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Table A.1
Radial parameters (in cm-1) adopted for the calculations in Mo iv.
| Configuration | Parameter | HFR | Fitted | Ratio | Notea |
|
|
|||||
| Even parity | |||||
| 4d3 | Eav | 17 281 | 16 028 | ||
| F2(4d, 4d) | 63 593 | 53 099 | 0.835 | ||
| F4(4d, 4d) | 41 828 | 36 184 | 0.865 | ||
| α | 0 | 9 | |||
| β | 0 | −491 | |||
| ζ4d | 812 | 810 | 0.997 | ||
| 4d25s | Eav | 75 210 | 73 187 | ||
| F2(4d, 4d) | 66 028 | 53 488 | 0.810 | ||
| F4(4d, 4d) | 43 601 | 36 324 | 0.833 | ||
| α | 0 | 30 | |||
| β | 0 | −417 | |||
| ζ 4d | 878 | 875 | 0.996 | ||
| G2(4d, 5s) | 15 995 | 14 485 | 0.906 | ||
| 4d26s | E av | 201 514 | 200 119 | ||
| F2(4d, 4d) | 67 245 | 53 932 | 0.802 | ||
| F4(4d, 4d) | 44 505 | 35 007 | 0.787 | ||
| α | 0 | 45 | |||
| β | 0 | −420 | F | ||
| ζ 4d | 904 | 924 | 1.023 | ||
| G2(4d, 6s) | 3356 | 2624 | 0.782 | ||
| 4d25d | E av | 193 759 | 193 316 | ||
| F2(4d, 4d) | 67 204 | 54 471 | 0.811 | ||
| F4(4d, 4d) | 44 476 | 36 658 | 0.824 | ||
| α | 0 | 31 | |||
| β | 0 | −256 | |||
| ζ 4d | 903 | 924 | 1.024 | ||
| ζ 5d | 139 | 150 | 1.077 | ||
| F2(4d, 5d) | 14 772 | 12 432 | 0.842 | ||
| F4(4d, 5d) | 6861 | 5749 | 0.838 | ||
| G0(4d, 5d) | 4764 | 3206 | 0.673 | ||
| G2(4d, 5d) | 5093 | 3789 | 0.744 | ||
| G4(4d, 5d) | 4081 | 3439 | 0.843 | ||
| Odd parity | |||||
| 4d25p | E av | 125 149 | 124 281 | ||
| F2(4d, 4d) | 66 425 | 53 851 | 0.811 | ||
| F4(4d, 4d) | 43 895 | 36 220 | 0.825 | ||
| α | 0 | 33 | |||
| β | 0 | −333 | |||
| ζ 4d | 888 | 930 | 1.048 | ||
| ζ 5p | 1801 | 2130 | 1.183 | ||
| F2(4d, 5p) | 25 420 | 23 019 | 0.906 | ||
| G1(4d, 5p) | 9987 | 9357 | 0.937 | ||
| G3(4d, 5p) | 8792 | 8106 | 0.922 | ||
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