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Table A.4

Equilibrium constants Ke, partition function factors Fq, and rate coefficients kf,kr (in 10-10 cm3 s-1) for the reactions of H/DCO+ with CO involving the isotope 17O.

Reaction T/K 5 10 20 40 60 80 100 200 300
F7 Fq 0.9981 0.9974 0.9971 0.9970 0.9969 0.9969 0.9969 0.9969 0.9970
Ke 1.97 1.40 1.18 1.09 1.05 1.04 1.03 1.01 1.01
(kf,kr) (6.36, 3.24) (5.37, 3.83) (4.87, 4.13) (4.48, 4.12) (4.21, 3.99) (3.98, 3.82) (3.81, 3.69) (3.12, 3.08) (2.61, 2.59)
F8 Fq 0.9981 0.9974 0.9971 0.9969 0.9969 0.9969 0.9969 0.9969 0.9970
Ke 1.97 1.40 1.18 1.09 1.06 1.04 1.03 1.01 1.01
(kf,kr) (6.37, 3.23) (5.37, 3.83) (4.88, 4.12) (4.48, 4.12) (4.21, 3.99) (3.98, 3.82) (3.81, 3.69) (3.12, 3.08) (2.61, 2.59)
F9 Fq 0.9983 0.9977 0.9974 0.9973 0.9972 0.9972 0.9972 0.9972 0.9973
Ke 1.82 1.35 1.16 1.08 1.05 1.04 1.03 1.01 1.01
(kf,kr) (6.20, 3.40) (5.28, 3.92) (4.83, 4.17) (4.46, 4.14) (4.20, 4.00) (3.97, 3.83) (3.80, 3.70) (3.12, 3.08) (2.61, 2.59)
F10 Fq 0.9982 0.9977 0.9974 0.9973 0.9972 0.9972 0.9972 0.9972 0.9973
Ke 1.83 1.35 1.16 1.08 1.05 1.04 1.03 1.01 1.01
(kf,kr) (6.21, 3.39) (5.29, 3.91) (4.84, 4.16) (4.46, 4.14) (4.20, 4.00) (3.97, 3.83) (3.80, 3.70) (3.12, 3.08) (2.61, 2.59)
F11 F q 0.9835 0.9806 0.9793 0.9786 0.9784 0.9783 0.9782 0.9784 0.9795
K e 68.17 8.16 2.83 1.66 1.39 1.27 1.21 1.09 1.05
(kf,kr) (9.46, 0.14) (8.20, 1.00) (6.65, 2.35) (5.37, 3.23) (4.77, 3.43) (4.37, 3.43) (4.10, 3.40) (3.23, 2.97) (2.66, 2.54)
F12 F q 0.9854 0.9832 0.9821 0.9816 0.9814 0.9813 0.9813 0.9815 0.9824
K e 34.67 5.83 2.39 1.53 1.32 1.23 1.17 1.07 1.04
(kf,kr) (9.33, 0.27) (7.85, 1.35) (6.35, 2.65) (5.20, 3.40) (4.67, 3.53) (4.30, 3.50) (4.05, 3.45) (3.21, 2.99) (2.65, 2.55)
F13 F q 0.9870 0.9854 0.9847 0.9843 0.9841 0.9841 0.9840 0.9842 0.9851
K e 19.03 4.33 2.06 1.42 1.26 1.18 1.14 1.06 1.03
(kf,kr) (9.12, 0.48) (7.47, 1.73) (6.06, 2.94) (5.05, 3.55) (4.57, 3.63) (4.23, 3.57) (4.00, 3.50) (3.19, 3.01) (2.64, 2.56)
F14 F q 0.9873 0.9857 0.9850 0.9846 0.9845 0.9844 0.9844 0.9845 0.9854
K e 17.57 4.16 2.02 1.41 1.25 1.18 1.14 1.06 1.03
(kf,kr) (9.08, 0.52) (7.42, 1.78) (6.02, 2.98) (5.03, 3.57) (4.56, 3.64) (4.22, 3.58) (3.99, 3.51) (3.19, 3.01) (2.64, 2.56)
F15 F q 0.9836 0.9809 0.9795 0.9789 0.9787 0.9786 0.9785 0.9787 0.9798
K e 63.58 7.89 2.78 1.65 1.39 1.27 1.21 1.09 1.05
(kf,kr) (9.45, 0.15) (8.16, 1.04) (6.62, 2.38) (5.35, 3.25) (4.76, 3.44) (4.36, 3.44) (4.10, 3.40) (3.23, 2.97) (2.66, 2.54)
F7(D) F q 0.9969 0.9958 0.9953 0.9950 0.9950 0.9949 0.9949 0.9950 0.9953
K e 2.25 1.50 1.22 1.10 1.06 1.05 1.04 1.02 1.01
(kf,kr) (6.65, 2.95) (5.52, 3.68) (4.95, 4.05) (4.51, 4.09) (4.23, 3.97) (3.99, 3.81) (3.82, 3.68) (3.12, 3.08) (2.61, 2.59)
F8(D) F q 0.9968 0.9957 0.9952 0.9950 0.9949 0.9949 0.9948 0.9950 0.9953
K e 2.26 1.50 1.22 1.10 1.07 1.05 1.04 1.02 1.01
(kf,kr) (6.65, 2.95) (5.52, 3.68) (4.95, 4.05) (4.51, 4.09) (4.23, 3.97) (3.99, 3.81) (3.82, 3.68) (3.12, 3.08) (2.61, 2.59)
F9(D) F q 0.9971 0.9962 0.9957 0.9955 0.9955 0.9954 0.9954 0.9955 0.9958
K e 2.06 1.43 1.19 1.09 1.06 1.04 1.03 1.01 1.01
(kf,kr) (6.46, 3.14) (5.42, 3.78) (4.90, 4.10) (4.49, 4.11) (4.21, 3.99) (3.98, 3.82) (3.81, 3.69) (3.12, 3.08) (2.61, 2.59)
F10(D) F q 0.9970 0.9961 0.9957 0.9955 0.9954 0.9954 0.9954 0.9955 0.9958
K e 2.07 1.44 1.20 1.09 1.06 1.04 1.03 1.01 1.01
(kf,kr) (6.48, 3.12) (5.42, 3.78) (4.90, 4.10) (4.49, 4.11) (4.22, 3.98) (3.98, 3.82) (3.81, 3.69) (3.12, 3.08) (2.61, 2.59)
F11(D) F q 0.9733 0.9691 0.9671 0.9661 0.9658 0.9657 0.9656 0.9667 0.9692
K e 168.50 12.75 3.51 1.84 1.48 1.33 1.25 1.10 1.06
(kf,kr) (9.54, 0.06) (8.53, 0.67) (7.00, 2.00) (5.57, 3.03) (4.90, 3.30) (4.46, 3.34) (4.17, 3.33) (3.25, 2.95) (2.67, 2.53)
F12(D) F q 0.9763 0.9732 0.9717 0.9710 0.9707 0.9706 0.9706 0.9715 0.9738
K e 74.76 8.52 2.87 1.67 1.39 1.27 1.21 1.08 1.05
(kf,kr) (9.47, 0.13) (8.23, 0.97) (6.68, 2.32) (5.38, 3.22) (4.77, 3.43) (4.37, 3.43) (4.10, 3.40) (3.22, 2.98) (2.66, 2.54)
F13(D) F q 0.9791 0.9769 0.9759 0.9753 0.9752 0.9751 0.9750 0.9759 0.9779
K e 36.27 5.95 2.41 1.53 1.32 1.22 1.17 1.07 1.04
(kf,kr) (9.34, 0.26) (7.88, 1.32) (6.36, 2.64) (5.20, 3.40) (4.66, 3.54) (4.29, 3.51) (4.04, 3.46) (3.20, 3.00) (2.65, 2.55)
F14(D) F q 0.9795 0.9774 0.9764 0.9759 0.9757 0.9756 0.9756 0.9764 0.9784
K e 33.10 5.68 2.35 1.52 1.31 1.22 1.16 1.07 1.04
(kf,kr) (9.32, 0.28) (7.82, 1.38) (6.32, 2.68) (5.18, 3.42) (4.65, 3.55) (4.28, 3.52) (4.03, 3.47) (3.20, 3.00) (2.65, 2.55)
F15(D) F q 0.9734 0.9694 0.9675 0.9666 0.9663 0.9661 0.9661 0.9671 0.9697
K e 154.91 12.23 3.44 1.82 1.47 1.33 1.24 1.10 1.06
(kf,kr) (9.54, 0.06) (8.50, 0.70) (6.97, 2.03) (5.55, 3.05) (4.89, 3.31) (4.45, 3.35) (4.16, 3.34) (3.24, 2.96) (2.67, 2.53)

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