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Table A.5

Comparison between available experimental and calculated energy levels in Mo iv. Energies are given in cm-1.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.00 −34 34 1.5 99 4d34F
778.02 742 36 2.5 99 4d34F
1759.76 1716 44 3.5 99 4d34F
2864.58 2817 48 4.5 98 4d34F
10 330.59 10 370 −39 1.5 82 4d34P + 16 4d32P
10 337.77 10 414 −76 0.5 92 4d34P + 8 4d32P
11 580.50 11 661 −80 3.5 99 4d32G
11 611.99 11 688 −76 2.5 99 4d34P
12 310.80 12 366 −55 4.5 83 4d32G + 15 4d32H
14 175.62 14 146 30 1.5 47 4d32P + 27 4d32D + 17 4d34P
14 347.72 14 124 224 0.5 91 4d32P + 8 4d34P
15 995.13 15 989 6 4.5 85 4d32H + 15 4d32G
16 357.48 16 326 31 5.5 100 4d32H
16 809.32 17 007 −198 2.5 80 4d32D + 17 4d32D
17 107.35 17 117 −10 1.5 46 4d32D + 36 4d32P + 14 4d32D
24 787.03 24 769 18 3.5 99 4d32F
25 100.40 25 075 25 2.5 98 4d32F
38 922.29 38 877 45 2.5 80 4d32D + 18 4d32D
39 230.53 39 234 −3 1.5 76 4d32D + 23 4d32D
60 896.28 60 933 −37 1.5 99 4d2(3F)5s 4F
61 626.19 61 665 −39 2.5 98 4d2(3F)5s 4F
62 708.50 62 744 −35 3.5 99 4d2(3F)5s 4F
64 046.46 64 077 −31 4.5 99 4d2(3F)5s 4F
69 178.07 69 126 52 2.5 93 4d2(3F)5s 2F
71 358.31 71 265 93 3.5 97 4d2(3F)5s 2F
71 750.36 71 680 70 0.5 99 4d2(3P)5s 4P
72 162.82 72 103 60 1.5 93 4d2(3P)5s 4P + 6 4d2(1D)5s 2D
72 236.20 72 217 19 2.5 72 4d2(3P)5s 4P + 25 4d2(1D)5s 2D
74 008.77 74 019 −10 1.5 89 4d2(1D)5s 2D + 6 4d2(3P)5s 4P
74 981.08 74 977 4 2.5 69 4d2(1D)5s 2D + 27 4d2(3P)5s 4P
79 106.26 79 132 −26 4.5 99 4d2(1G)5s 2G
79 193.56 79 168 26 3.5 98 4d2(1G)5s 2G
79 898.80 79 976 −77 0.5 97 4d2(3P)5s 2P
81 052.21 81 122 −70 1.5 95 4d2(3P)5s 2P
99 783.80 99 784 0 0.5 98 4d2(1S)5s 2S
180 788.80 180 803 −14 2.5 64 4d2(3F)5d 4G + 32 4d2(3F)5d 2F
181 502.72 181 458 45 3.5 69 4d2(3F)5d 4H + 24 4d2(3F)5d 4G
182 001.68 182 007 −5 2.5 52 4d2(3F)5d 2F + 33 4d2(3F)5d 4G + 6 4d2(3F)5d 4D
182 009.98 182 053 −43 0.5 76 4d2(3F)5d 4D + 18 4d2(3F)5d 2P
182 139.47 182 091 48 3.5 72 4d2(3F)5d 4G + 22 4d2(3F)5d 4H
182 451.72 182 382 70 4.5 64 4d2(3F)5d 4H + 33 4d2(3F)5d 4G
182 782.89 182 767 16 1.5 91 4d2(3F)5d 4D
182 924.12 183 012 −88 3.5 71 4d2(3F)5d 2F + 9 4d2(3F)5d 4D + 7 4d2(3F)5d 2G
183 312.22 183 277 35 4.5 64 4d2(3F)5d 4G + 32 4d2(3F)5d 4H
183 672.70 183 612 61 5.5 64 4d2(3F)5d 4H + 33 4d2(3F)5d 4G
183 697.92 183 694 4 2.5 84 4d2(3F)5d 4D + 7 4d2(3F)5d 2F
184 007.99 184 108 −100 0.5 48 4d2(3F)5d 2P + 25 4d2(3F)5d 4P + 14 4d2(3F)5d 4D
184 547.29 184 527 20 5.5 64 4d2(3F)5d 4G + 35 4d2(3F)5d 4H
184 987.76 185 000 −12 3.5 84 4d2(3F)5d 4D + 6 4d2(3F)5d 2G + 5 4d2(3F)5d 2F
185 253.43 185 379 −126 1.5 44 4d2(3F)5d 4P + 38 4d2(3F)5d 2P + 8 4d2(3P)5d 4P
185 283.50 185 262 22 6.5 99 4d2(3F)5d 4H
185 412.03 185 440 −28 0.5 57 4d2(3F)5d 4P + 21 4d2(3F)5d 2P + 9 4d2(3P)5d 4P
186 019.92 185 978 42 3.5 65 4d2(3F)5d 2G + 13 4d2(3F)5d 2F + 8 4d2(1D)5d 2G
186 710.11 186 571 139 4.5 85 4d2(3F)5d 2H + 10 4d2(1G)5d 2H
186 810.77 186 908 −97 1.5 38 4d2(3F)5d 4P + 31 4d2(3F)5d 2P + 15 4d2(3F)5d 2D
186 931.08 186 976 −45 2.5 61 4d2(3F)5d 4P + 15 4d2(3P)5d 4P + 11 4d2(3F)5d 2D
187 202.27 187 228 −26 1.5 74 4d2(3F)5d 4F + 11 4d2(3F)5d 2D + 8 4d2(3F)5d 2P
187 237.70 187 192 46 4.5 79 4d2(3F)5d 2G + 10 4d2(1D)5d 2G
187 688.42 187 725 −37 1.5 44 4d2(3F)5d 2D + 18 4d2(3F)5d 4F + 14 4d2(1D)5d 2D
188 032.96 188 038 −5 2.5 82 4d2(3F)5d 4F + 5 4d2(3F)5d 2D
188 595.01 188 641 −46 2.5 53 4d2(3F)5d 2D + 17 4d2(1D)5d 2D + 12 4d2(3F)5d 4P
188 709.85 188 615 95 5.5 86 4d2(3F)5d 2H + 10 4d2(1G)5d 2H
188 979.01 188 982 −3 3.5 91 4d2(3F)5d 4F
189 966.52 189 963 4 4.5 93 4d2(3F)5d 4F
190 833.77 190 844 −10 1.5 96 4d2(3F)6s 4F
191 339.64 191 333 7 2.5 77 4d2(3F)6s 4F + 19 4d2(3F)6s 2F
191 540.13 191 524 16 1.5 59 4d2(3P)5d 2P + 35 4d2(1D)5d 2P
191 755.47 191 757 −2 0.5 72 4d2(1D)5d 2S + 17 4d2(3P)5d 2P
192 578.85 192 614 −35 3.5 88 4d2(3F)6s 4F + 8 4d2(3F)6s 2F
192 624.98 192 633 −8 2.5 59 4d2(1D)5d 2F + 20 4d2(3P)5d 2F + 8 4d2(3F)6s 2F
193 319.52 193 339 −19 3.5 55 4d2(1D)5d 2F + 10 4d2(3P)5d 4F + 10 4d2(3P)5d 2F
193 379.15 193 435 −56 2.5 71 4d2(3F)6s 2F + 15 4d2(3F)6s 4F + 11 4d2(1D)5d 2F
193 462.57 193 474 −12 0.5 42 4d2(3P)5d 2P + 27 4d2(1D)5d 2P + 20 4d2(1D)5d 2S
193 779.78 193 718 62 4.5 38 4d2(1D)5d 2G + 31 4d2(3P)5d 4F + 19 4d2(3F)6s 4F
193 815.29 193 805 10 1.5 92 4d2(3P)5d 4F
194 100.67 194 059 42 3.5 49 4d2(1D)5d 2G + 20 4d2(1D)5d 2F + 9 4d2(3P)5d 4F
194 235.12 194 244 −9 2.5 85 4d2(3P)5d 4F + 5 4d2(3P)5d 4D
194 296.81 194 334 −37 4.5 78 4d2(3F)6s 4F + 15 4d2(1D)5d 2G
194 970.47 194 952 18 3.5 63 4d2(3P)5d 4F + 10 4d2(3P)5d 2F + 8 4d2(3P)5d 4D
195 307.98 195 298 10 1.5 72 4d2(3P)5d 4D + 15 4d2(1D)5d 2D + 6 4d2(3F)5d 2D
195 454.02 195 423 31 3.5 85 4d2(3F)6s 2F + 7 4d2(3F)6s 4F
195 672.25 195 653 19 0.5 89 4d2(3P)5d 4D + 6 4d2(3P)5d 2P
195 740.65 195 722 19 2.5 81 4d2(3P)5d 4D + 5 4d2(1D)5d 2D
196 151.58 196 092 60 2.5 44 4d2(3P)5d 2F + 36 4d2(1G)5d 2F + 11 4d2(1D)5d 2F
196 179.49 196 187 −8 1.5 30 4d2(3P)5d 4P + 22 4d2(1D)5d 2D + 13 4d2(3P)5d 4D
196 335.08 196 332 3 4.5 61 4d2(3P)5d 4F + 27 4d2(1D)5d 2G + 7 4d2(1G)5d 2G
196 688.12 196 670 18 3.5 39 4d2(3P)5d 4D + 17 4d2(1G)5d 2F + 11 4d2(3P)5d 2F
196 828.31 196 863 −35 3.5 38 4d2(3P)5d 4D + 33 4d2(3P)5d 2F + 12 4d2(1G)5d 2F
196 953.22 196 943 10 0.5 56 4d2(3P)5d 4P + 17 4d2(1D)5d 2P + 14 4d2(3P)5d 2P
197 119.54 197 108 12 2.5 55 4d2(3P)5d 4P + 18 4d2(1D)5d 2D + 15 4d2(3F)5d 4P
197 258.73 197 292 −33 1.5 28 4d2(3P)5d 4P + 17 4d2(3P)5d 2D + 14 4d2(1D)5d 2D
198 334.87 198 425 −90 2.5 26 4d2(3P)5d 2D + 21 4d2(1G)5d 2D + 18 4d2(3P)5d 4P
198 712.48 198 686 26 0.5 39 4d2(1D)5d 2P + 28 4d2(3P)5d 4P + 17 4d2(3P)5d 2P
199 069.41 199 165 −96 3.5 86 4d2(1G)5d 2G + 6 4d2(3F)5d 2G + 5 4d2(1D)5d 2G
199 087.52 199 110 −22 1.5 24 4d2(3P)5d 2D + 20 4d2(3P)5d 4P + 19 4d2(1D)5d 2P
199 229.00 199 252 −23 2.5 35 4d2(1D)5d 2D + 34 4d2(3P)5d 2D + 10 4d2(1G)5d 2D
199 394.17 199 478 −84 4.5 73 4d2(1G)5d 2G + 12 4d2(1G)5d 2H + 7 4d2(3F)5d 2G
199 722.50 199 711 12 5.5 98 4d2(1G)5d 2I
200 086.20 200 048 38 6.5 99 4d2(1G)5d 2I
200 189.54 200 189 1 1.5 23 4d2(1D)5d 2P + 18 4d2(1D)5d 2D + 18 4d2(3P)5d 2D
201 009.39 200 995 14 4.5 76 4d2(1G)5d 2H + 9 4d2(3F)5d 2H + 8 4d2(1G)5d 2G
201 022.59 200 980 43 5.5 86 4d2(1G)5d 2H + 11 4d2(3F)5d 2H
201 355.10 201 306 49 2.5 71 4d2(1D)6s 2D + 26 4d2(3P)6s 4P
201 545.32 201 488 57 1.5 79 4d2(1D)6s 2D + 9 4d2(3P)6s 4P + 8 4d2(3P)6s 2P
202 114.64 202 120 −5 0.5 95 4d2(3P)6s 4P
202 770.34 202 787 −17 1.5 86 4d2(3P)6s 4P + 8 4d2(3P)6s 2P + 5 4d2(1D)6s 2D
203 894.00 203 890 4 0.5 96 4d2(3P)6s 2P
204 269.40 204 276 −7 2.5 47 4d2(3P)6s 4P + 21 4d2(1G)5d 2F + 15 4d2(1D)6s 2D
204 245.11 204 148 97 3.5 59 4d2(1G)5d 2F + 27 4d2(3P)5d 2F + 8 4d2(1D)5d 2F
204 426.26 204 360 66 2.5 35 4d2(1G)5d 2F + 27 4d2(3P)6s 4P + 15 4d2(3P)5d 2F
205 341.50 205 360 −18 1.5 82 4d2(3P)6s 2P + 12 4d2(1D)6s 2D
206 861.16 206 904 −43 1.5 65 4d2(1G)5d 2D + 26 4d2(3P)5d 2D
207 103.42 207 142 −39 2.5 60 4d2(1G)5d 2D + 29 4d2(3P)5d 2D
207 561.80 207 554 8 4.5 99 4d2(1G)6s 2G
207 567.86 207 556 12 3.5 98 4d2(1G)6s 2G
221 465.60 221 414 52 1.5 94 4d2(1S)5d 2D
221 491.80 221 541 −49 2.5 96 4d2(1S)5d 2D
Odd parity
109 415.25 109 428 −13 2.5 81 4d2(3F)5p 4G + 12 4d2(3F)5p 2F
111 339.53 111 334 6 3.5 90 4d2(3F)5p 4G + 5 4d2(3F)5p 2F
111 760.03 111 727 33 1.5 76 4d2(3F)5p 4F + 18 4d2(3F)5p 2D
112 925.24 112 962 −37 2.5 71 4d2(3F)5p 4F + 12 4d2(3F)5p 2D + 7 4d2(3F)5p 4D
113 443.02 113 424 19 4.5 92 4d2(3F)5p 4G + 6 4d2(3F)5p 4F
113 984.98 114 010 −25 2.5 39 4d2(3F)5p 2F + 21 4d2(3F)5p 4F + 16 4d2(3F)5p 4G
114 624.49 114 561 63 3.5 90 4d2(3F)5p 4F
114 708.24 114 756 −48 1.5 42 4d2(3F)5p 2D + 22 4d2(3F)5p 4F + 16 4d2(3F)5p 4D
115 762.16 115 869 −107 3.5 62 4d2(3F)5p 2F + 23 4d2(3F)5p 4D + 6 4d2(3F)5p 4G
115 789.36 115 729 60 0.5 79 4d2(3F)5p 4D + 17 4d2(3P)5p 4D
115 881.12 115 816 65 5.5 99 4d2(3F)5p 4G
115 961.91 115 897 65 4.5 84 4d2(3F)5p 4F + 7 4d2(3F)5p 2G + 7 4d2(3F)5p 4G
116 583.82 116 641 −57 2.5 46 4d2(3F)5p 4D + 17 4d2(3F)5p 2F + 14 4d2(3F)5p 2D
116 586.00 116 618 −32 1.5 61 4d2(3F)5p 4D + 16 4d2(3P)5p 4D + 12 4d2(3F)5p 2D
117 604.08 117 752 −148 2.5 31 4d2(3F)5p 2D + 28 4d2(3F)5p 4D + 17 4d2(3P)5p 2D
117 922.63 118 177 −255 0.5 92 4d2(3P)5p 2S
118 080.17 118 097 −17 3.5 58 4d2(3F)5p 4D + 15 4d2(3F)5p 2F + 10 4d2(3P)5p 4D
119 002.33 118 975 27 3.5 77 4d2(3F)5p 2G + 13 4d2(1G)5p 2G
120 645.02 120 664 −19 4.5 72 4d2(3F)5p 2G + 15 4d2(1G)5p 2G + 11 4d2(3F)5p 4F
120 823.46 120 749 74 1.5 69 4d2(3P)5p 4S + 22 4d2(1D)5p 2P
122 419.26 122 399 20 0.5 80 4d2(3P)5p 4D + 17 4d2(3F)5p 4D
122 808.84 122 887 −78 1.5 31 4d2(1D)5p 2P + 21 4d2(3P)5p 4S + 19 4d2(3P)5p 4D
123 432.84 123 426 7 1.5 61 4d2(3P)5p 4D + 19 4d2(1D)5p 2P + 8 4d2(3F)5p 4D
123 534.18 123 406 128 2.5 59 4d2(1D)5p 2F + 15 4d2(3F)5p 2F + 8 4d2(3P)5p 4D
124 741.62 124 818 −76 0.5 82 4d2(1D)5p 2P + 12 4d2(3P)5p 4P
124 789.75 124 723 67 2.5 70 4d2(3P)5p 4D + 14 4d2(1D)5p 2F + 9 4d2(3F)5p 4D
124 947.54 124 828 120 3.5 43 4d2(1D)5p 2F + 20 4d2(1G)5p 2G + 16 4d2(3P)5p 4D
126 243.19 126 330 −87 1.5 44 4d2(1D)5p 2D + 20 4d2(1D)5p 2P + 18 4d2(3P)5p 4P
126 416.33 126 342 74 3.5 55 4d2(3P)5p 4D + 29 4d2(1G)5p 2G + 5 4d2(3F)5p 2G
126 716.64 126 760 −43 2.5 53 4d2(1D)5p 2D + 29 4d2(3P)5p 4P + 6 4d2(3F)5p 2D
126 760.46 126 707 53 0.5 83 4d2(3P)5p 4P + 9 4d2(1D)5p 2P + 6 4d2(3P)5p 2S
126 999.09 126 897 102 4.5 70 4d2(1G)5p 2G + 19 4d2(3F)5p 2G + 10 4d2(1G)5p 2H
127 181.20 127 129 52 1.5 77 4d2(3P)5p 4P + 18 4d2(1D)5p 2D
127 728.82 127 634 95 3.5 33 4d2(1G)5p 2G + 32 4d2(1D)5p 2F + 17 4d2(3P)5p 4D
128 897.78 128 862 36 2.5 64 4d2(3P)5p 4P + 32 4d2(1D)5p 2D
130 149.35 129 987 162 4.5 87 4d2(1G)5p 2H + 12 4d2(1G)5p 2G
131 699.83 131 641 59 1.5 65 4d2(3P)5p 2D + 13 4d2(3P)5p 2P + 13 4d2(3F)5p 2D
132 012.37 131 849 163 5.5 99 4d2(1G)5p 2H
132 219.07 132 241 −22 2.5 70 4d2(3P)5p 2D + 20 4d2(3F)5p 2D
133 362.00 133 350 12 0.5 92 4d2(3P)5p 2P
134 242.50 134 223 20 1.5 79 4d2(3P)5p 2P + 9 4d2(3P)5p 2D
134 951.06 135 198 −247 3.5 90 4d2(1G)5p 2F
136 324.44 136 602 −278 2.5 94 4d2(1G)5p 2F
150 069.22 150 096 −27 0.5 92 4d2(1S)5p 2P
152 757.31 152 729 28 1.5 95 4d2(1S)5p 2P

Notes.

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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