Table 3
Spectroscopic parametersa (MHz) of the
gauche conformers of C2H5SH and C2H
SH determined in the present
study.
| Parameter | C2H5SH | C2HSH |
||
|
|
||||
| A | 28 746.912 8(58) | 28 708.867 5(189) | ||
| B | 5294.877 932(99) | 5175.221 38(36) | ||
| C | 4846.575 3(58) | 4745.419 1(72) | ||
| DK × 103 | 203.821 84(264) | 202.21(114) | ||
| DJK × 103 | −18.152 94(89) | −17.716 01(185) | ||
| DJ × 103 | 3.287 853(196) | 3.147 245(116) | ||
| d1 × 106 | −518.999(130) | −485.551(133) | ||
| d2 × 106 | −16.383(53) | −14.889(87) | ||
| HK × 106 | 5.417 4(50) | 5.40 | ||
| HKJ × 106 | −1.061 41(106) | −1.029 0(72) | ||
| HJK × 109 | −3.18(35) | −3.0 | ||
| HJ × 109 | 2.661 63(252) | 2.491 | ||
| h1 × 109 | 1.209 1(90) | 1.073 3(281) | ||
| h2 × 109 | 0.155 98(200) | 0.140 | ||
| E | 876.994 80(247) | 865.478 2(62) | ||
| EK × 103 | 71.894(308) | 64.73(238) | ||
| EJ × 103 | −13.007(214) | −10.926(248) | ||
| E2 × 103 | −13.120(104) | −11.948(118) | ||
| EKK × 106 | 106.9(42) | 90. | ||
| EJK × 106 | −6.395(235) | −5.4 | ||
| EJJ × 109 | 84.5(84) | 69. | ||
| EKKK × 109 | −540.6(242) | −420. | ||
| EJKK × 109 | −8.31(185) | −6.4 | ||
| EJJK × 109 | 0.469(41) | 0.36 | ||
| EKKKK × 1012 | 844.(41) | 610. | ||
| EJKKK × 1012 | 12.85(303) | 9.1 | ||
| F bc | 12.200 46(194) | 11.935 60(118) | ||
| Fbc,K × 103 | 13.28(74) | 13.0 | ||
| Fbc,J × 106 | 93.0(47) | 91. | ||
| Fbc,KK × 106 | 6.70(43) | 6.6 | ||
| Fbc,JJ × 109 | −1.565(304) | −1.53 | ||
| F ac | 100.95(69) | 100.33(86) | ||
| Fac,J × 103 | −0.951(39) | −0.944 | ||
| F2ac × 103 | 1.468 3(100) | 1.458 | ||
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