Table C.1
Small part of the line-list for DMS in the Far-Infrared Range.
| Upper state | Lower state | |||||||||||||||
| ν11, ν15 | J′ |
|
|
ν11, ν 15 a | J ′′ |
|
|
Freq. Obs.b | Freq. Cal.c | Obs.− Calc.d | E ′ e | E ′′ f | Sym.g | |||
| cm-1 | cm-1 | cm-1 | cm-1 | |||||||||||||
|
|
||||||||||||||||
| 01 | 4 | 3 | 2 | 00 | 3 | 2 | 2 | 187.2254(4) | 187.2241 | 0.0014 | 379.0095 | 191.7854 | AA | |||
| 01 | 18 | 3 | 15 | 00 | 17 | 2 | 15 | 195.1112(4) | 195.1122 | –0.0010 | 453.4215 | 258.3092 | AA | |||
| 01 | 21 | 3 | 18 | 00 | 20 | 2 | 18 | 197.2921(4) | 197.2925 | –0.0004 | 479.7745 | 282.4820 | AA | |||
| 01 | 19 | 4 | 15 | 00 | 18 | 3 | 15 | 195.1048(4) | 195.1034 | 0.0014 | 465.2528 | 270.1494 | AA | |||
| 01 | 11 | 3 | 9 | 00 | 10 | 2 | 9 | 190.9340(4) | 190.9324 | 0.0015 | 403.9876 | 213.0552 | AA | |||
| 01 | 15 | 2 | 14 | 00 | 16 | 3 | 14 | 172.6030(4) | 172.6034 | –0.0005 | 423.6603 | 251.0569 | AA | |||
| 01 | 14 | 2 | 13 | 00 | 15 | 3 | 13 | 173.3282(4) | 173.3285 | –0.0003 | 417.4880 | 244.1595 | AA | |||
| 01 | 23 | 3 | 20 | 00 | 24 | 4 | 20 | 167.3158(4) | 167.3175 | –0.0017 | 499.1823 | 331.8648 | AA | |||
| 01 | 10 | 5 | 5 | 00 | 11 | 6 | 5 | 174.5303(4) | 174.5311 | –0.0008 | 405.1221 | 230.5910 | AA | |||
| 01 | 6 | 5 | 1 | 00 | 7 | 6 | 1 | 176.3690(4) | 176.3708 | –0.0017 | 389.8637 | 213.4929 | AA | |||
| 01 | 13 | 5 | 8 | 00 | 12 | 4 | 8 | 192.3193(4) | 192.3208 | –0.0015 | 421.4556 | 229.1348 | AA | |||
| 01 | 8 | 4 | 5 | 00 | 9 | 5 | 5 | 176.1740(4) | 176.1727 | 0.0013 | 393.2615 | 217.0888 | AA | |||
| 01 | 4 | 4 | 1 | 00 | 5 | 5 | 1 | 178.0102(4) | 178.0101 | 0.0000 | 381.6092 | 203.5991 | AA | |||
| 01 | 13 | 4 | 10 | 00 | 12 | 3 | 10 | 192.2187(4) | 192.2180 | 0.0007 | 418.0421 | 225.8241 | AA | |||
| 01 | 9 | 2 | 8 | 00 | 10 | 3 | 8 | 176.6724(4) | 176.6719 | 0.0005 | 392.2997 | 215.6278 | AA | |||
| 01 | 7 | 5 | 2 | 00 | 6 | 4 | 2 | 190.0235(4) | 190.0232 | 0.0003 | 392.9944 | 202.9712 | AA | |||
| 01 | 9 | 5 | 4 | 00 | 8 | 4 | 4 | 190.8671(4) | 190.8671 | –0.0000 | 400.6202 | 209.7530 | AA | |||
| 01 | 25 | 2 | 23 | 00 | 24 | 1 | 23 | 200.3931(4) | 200.3928 | 0.0003 | 513.5741 | 313.1813 | AA | |||
| 01 | 14 | 4 | 11 | 00 | 13 | 3 | 11 | 192.7928(4) | 192.7919 | 0.0009 | 424.3296 | 231.5377 | AA | |||
| 01 | 21 | 2 | 19 | 00 | 22 | 3 | 19 | 168.5083(4) | 168.5082 | 0.0001 | 474.5946 | 306.0864 | AA | |||
| 01 | 14 | 2 | 12 | 00 | 15 | 3 | 12 | 173.9100(4) | 173.9112 | –0.0012 | 420.8914 | 246.9802 | AA | |||
| 01 | 16 | 2 | 14 | 00 | 17 | 3 | 14 | 172.3051(4) | 172.3069 | –0.0018 | 434.3755 | 262.0686 | AA | |||
| 01 | 17 | 5 | 12 | 00 | 18 | 6 | 12 | 171.6425(4) | 171.6424 | 0.0001 | 450.2336 | 278.5913 | AA | |||
| 01 | 13 | 2 | 11 | 00 | 14 | 3 | 11 | 174.7003(4) | 174.6997 | 0.0006 | 414.6950 | 239.9953 | AA | |||
| 01 | 9 | 6 | 3 | 00 | 10 | 7 | 3 | 174.2676(4) | 174.2685 | –0.0009 | 404.6806 | 230.4121 | AA | |||
| 01 | 21 | 5 | 16 | 00 | 22 | 6 | 16 | 169.8776(4) | 169.8788 | –0.0013 | 487.1456 | 317.2668 | AA | |||
| 01 | 10 | 2 | 8 | 00 | 11 | 3 | 8 | 176.7771(4) | 176.7754 | 0.0016 | 398.3315 | 221.5560 | AA | |||
| 01 | 12 | 6 | 6 | 00 | 13 | 7 | 6 | 172.8807(4) | 172.8795 | 0.0012 | 419.5060 | 246.6265 | AA | |||
| 01 | 20 | 5 | 15 | 00 | 21 | 6 | 15 | 170.4110(4) | 170.4110 | –0.0000 | 477.2119 | 306.8009 | AA | |||
| 01 | 14 | 5 | 9 | 00 | 15 | 6 | 9 | 172.7738(4) | 172.7728 | 0.0010 | 427.8757 | 255.1030 | AA | |||
| 01 | 16 | 5 | 11 | 00 | 17 | 6 | 11 | 172.0027(4) | 172.0035 | –0.0008 | 442.2567 | 270.2531 | AA | |||
| 01 | 13 | 5 | 8 | 00 | 14 | 6 | 8 | 173.1910(4) | 173.1912 | –0.0001 | 421.4556 | 248.2644 | AA | |||
Notes. The table includes assignments, observed frequencies and calculated frequencies from the BELGI-Cs-2Tops fit, residuals, upper and lower state energy levels as well as line symmetry for dimethyl sulfide The full table is available at the CDS.
Upper and lower state quantum numbers are indicated by “and”, respectively. Energy levels of EA, AE and EE species have a signed Ka value (Herbst et al. 1984).
Observed transitions in the torsional band (ν11,ν15 = 0,1) ← (ν11,ν15 = 1,0) in cm-1 with estimated uncertainties in parentheses on the last digit.
Upper state energy (cm-1) including the zero-point torsional energy calculated at 187.6294 cm-1.
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