotny et al. (2010), 94: Jensen et al. (2000), 95: Mitchell (1984), 96: Klippenstein & Georgievskii (2010), 97: Petuchowski et al. (1989), 98: Rosén et al. (1998), 99: Federer et al. (1984), 100: Scott et al. (1997), 101: Geppert et al. (2005), 102: Adams et al. (1978), 103: Smith et al. (2002), 104: Wagner-Redeker et al. (1985), 105: Glover et al. (2010) and 106: Warnatz (1984).

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