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Table A.8

Comparison between available experimental and calculated energy levels in Kr vii. Energies are given in cm-1.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.0 0 0 0 98 4s21S
274 931.7 274 895 36 0 96 4p23P
279 414.5 279 463 −49 1 100 4p23P
279 714.8 279 726 −12 2 58 4p21D + 32 4p23P + 10 4s4d 1D
288 190.2 288 165 26 2 68 4p23P + 27 4p21D + 5 4s4d 1D
321 794.0 321 795 −1 0 93 4p21S
349 973.1 349 973 0 1 100 4s4d 3D
350 416.8 350 420 −3 2 100 4s4d 3D
351 116.2 351 113 3 3 100 4s4d 3D
379 488.3 379 488 0 2 83 4s4d 1D + 14 4p21D
438 644.0 438 644 0 1 99 4s5s 3S
447 769.0 447 769 0 0 98 4s5s 1S
578 470.0 578 470 0 1 98 4s5d 3D
578 722.0 578 722 0 2 97 4s5d 3D
579 109.0 579 109 0 3 98 4s5d 3D
581 038.0 581 038 0 2 95 4s5d 1D
616 314.0 616 314 0 1 99 4s6s 3S
618 693.0 618 693 0 0 97 4s6s 1S
663 983.0 664 168 −185 4 39 4p4f 3F + 25 4p4f 3G + 24 4p4f 1G
664 923.0 665 371 −448 2 85 4p4f 3F + 9 4d23F
664 997.0 664 462 535 3 51 4p4f 3G + 31 4p4f 3F + 14 4p4f 1F
671 378.0 670 779 599 4 44 4p4f 3F + 34 4p4f 1G + 15 4d21G
671 908.0 672 123 −215 3 45 4p4f 3G + 35 4p4f 1F + 18 4p4f 3F
680 086.0 680 437 −351 3 89 4p4f 3D
681 681.0 681 474 207 2 70 4p4f 3D + 18 4p4f 1D
684 070.0 683 922 148 1 99 4p4f 3D
684 941.0 685 206 −265 2 55 4p4f 1D + 26 4p4f 3D + 17 4d21D
694 858.0 694 912 −54 1 99 4s6d 3D
695 015.0 695 051 −36 3 99 4s6d 3D
695 056.0 694 966 90 2 99 4s6d 3D
697 330.0 697 328 2 2 94 4s6d 1D
Odd parity
117 389.6 117 398 −8 0 100 4s4p 3P
120 094.8 120 083 12 1 99 4s4p 3P
126 553.8 126 556 −3 2 100 4s4p 3P
170 835.0 170 834 1 1 97 4s4p 1P
475 890.0 475 834 56 2 87 4p4d 3F + 6 4p4d 1D + 6 4s4f 3F
479 655.0 479 534 121 3 91 4p4d 3F + 7 4s4f 3F
484 543.0 484 405 138 4 91 4p4d 3F + 9 4s4f 3F
487 650.0 487 948 −298 2 87 4p4d 1D + 5 4p4d 3P + 5 4p4d 3F
492 776.0 492 750 26 0 97 4s5p 3P
493 219.0 493 247 −28 1 86 4s5p 3P + 10 4s5p 1P
495 578.4 495 560 18 2 90 4s5p 3P + 7 4p4d 3P
497 395.0 497 387 8 1 83 4s5p 1P + 8 4s5p 3P
501 542.0 501 700 −158 1 64 4p4d 3D + 28 4p4d 3P
501 769.0 501 895 −126 2 51 4p4d 3P + 35 4p4d 3D + 8 4s5p 3P
505 076.0 503 287 1789 3 44 4p4d 1F + 42 4s4f 1F + 13 4p4d 3D
506 933.0 506 924 9 0 97 4p4d 3P
507 446.0 507 507 −61 1 65 4p4d 3P + 33 4p4d 3D
507 934.0 508 016 −82 2 62 4p4d 3D + 36 4p4d 3P
508 473.0 508 317 156 3 86 4p4d 3D + 8 4s4f 1F + 6 4p4d 1F
530 349.0 530 256 93 2 93 4s4f 3F + 7 4p4d 3F
530 491.0 530 510 −19 3 92 4s4f 3F + 7 4p4d 3F
530 772.0 530 881 −109 4 91 4s4f 3F + 9 4p4d 3F
535 462.0 535 503 −41 1 94 4p4d 1P
560 671.0 562 201 −1530 3 50 4s4f 1F + 47 4p4d 1F
587 029.0 587 029 0 1 84 4p5s 3P + 14 4p5s 1P
594 617.0 594 617 0 2 99 4p5s 3P
598 281.0 598 281 0 1 79 4p5s 1P + 15 4p5s 3P
640 160.0 640 220 −60 0 100 4s6p 3P
640 761.0 640 686 75 1 97 4s6p 3P
642 010.0 642 022 −12 2 100 4s6p 3P
645 430.0 645 432 −2 1 93 4s6p 1P
656 725.0 656 803 −78 2 99 4s5f 3F
656 868.0 656 845 23 3 99 4s5f 3F
656 956.0 656 902 54 4 99 4s5f 3F
659 927.0 659 904 23 3 96 4s5f 1F
719 130.0 719 730 −600 3 54 4p5d 3F + 17 4p5d 3D + 11 4s6f 3F
724 826.0 725 290 −464 3 48 4s6f 1F + 21 4p5d 1F + 15 4s6f 3F
724 718.0 725 986 −1268 2 38 4p5d 3D + 33 4p5d 1D + 16 4s6f 3F
725 989.0 724 706 1283 4 52 4p5d 3F + 47 4s6f 3F

Notes.

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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