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Fig. 5

image

Modelling results of the desorption rates (ML s−1) and the desorption energy distribution (K) of formamide on graphite (HOPG) surface. Top panel: red crosses indicate TPD data of NH2CHO (mz = 45) on HOPG surface for different exposure doses of 0.14, 0.30, 0.61, and 1.0 ML; blue lines: the best fits of the TPD curves of NH2CHO from the HOPG surface, calculated with the pre-exponential factor A = 1018 s−1 are shown. Bottom panel: the surface population (ML) of NH2CHO on HOPG surface as a function of the desorption energy (K) is shown. The desorption energy distribution (Ei) and the surface population (Ni) of formamide are derived from Eq. (5) with the best pre-exponential factor A = 1018 s−1 for the exposure dose .

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