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Table A.8

Comparison between available experimental and calculated energy levels in Mo vii. Energies are given in cm-1.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.00 0 0 0 97 4p61S
542 265.29 542 456 −191 1 80 4p55p 3S + 17 4p55p 3P
544 663.10 544 655 8 1 73 4s4p64d 3D + 12 4p4(1D)4d23D + 8 4p54f 3D
545 906.83 545 883 24 2 73 4s4p64d 3D + 11 4p4(1D)4d23D + 8 4p54f 3D
548 077.57 547 987 91 2 55 4p55p 3D + 35 4p55p 1D + 8 4p55p 3P
548 120.43 548 120 0 3 74 4s4p64d 3D + 12 4p4(1D)4d23D + 7 4p54f 3D
552 329.97 552 000 330 3 98 4p55p 3D
554 401.01 554 408 −7 1 48 4p55p 1P + 28 4p55p 3D + 18 4p55p 3P
557 437.49 557 605 −168 2 65 4p55p 3P + 29 4p55p 1D
563 567.72 563 589 −21 2 62 4s4p64d 1D + 18 4p4(1D)4d21D + 9 4p4(1D)4d21D
565 803.85 565 892 −88 0 77 4p55p 3P + 22 4p55p 1S
570 658.75 570 618 41 1 64 4p55p 3D + 33 4p55p 1P
577 644.10 577 596 48 2 34 4p55p 1D + 41 4p55p 3D + 23 4p55p 3P
577 765.90 577 851 −85 1 63 4p55p 3P + 18 4p55p 1P + 13 4p55p 3S
585 026.11 585 000 26 0 76 4p55p 1S + 23 4p55p 3P
609 898.90 606 995 2904 2 42 4p4(3P)4d25D + 22 4p4(3P)4d25F + 15 4p4(3P)4d25D
610 564.98 610 483 82 5 70 4p54f 3G + 24 4p4(3P)4d23G
610 908.23 610 998 −90 4 47 4p54f 3G + 22 4p54f 1G + 19 4p4(3P)4d23G
611 395.80 614 262 −2866 4 40 4p4(3P)4d25F + 29 4p4(3P)4d25D + 11 4p4(3P)4d25G
611 727.25 611 765 −38 1 54 4p54f 3D + 13 4p4(3P)4d25F + 10 4p4(3P)4d23D
613 593.09 613 685 −92 2 43 4p54f 3D + 8 4p54f 3F + 7 4p4(3P)4d23D
615 203.92 615 179 25 3 24 4p54f 3F + 24 4p54f 3G + 11 4p4(3P)4d23G
615 725.35 615 720 5 3 22 4p4(3P)4d25F + 17 4p4(3P)4d25D + 16 4p54f 3D
616 148.25 616 162 −14 4 38 4p54f 3F + 21 4p4(3P)4d23F + 20 4p54f 1G
624 603.86 624 455 149 2 26 4p54f 3F + 16 4p54f 1D + 12 4p54f 3D
633 788.90 633 559 230 3 24 4p54f 3G + 19 4p54f 3F + 18 4p4(3P)4d23G
635 262.40 635 075 187 4 32 4p54f 1G + 18 4p4(3P)4d23F + 11 4p54f 3G
635 910.50 636 296 −385 3 30 4p54f 1F + 19 4p54f 3D + 6 4p4(3P)4d23F
645 811.86 645 895 −83 2 26 4p54f 1D + 11 4p4(1D)4d21D + 8 4p54f 3F
648 282.60 647 870 413 4 43 4p4(3P)4d25D + 24 4p4(3P)4d25D + 6 4p4(3P)4d23F
771 708.20 770 648 1060 1 15 4p4(3P)4d23P + 29 4p55f 3D + 11 4p4(1S)4d23P
773 033.30 769 815 3218 2 56 4p55f 3D + 13 4p55f 3F + 8 4p4(3P)4d23D
774 110.00 774 662 −552 5 88 4p55f 3G + 7 4p4(3P)4d23G
775 406.00 775 927 −521 4 65 4p55f 3G + 12 4p55f 1G + 11 4p55f 3F
775 781.00 774 531 1250 3 45 4p55f 3D + 15 4p55f 3F + 15 4p4(3P)4d21F
776 649.60 778 934 −2284 2 20 4p4(1D)4d23D + 21 4p55f 3D + 16 4p4(3P)4d23D
777 161.10 777 843 −682 3 33 4p55f 3G + 32 4p55f 1F + 22 4p55f 3F
779 373.60 781 310 −1936 4 48 4p55f 3F + 30 4p55f 1G
794 751.20 794 987 −236 2 59 4p55f 3F + 13 4p55f 1D + 13 4p55f 3D
797 800.50 797 278 522 3 43 4p55f 1F + 35 4p55f 3G + 13 4p55f 3D
797 995.40 797 598 397 3 45 4p55f 3F + 23 4p55f 3G + 18 4p55f 3D
800 199.70 800 881 −681 4 33 4p55f 1G + 25 4p55f 3G + 22 4p55f 3F
Odd parity
302 343.70 302 618 −274 0 99 4p54d 3P
305 558.90 305 795 −236 1 96 4p54d 3P
312 048.40 312 226 −178 2 88 4p54d 3P + 9 4p54d 3D
315 491.80 314 944 548 4 99 4p54d 3F
318 103.90 317 625 479 3 83 4p54d 3F + 10 4p54d 1F + 6 4p54d 3D
322 896.00 322 759 137 2 66 4p54d 3F + 20 4p54d 1D + 13 4p54d 3D
333 618.90 334 040 −421 3 64 4p54d 3D + 35 4p54d 1F
341 503.80 341 537 −33 2 45 4p54d 1D + 33 4p54d 3F + 21 4p54d 3D
341 713.00 341 727 −14 1 95 4p54d 3D
347 433.40 347 624 −191 2 57 4p54d 3D + 31 4p54d 1D + 11 4p54d 3P
351 126.60 350 945 182 3 55 4p54d 1F + 29 4p54d 3D + 16 4p54d 3F
417 528.60 417 528 1 1 96 4p54d 1P
477 767.80 477 772 −4 2 99 4p55s 3P
481 295.99 481 291 5 1 53 4p55s 1P + 45 4p55s 3P
500 618.75 500 613 6 0 99 4p55s 3P
502 933.27 502 939 −6 1 53 4p55s 3P + 45 4p55s 1P
657 602.91 657 637 −34 0 99 4p55d 3P
659 015.62 659 037 −21 1 88 4p55d 3P + 9 4p55d 3D
661 488.47 661 358 130 4 99 4p55d 3F
661 678.46 661 689 −11 2 64 4p55d 3P + 26 4p55d 3D + 8 4p55d 1D
661 683.19 661 680 3 3 58 4p55d 3F + 38 4p55d 1F
664 362.66 664 363 0 2 46 4p55d 1D + 31 4p55d 3F + 21 4p55d 3D
665 713.78 665 693 21 3 67 4p55d 3D + 27 4p55d 1F
669 063.09 669 155 −92 1 46 4p55d 3D + 50 4p55d 1P
684 805.34 684 824 −19 2 66 4p55d 3F + 25 4p55d 1D + 7 4p55d 3D
686 113.49 686 168 −55 2 45 4p55d 3D + 32 4p55d 3P + 20 4p55d 1D
686 635.00 686 656 −21 3 34 4p55d 1F + 37 4p55d 3F + 29 4p55d 3D
689 784.69 689 687 98 1 47 4p55d 1P + 43 4p55d 3D + 8 4p55d 3P
708 843.60 708 839 5 2 100 4p56s 3P
710 068.90 710 073 −5 1 62 4p56s 1P + 37 4p56s 3P
731 864.90 731 872 −7 0 99 4p56s 3P
732 582.50 732 575 8 1 62 4p56s 3P + 37 4p56s 1P
780 390.00 780 389 1 1 60 4s4p65p 3P + 18 4p4(1D)4d5p 3P + 13 4p56d 3P
789 696.00 789 687 9 1 61 4s4p65p 1P + 20 4p4(1D)4d5p 1P + 8 4p56d 3P
793 700.50 793 689 11 2 75 4p55g 3F + 12 4p56d 3D
793 909.10 794 182 −273 3 42 4p55g 3F + 31 4p56d 3D + 13 4p55g 1F
794 550.20 794 567 −17 6 99 4p55g 3H
794 669.80 794 661 9 5 52 4p55g 1H + 47 4p55g 3H
795 532.00 795 626 −94 1 54 4p56d 1P + 37 4p56d 3D + 6 4s4p65p 1P
795 665.20 795 574 91 4 49 4p55g 3F + 28 4p55g 3G + 22 4p55g 1G
795 918.60 795 923 −4 3 39 4p55g 1F + 49 4p55g 3G + 9 4p55g 3F
796 389.50 796 411 −21 4 38 4p55g 1G + 31 4p55g 3H + 30 4p55g 3G
796 442.60 796 470 −27 5 68 4p55g 3G + 16 4p55g 1H + 15 4p55g 3H
816 413.00 817 148 −735 1 61 4p57s 1P + 33 4p57s 3P
818 278.10 818 257 21 4 26 4p55g 3G + 49 4p55g 3F + 23 4p55g 1G
818 504.10 818 503 1 4 68 4p55g 3H + 16 4p55g 1G + 15 4p55g 3G
818 583.40 818 606 −23 3 48 4p55g 3G + 30 4p55g 1F + 20 4p55g 3F
818 597.80 818 598 0 5 37 4p55g 3H + 31 4p55g 1H + 31 4p55g 3G
839 342.00 839 304 38 1 65 4p57s 3P + 35 4p57s 1P
874 998.00 874 906 92 1 43 4p58s 1P + 22 4p58s 3P + 9 4p4(1D)4d5p 3D
898 093.00 897 197 896 1 38 4p58s 3P + 19 4p58s 1P + 6 4p4(3P)4d5p 3P
910 830.00 910 688 142 1 63 4p59s 1P + 33 4p59s 3P
934 536.00 934 473 63 1 65 4p510s 1P + 33 4p510s 3P

Notes.

(a)

From Reader (2010).

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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