A chemistry and cooling module for the NIRVANA code

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Table A.1.

NC²M – gas-phase reactions.

No.	Reaction	Notes	Ref.
1	H + e⁻ → H⁺ + 2 e⁻		1
2	H⁺ + e⁻ → H	Case A	2
3	He + e⁻ → He⁺ + 2 e⁻		1
4^a	He⁺ + e⁻ → He	Case A	3,4
5	He⁺ + e⁻ → He²⁺ + 2 e⁻		1
6	He⁺ + e⁻ → He⁺	Case A	2
7	He⁺ + H → He + H⁺		5
8	He + H⁺ → He⁺ + H		6
9–14	Cⁿ⁺ + e⁻ → C^(n + 1)+ + 2 e⁻	n = 0…5	7
15–20^a	C^(n + 1)+ + e⁻ → Cⁿ⁺	n = 0…5	8
21–24	C^(n + 1)+ + H → Cⁿ⁺ + H⁺	n = 0…3	9
25	C + H⁺ → C⁺ + H		9
26,27	C^(n + 1)+ + He → Cⁿ⁺ + He⁺	n = 2, 3	9
28–34	Nⁿ⁺ + e⁻ → N^(n + 1)+ + 2 e⁻	n = 0…6	7
35–41^a	N^(n + 1)+ + e⁻ → Nⁿ⁺	n = 0…6	8
42–45	N^(n + 1)+ + H → Nⁿ⁺ + H⁺	n = 0…3	9
46	N + H⁺ → N⁺ + H		9
47–49	N^(n + 1)+ + He → Nⁿ⁺ + He⁺	n = 1…3	9
50–57	Oⁿ⁺ + e⁻ → O^(n + 1)+ + 2 e⁻	n = 0…7	7
58–65^a	O^(n + 1)+ + e⁻ → Oⁿ⁺	n = 0…7	8
66–69	O^(n + 1)+ + H → Oⁿ⁺ + H⁺	n = 0…3	9
70	O + H⁺ → O⁺ + H		9
71–73	O^(n + 1)+ + He → Oⁿ⁺ + He⁺	n = 1…3	9
74–83	Neⁿ⁺ + e⁻ → Ne^(n + 1)+ + 2 e⁻	n = 0…9	7
84–93^a	Ne^(n + 1)+ + e⁻ → Neⁿ⁺	n = 0…9	8
94–96	Ne^(n + 1)+ + H → Neⁿ⁺ + H⁺	n = 1…3	9
97–99	Ne^(n + 1)+ + He → Neⁿ⁺ + He⁺	n = 1…3	9
100–111	Mgⁿ⁺ + e⁻ → Mg^(n + 1)+ + 2 e⁻	n = 0…11	7
112–123^a	Mg^(n + 1)+ + e⁻ → Mgⁿ⁺	n = 0…11	8
124–126	Mg^(n + 1)+ + H → Mgⁿ⁺ + H⁺	n = 1…3	9
127,128	Mgⁿ⁺ + H⁺ → Mg^(n + 1)+ + H	n = 0, 1	9
129,130	Mg^(n + 1)+ + He → Mgⁿ⁺ + He⁺	n = 2, 3	9
131–144	Siⁿ⁺ + e⁻ → Si^(n + 1)+ + 2 e⁻	n = 0…13	7
145–158^a	Si^(n + 1)+ + e⁻ → Siⁿ⁺	n = 0…13	8
159–161	Si^(n + 1)+ + H → Siⁿ⁺ + H⁺	n = 1…3	9
162,163	Siⁿ⁺ + H⁺ → Si^(n + 1)+ + H	n = 0, 1	9
164,165	Si^(n + 1)+ + He → Siⁿ⁺ + He⁺	n = 2, 3	9
166	Si + He⁺ → Si⁺ + He		9
167–192	Feⁿ⁺ + e⁻ → Fe^(n + 1)+ + 2 e⁻	n = 0…25	7
193–218^a	Fe^(n + 1)+ + e⁻ → Feⁿ⁺	n = 0…25	8,10,11
219–221	Fe^(n + 1)+ + H → Feⁿ⁺ + H⁺	n = 1…3	9
222,223	Feⁿ⁺ + H⁺ → Fe^(n + 1)+ + H	n = 0, 1	9
224,225	Fe^(n + 1)+ + He → Feⁿ⁺ + He⁺	n = 2, 3	9
300	H + e⁻ → H⁻		12
301	H⁻ + H → H₂ + e⁻		13
302	H + H⁺ →		14
303	H + → H₂ + H⁺		15
304	H⁺ + H₂ → + H		16
305	H₂ + e⁻ → 2 H + e⁻		17
306	H₂ + H → 3 H		18,19
307	H⁻ + e⁻ → H + 2 e⁻		1
308	H⁻ + H → 2 H + e⁻		1
309	H⁻ + H⁺ → 2 H		20
310	H⁻ + H⁺ → + e⁻		21
311	+ e⁻ → 2 H		22
312	+ H⁻ → H + H₂		23
313	3 H → H₂ + H		24,25
314	2 H + H₂ → 2 H₂		26
315	2 H₂ → H₂ + 2 H		27,28
316	He⁺ + H⁻ → He + H		29
317	2 H + He → H₂ + He		30
318	H₂ + He → 2 H + He		31
319	H₂ + He⁺ → + He		32
320	H₂ + He⁺ → H⁺ + H + He		32
321	H₂ + H⁺ →		33
322	+ e⁻ → H₂ + H		34
323	+ e⁻ → 3 H		34
324	+ H₂ → + H		35
325	+ H → + H₂		36
326	+ H⁻ → 3 H		23
327	H₂ + e⁻ → H + H⁻		37
328	He + H⁻ → He + H + e⁻		38
350	D + e⁻ → D⁺ + 2 e⁻		1
351	D⁺ + e⁻ → D		2
352	D + He⁺ → D⁺ + He		5
353	D⁺ + He → D + He⁺		6
354	D⁺ + H → D + H⁺		39
355	D + H⁺ → D⁺ + H		39
356	D⁺ + H₂ → HD + H⁺		40
357	HD + H⁺ → H₂ + D⁺		40
358	H₂ + D → HD + H		41,42
359	HD + H → D + H₂		43
400	C⁻ + H⁺ → C + H		29
401	C⁻ + H → CH + e⁻		29
402	C⁻ + H₂ → CH₂ + e⁻		29
403	C⁻ + O → CO + e⁻		29
404	O⁻ + H⁺ → O + H		29
405	O⁻ + H → OH + e⁻		29
406	O⁻ + H₂ → H₂O + e⁻		29
407	O⁻ + C → CO + e⁻		29
408	C + e⁻ → C⁻		44
409	C + H⁻ → CH + e⁻		29
410	C + H → CH		45
411	C + H₂ → CH₂		45
412	C + H₂ → CH + H		46
413	C + → CH⁺ + H		29
414	C + → CH⁺ + H₂		29
415	2 C → C₂		47
416	C + O → CO		48,49
417	C⁺ + H → CH⁺		50
418	C⁺ + H₂ → CH⁺ + H		51
419	C⁺ + H₂ → C		29
420	C⁺ + O → CO⁺		48
421	O + e⁻ → O⁻		29
422	O + H⁻ → OH + e⁻		29
423	O + H → OH		29
424	O + H₂ → OH + H		52
425	O + → OH⁺ + H		29
426	O + → OH⁺ + H₂		53
427	2 O → O₂		45
428	O⁺ + H₂ → OH⁺ + H		54,55
429	C₂ + He⁺ → C⁺ + C + He		29
430	C₂ + O → CO + C		56,57
431	C₂ + O⁺ → CO⁺ + C		29
432	O₂ + H → OH + O		29
433	O₂ + H⁺ → + H		58
434	O₂ + He⁺ → + He		59,60
435	O₂ + He⁺ → O⁺ +O + He		59,60
436	O₂ + H₂ → 2 OH		61
437	O₂ + C → CO + O		62
438	O₂ + C⁺ → CO + O⁺		63,64
439	O₂ + C⁺ → CO⁺ + O		63,64
440	O₂ + → HCO⁺ + OH		63,64
441	+ e⁻ → 2 O		65
442	+ C → O₂ + C⁺		29
443	+ C → CO⁺ + O		29
444	CH + H → C + H₂		66
445	CH + H₂ → CH₂ + H		29
446	CH + C → C₂ + H		62
447	CH + O → CO + H		67,68
448	CH + O → HCO⁺ + e⁻		69
449	CH + H⁺ → CH⁺ + H		29
450	CH⁺ + e⁻ → C + H		70
451	CH⁺ + H → C⁺ + H₂		71
452	CH⁺ + H₂ → C + H		71
453	CH⁺ + O → CO⁺ + H		72
454	CH₂ + H → CH + H₂		29
455	CH₂ + O → CO + 2 H		73
456	CH₂ + O → CO + H₂		29
457	CH₂ + H⁺ → CH⁺ + H₂		29
458	CH₂ + H⁺ → C + H		29
459	CH₂ + He⁺ → C⁺ + H₂ + He		29
460	C + e⁻ → CH + H		74
461	C + e⁻ → C + 2 H		74
462	C + e⁻ → C + H₂		74
463	C + H → CH⁺ + H₂		29
464	C + H₂ → C + H		63,64
465	C + O → HCO⁺ + H		45
466	C + e⁻ → CH₂ + H		75
467	C + e⁻ → CH + H₂		75
468	C + e⁻ → CH + 2 H		29
469	C + H → C + H₂		29
470	C + O → HCO⁺ + H₂		76
471	OH + H⁻ → H₂O + e⁻		29
472	OH + H → O + 2 H		29
473	OH + H → H₂O		77
474	OH + H → O + H₂		78
475	OH + H₂ → H₂O + H		79
476	OH + C → CO + H		62
477	OH + O → O₂ + H		29
478	2 OH → O + H₂O		62
479	OH + H⁺ → OH⁺ + H		29
480	OH + He⁺ → O⁺ + H +He		29
481	OH + → H₂O⁺ + H₂		29
482	OH + C⁺ → CO⁺ + H		80
483	OH + C⁺ → CO + H⁺		80
484	OH⁺ + e⁻ → O + H		81
485	OH⁺ + H₂ → H₂O⁺ + H		82
486	H₂O + H → OH + H₂		83
487	H₂O + H⁺ → H₂O⁺ + H		58
488	H₂O + He⁺ → OH + H⁺ + He		84,85
489	H₂O + He⁺ → OH⁺ + H + He		84,85
490	H₂O + He⁺ → H₂O⁺ + He		84,85
491	H₂O + → H₃O⁺ + H₂		86,87
492	H₂O + C⁺ → HCO⁺ + H		88,89
493	H₂O + C⁺ → HOC⁺ + H		90
494	H₂O⁺ + e⁻ → O + 2 H		91
495	H₂O⁺ + e⁻ → O + H₂		91
496	H₂O⁺ + e⁻ → OH + H		91
497	H₂O⁺ + H₂ → H₃O⁺ + H		92
498	H₃O⁺ + e⁻ → H₂O + H		93
499	H₃O⁺ + e⁻ → OH + H₂		93
500	H₃O⁺ + e⁻ → OH + 2 H		93
501	H₃O⁺ + e⁻ → O + H +H₂		94
502	H₃O⁺ + C → HCO⁺ + H₂		45
503	CO + H → C + OH		95
504	CO + → HOC⁺ + H₂		96
505	CO + → HCO⁺ + H₂		96
506	CO + He⁺ → C⁺ + O + He		97
507	CO + He⁺ → O⁺ + C + He		97
508	CO⁺ + e⁻ → C + O		98
509	CO⁺ + H → CO + H⁺		99
510	CO⁺ + H₂ → HCO⁺ + H		100
511	CO⁺ + H₂ → HOC⁺ + H		100
512	HCO⁺ + e⁻ → OH + C		101
513	HCO⁺ + e⁻ → CO + H		101
514	HCO⁺ + C → CO + CH⁺		45
515	HCO⁺ + H₂O → CO + H₃O⁺		102
516	HOC⁺ + e⁻ → CO + H		29
517	HOC⁺ + H₂ → HCO⁺ + H₂		103
518	HOC⁺ + CO → HCO⁺ + CO		104
519	2 C + He → C₂ + He		105
520	2 O + He → O₂ + He		106
521	C + O + He → CO + He		97
522	C⁺ + O + He → CO⁺ + He		97
523	O⁺ + C + He → CO⁺ + He		97
524	O + H + He → OH + He		78
525	OH + H + He → H₂O + He		67

Notes.

^(a)

Both RR and DR. References. 1:Janev et al. (1987), 2: Ferland et al. (1992), 3: Hummer & Storey (1998), 4: Aldrovandi & Pequignot (1973), 5: Zygelman et al. (1989), 6: Kimura et al. (1993), 7: Voronov (1997), 8: Badnell (2006), 9: Stancil et al. (2015), 10: Shull & van Steenberg (1982), 11: Arnaud & Raymond (1992), 12: Wishart (1979), 13: Bruhns et al. (2010), 14: Ramaker & Peek (1976), 15: Karpas et al. (1979), 16: Savin et al. (2004), 17: Trevisan & Tennyson (2002), 18: MacLow & Shull (1986), 19: Lepp & Shull (1983), 20: Croft et al. (1999), 21: Poulaert et al. (1978), 22: Schneider et al. (1994), 23: Dalgarno & Lepp (1987), 24: Orel (1987), 25: Abel et al. (2002), 26: Cohen & Westberg (1983), 27: Martin et al. (1998), 28: Shapiro & Kang (1987), 29: McElroy et al. (2013), 30: Walkauskas & Kaufman (1975), 31: Dove et al. (1987), 32: Barlow (1984), 33: Gerlich & Horning (1992), 34: Woodall et al. (2007), 35: Linder et al. (1995), 36: Sidhu et al. (1992), 37: Schulz & Asundi (1967), 38: Huq et al. (1982), 39: Savin (2002), 40: Gerlich (1982), 41: Mielke et al. (2003), 42: Glover & Abel (2008), 43: Shavitt (1959), 44: Stancil & Dalgarno (1998), 45: Prasad & Huntress (1980), 46: Dean et al. (1991), 47: Andreazza & Singh (1997), 48: Dalgarno et al. (1990), 49: Singh et al. (1999), 50: Barinovs & van Hemert (2006), 51: Adams et al. (1984), 52: Natarajan & Roth (1987), 53: Milligan & McEwan (2000), 54: Smith et al. (1978), 55: Adams et al. (1980), 56: Mitchell & Deveau (1983), 57: Fairbairn (1969), 58: Smith et al. (1992), 59: Adams & Smith (1976a), 60: Adams & Smith (1976b), 61: Azatyan et al. (1975), 62: Smith et al. (2004), 63: Smith & Adams (1977a), 64: Smith & Adams (1977b), 65: Alge et al. (1983), 66: Harding et al. (1993), 67: Baulch et al. (1992), 68: Murrell & Rodriguez (1986), 69: MacGregor & Berry (1973), 70: Takagi et al. (1991), 71: McEwan et al. (1999), 72: Viggiano et al. (1980), 73: Frank (1986), 74: Larson et al. (1998), 75: Mitchell (1990), 76: Fehsenfeld (1976), 77: Field et al. (1980), 78: Tsang & Hampson (1986), 79: Oldenborg et al. (1992), 80: Dubernet et al. (1992), 81: Guberman (1995), 82: Jones et al. (1981), 83: Cohen & Westberg (1979), 84: Mauclaire et al. (1978a), 85: Mauclaire et al. (1978b), 86: Kim et al. (1974), 87: Anicich et al. (1975), 88: Anicich et al. (1976), 89: Watson et al. (1976), 90: Martinez et al. (2008), 91: Rosén et al. (2000), 92: Raksit & Warneck (1980), 93: Novotny et al. (2010), 94: Jensen et al. (2000), 95: Mitchell (1984), 96: Klippenstein & Georgievskii (2010), 97: Petuchowski et al. (1989), 98: Rosén et al. (1998), 99: Federer et al. (1984), 100: Scott et al. (1997), 101: Geppert et al. (2005), 102: Adams et al. (1978), 103: Smith et al. (2002), 104: Wagner-Redeker et al. (1985), 105: Glover et al. (2010) and 106: Warnatz (1984).

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