Table A.1
Presentation of experimental log (gf) values together with the transition, wavelength, λ, wavenumber, σ, branching fraction, BF, the transition probability, Aul, and the corresponding theoretical log (gf) values of this work.
Transition | λ | σ | BF | BF Unc. | A ul | log(gf) | log(gf) |
(Å) | (cm-1) | % | (s-1) | Exp. | Calc. | ||
|
|||||||
3p 3P![]() |
5167.321 | 19 346.997 | 0.1121 | 7 | 9.75 × 106 | –0.854 ± 0.05 | –0.865 |
3p 3P![]() |
5172.684 | 19 326.939 | 0.3471 | 3 | 3.02 × 107 | –0.363 ± 0.04 | –0.387 |
3p 3P![]() |
5183.604 | 19 286.225 | 0.5408 | 1 | 4.70 × 107 | –0.168 ± 0.04 | –0.166 |
Residual | <10-4 | ||||||
τ = 9.6∗ ns | |||||||
3p 1P![]() |
11 828.185 | 8452.08 | 1 | 0 | 2.13 × 107 | –0.350 ± 0.03 | –0.343 |
Residual | <10-4 | ||||||
τ = 47 ns | |||||||
3p 1P![]() |
8806.756 | 11 351.800 | 1 | 0 | 1.23 × 107 | –0.144 ± 0.03 | –0.128 |
Residual | <10-4 | ||||||
τ = 81 ns | |||||||
4s 3S1–4p 3P![]() |
15 047.705 | 6643.71 | 1 | 0 | 1.27 × 107 | –0.364 ± 0.04 | –0.360 |
τ = 78.5∗ ns | |||||||
4s 3S1–4p 3P![]() |
15 040.246 | 6647.01 | 1 | 0 | 1.27 × 107 | 0.113 ± 0.04 | 0.117 |
Residual | <10-4 | ||||||
τ = 78.5∗ ns | |||||||
4s 3S1–4p 3P![]() |
15 024.992 | 6653.76 | 1 | 0 | 1.27 × 107 | 0.334 ± 0.03 | 0.339 |
τ = 78.5∗ ns | |||||||
3p 1P![]() |
5711.088 | 17 504.942 | 0.2942 | 10 | 2.94 × 106 | –1.842 ± 0.05 | –1.742 |
4p 1P![]() |
31 157.72vac | 3209.447 | 0.7057 | 1 | 7.06 × 106 | 0.012 ± 0.02 | –0.052 |
Residual | <10-4 | ||||||
τ = 100 ns | |||||||
3p 1P![]() |
5528.405 | 18 083.378 | 0.7060 | 3 | 1.24 × 107 | –0.547 ± 0.02 | –0.513 |
4p 1P![]() |
26 399.76vac | 3787.88 | 0.2938 | 7 | 5.16 × 106 | 0.430 ± 0.04 | 0.444 |
Residual | 0.0001 | ||||||
τ = 57 ns | |||||||
4s 3S1–5p 3P![]() |
7659.901 | 13 051.405 | 0.3424 | 9 | 1.28 × 106 | –1.948 ± 0.05 | –1.986 |
3d 3D1 | 15 889.485 | 6291.74 | 0.0939 | 17 | 3.51 × 105 | –1.876 ± 0.08 | –1.817 |
5s 3S1 | 42 082.53vac | 2376.305 | 0.5636 | 5 | 2.11 × 106 | -0.252 ± 0.05 | –0.236 |
Residual | <10-4 | ||||||
τ = 267.6∗ ns | |||||||
4s 3S1–5p 3P![]() |
7659.152 | 13 052.683 | 0.3810 | 9 | 1.42 × 106 | –1.425 ± 0.05 | –1.509 |
3d 3D2 | 15 886.183 | 6293.06 | 0.0300 | 24 | 1.12 × 105 | –1.896 ± 0.10 | –1.465 |
3d 3D1 | 15 886.261 | 6293.028 | 0.0410 | 38 | 1.53 × 105 | –1.760 ± 0.14 | –1.942 |
5s 3S1 | 42 059.93vac | 2377.595 | 0.5480 | 6 | 2.05 × 106 | 0.212 ± 0.05 | 0.241 |
Residual | 0.0001 | ||||||
τ = 267.6∗ ns | |||||||
4s 3S1–5p 3P![]() |
7657.603 | 13 055.323 | 0.3105 | 8 | 1.16 × 106 | –1.292 ± 0.05 | –1.287 |
3d 3D3 | 15 879.567 | 6295.68 | 0.0669 | 11 | 2.50 × 105 | –1.326 ± 0.06 | –1.194 |
5s 3S1 | 42 013.28vac | 2380.236 | 0.5995 | 4 | 2.24 × 106 | 0.472 ± 0.04 | 0.463 |
Residual | 0.0231 | ||||||
τ = 267.6∗ ns | |||||||
3d 1D2–4f 1F![]() |
12 083.662 | 8273.38 | 0.9505 | 1 | 1.55 × 107 | 0.377 ± 0.04 | 0.368 |
3d 3D2 | 14 878.191 | 6719.42 | 0.0158 | 8 | 2.58 × 105 | –1.223 ± 0.05 | –1.211 |
Residual | 0.0337 | ||||||
τ = 61.2∗ ns | |||||||
3d 3D1–4f 3F![]() |
14 877.752 | 6719.60 | 0.8388 | 0.03 | 6.126 × 108 | 0.357 ± 0.04 | 0.371 |
Residual | 0.1612 | ||||||
τ = 61.2∗ ns | |||||||
3d 1D2–4f 3F![]() |
12 083.278 | 8273.64 | 0.0180 | 8 | 2.94 × 105 | –1.347 ± 0.05 | –1.376 |
3d 3D2 | 14 877.608 | 6719.67 | 0.8699 | 1 | 1.42 × 107 | 0.518 ± 0.04 | 0.534 |
Residual | 0.1121 | ||||||
τ = 61.2∗ ns | |||||||
3d 3D3–4f 3F![]() |
14 877.529 | 6719.71 | 0.9987 | 3 | 1.63 × 107 | 0.688 ± 0.04 | 0.702 |
Residual | 0.0013 | ||||||
τ = 61.2∗ ns | |||||||
3d 1D2–5f 1F![]() |
9255.778 | 10 801.098 | 0.8724 | 1 | 7.22 × 106 | –0.187 ± 0.04 | – |
4d 1D2 | 24 572.92vac | 4069.51 | 0.0776 | 10 | 6.42 × 105 | –0.391 ± 0.06 | – |
Residual | 0.0501 | ||||||
τ = 120.7∗ ns | |||||||
3d 3D1–5f 3F![]() |
10 811.158 | 9247.170 | 0.6499 | 2 | 5.45 × 106 | -0.321 ± 0.04 | – |
4d 3D1 | 33 201.71vac | 3011.893 | 0.1891 | 8 | 1.58 × 106 | 0.117 ± 0.05 | – |
Residual | 0.1610 | ||||||
τ = 119.4∗ ns | |||||||
3d 3D3–5f 3F![]() |
10 811.053 | 9247.260 | 0.8524 | 1 | 7.14 × 106 | 0.052 ± 0.04 | – |
4d 3D3 | 33 199.99vac | 3012.049 | 0.1465 | 7 | 1.23 × 106 | 0.261 ± 0.05 | – |
Residual | 0.0011 | ||||||
τ = 119.4∗ ns |
Notes. The radiative lifetimes are from Jönsson et al. (1984) where available or from our calculations (marked with ∗). For 2000 Å <λ< 20 000 Å, the wavelength is given in vacuum, otherwise in air.
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