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Table A.6

Comparison between available experimental and calculated energy levels in Kr v. Energies are given in cm-1.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.0 −33 33 0 94 4p23P
3742.8 3782 −39 1 97 4p23P
7595.3 7630 −34 2 88 4p23P + 9 4p21D
19 722.9 19 722 1 2 88 4p21D + 9 4p23P
39 203.9 39 086 118 0 93 4p21S
278 654.0 276 953 1701 2 48 4p43P + 41 4s4p24d 3P
278 928.0 279 073 −145 1 54 4p5p 1P + 42 4p5p 3D
282 439.0 281 129 1310 1 45 4p43P + 42 4s4p24d 3P + 5 4p5p 3P
283 439.0 282 245 1194 0 42 4p43P + 39 4s4p24d 3P + 12 4p5p 3P
283 559.0 283 510 49 1 43 4p5p 3D + 26 4p5p 1P + 17 4p5p 3P
283 677.0 284 044 −367 2 85 4p5p 3D + 8 4p5p 3P
285 981.0 285 743 238 0 82 4p5p 3P + 7 4p4 3P + 5 4s4p24d 3P
288 683.0 288 408 275 1 67 4p5p 3P + 15 4p5p 1P + 11 4p5p 3D
289 297.0 288 809 488 2 55 4p41D + 28 4s4p24d 1D
289 998.0 289 534 464 3 98 4p5p 3D
291 138.0 290 937 201 2 81 4p5p 3P + 10 4p5p 3D
293 705.0 293 846 −141 1 88 4p5p 3S + 8 4p5p 3P
296 600.0 298 028 −1428 2 91 4p5p 1D + 6 4p5p 3P
307 667.0 306 878 789 0 91 4p5p 1S
313 479.1 316 178 −2699 2 98 4s4p24d 5P
318 440.7 317 049 1391 1 99 4s4p24d 5P
319 567.4 324 289 −4722 0 52 4p41S + 36 4s4p24d 1S
331 254.6 330 875 380 2 31 4p43P + 27 4s4p24d 3P + 22 4s4p24d 3P
356 571.8 354 502 2070 0 47 4s4p25s 3P + 30 4s4p24d 3P
Odd parity
129 658.2 129 841 −183 1 84 4s4p33D + 11 4p4d 3D
129 779.3 129 867 −88 2 82 4s4p33D + 10 4p4d 3D + 6 4s4p33P
131 016.4 131 249 −232 3 88 4s4p33D + 11 4p4d 3D
147 925.2 147 849 76 0 87 4s4p33P + 12 4p4d 3P
148 286.8 148 187 100 1 83 4s4p33P + 12 4p4d 3P
148 668.4 148 398 270 2 73 4s4p33P + 11 4p4d 3P + 5 4s4p33D
163 387.2 161 459 1928 2 55 4s4p31D + 35 4p4d 1D + 6 4s4p33P
185 063.5 184 939 124 1 72 4s4p33S + 22 4s4p31P
190 279.0 190 262 17 2 97 4p4d 3F
192 949.0 192 586 363 3 97 4p4d 3F
194 041.1 194 960 −919 1 64 4s4p31P + 24 4s4p33S + 10 4p4d 1P
211 336.6 211 924 −587 2 62 4p4d 3P + 15 4p4d 3D + 9 4s4p33P
213 932.8 213 854 79 1 50 4p4d 3P + 35 4p4d 3D + 7 4s4p33P
216 420.3 216 387 33 0 86 4p4d 3P + 12 4s4p33P
216 874.5 218 779 −1905 2 62 4p4d 3D + 14 4p4d 1D + 8 4s4p31D
218 746.8 218 251 496 1 50 4p4d 3D + 35 4p4d 3P + 7 4s4p33D
219 381.6 218 839 542 3 85 4p4d 3D + 10 4s4p33D
219 823.3 220 259 −436 2 41 4p4d 1D + 24 4s4p31D + 19 4p4d 3P
234 120.9 233 267 854 3 95 4p4d 1F
237 720.6 237 857 −136 1 45 4p5s 3P + 27 4p5s 1P + 22 4p4d 1P
238 526.0 238 229 297 0 97 4p5s 3P
240 926.0 241 845 −919 1 46 4p4d 1P + 42 4p5s 3P + 6 4s4p31P
246 798.0 246 644 154 2 97 4p5s 3P
250 993.0 250 921 72 1 69 4p5s 1P + 16 4p4d 1P + 11 4p5s 3P
344 908.0 344 800 108 2 76 4p5d 3F + 20 4p5d 1D
346 599.0 346 883 −284 3 74 4p5d 3F + 17 4p5d 3D + 8 4p5d 1F
346 920.0 346 966 −46 2 37 4p5d 3P + 31 4p5d 3D + 25 4p5d 1D
348 555.0 348 345 210 1 69 4p5d 3D + 19 4p5d 3P + 11 4p5d 1P
352 537.0 352 653 −116 2 50 4p5d 1D + 22 4p5d 3D + 17 4p5d 3F
353 957.0 353 722 235 3 75 4p5d 3D + 21 4p5d 3F
354 291.0 354 546 −255 2 52 4p5d 3P + 43 4p5d 3D
354 795.0 354 787 8 0 97 4p5d 3P
354 933.0 354 695 238 1 76 4p5d 3P + 22 4p5d 3D
358 656.0 358 908 −252 3 89 4p5d 1F + 6 4p5d 3D
358 703.0 358 899 −196 0 98 4p6s 3P
359 544.0 359 284 260 1 45 4p6s 3P + 36 4p5d 1P + 15 4p6s 1P
359 571.0 359 482 89 1 51 4p5d 1P + 29 4p6s 3P + 10 4p6s 1P
366 900.0 366 837 63 2 99 4p6s 3P
367 959.0 368 024 −65 1 75 4p6s 1P + 25 4p6s 3P

Notes.

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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