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Table 2

New bands observed during the VUV photolysis of solid H2CO at 13 K.

ν (cm-1) Mode A Molecule Ref
12C 13C (cm molec-1)

2343 2275 ν(CO) 7.6 × 10-17 CO2 a
2136 2087 ν(CO) 1.1 × 10-17 CO b
1846 1804 ν(C = O) 2.1 × 10-17 HCO c
1751 1721 ν(C = O) 2.6 × 10-17 GA d
1217 1205 ?? POM e
1109 1095 ν(CO) 9.7 × 10-18 POM e
1075 1058 ν(CO) 3.9 × 10-18 EG d
1046 xx ν(CO) 3.9 × 10-18 EG d
1027 1006 ν(CO) 1.8 × 10-17 CH3OH f
991 970 ν(CO) POM e
945 919 ν(CO) 3.0 × 10-17g POM e
912 887 ν(CO) 3.0 × 10-17g POM e

Notes. ν: stretching; δ: bending; ρ: rocking; ω: wagging.

(g)

since the lengths of the polymer chains are unknown, the strengths of the indicated bands are given per carbon atom (Schutte et al. 1993).

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