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Table A.7

Comparison between available experimental and calculated energy levels in Mo vi. Energies are given in cm-1.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.00 0 0 1.5 99 4d 2D
2583.50 2583 0 2.5 99 4d 2D
119 725.62 119 725 0 0.5 99 5s 2S
282 825.59 282 825 0 1.5 99 5d 2D
283 610.94 283 611 0 2.5 99 5d 2D
313 806.81 313 807 0 0.5 100 6s 2S
386 165.59 386 166 0 1.5 99 6d 2D
386 552.16 386 552 0 2.5 99 6d 2D
395 181.34 395 181 0 3.5 100 5g 2G
395 184.31 395 184 0 4.5 100 5g 2G
400 761.59 400 762 0 0.5 100 7s 2S
439 465.16 439 465 0 1.5 99 7d 2D
439 691.28 439 691 0 2.5 99 7d 2D
443 937.56 443 938 0 3.5 100 6g 2G
443 941.00 443 941 0 4.5 100 6g 2G
447 730.19 447 730 0 0.5 100 8s 2S
470 813.00 470 813 0 1.5 99 8d 2D
470 962.00 470 962 0 2.5 99 8d 2D
473 433.70 473 434 0 3.5 100 7g 2G
473 437.06 473 437 0 4.5 100 7g 2G
474 431.80 474 432 0 5.5 100 7i 2I
474 435.50 474 436 0 6.5 100 7i 2I
492 596.81 492 597 0 3.5 100 8g 2G
492 601.06 492 601 0 4.5 100 8g 2G
493 347.38 493 347 0 5.5 100 8i 2I
493 348.19 493 348 0 6.5 100 8i 2I
Odd parity
182 404.47 182 404 0 0.5 99 5p 2P
187 331.19 187 331 0 1.5 99 5p 2P
267 047.22 266 941 106 2.5 86 4f 2F + 11 4p54d2(1G)2F
267 456.84 267 566 −109 3.5 87 4f 2F + 8 4p54d2(1G)2F
286 236.00 286 288 −52 0.5 85 4p54d2(3F)4D + 13 4p54d2(3P)4D
287 250.00 287 263 −13 1.5 78 4p54d2(3F)4D + 16 4p54d2(3P)4D
288 938.00 288 902 36 2.5 67 4p54d2(3F)4D + 22 4p54d2(3P)4D + 6 4p54d2(3F)4F
300 690.00 300 600 90 2.5 87 4p54d2(3P)4P
303 186.00 303 246 −60 2.5 21 4p54d2(3F)4F + 38 4p54d2(3F)4G + 15 4p54d2(3F)2F
304 074.00 304 043 31 1.5 82 4p54d2(3P)4P
306 806.00 306 871 −65 1.5 32 4p54d2(1D)2D + 36 4p54d2(3F)4F + 12 4p54d2(3F)2D
307 386.00 307 433 −47 0.5 87 4p54d2(3P)4P + 5 4p54d2(3P)2S
308 874.00 308 782 92 2.5 54 4p54d2(1D)2D + 15 4p54d2(3F)2D + 9 4p54d2(3F)4G
312 090.37 311 918 172 3.5 39 4p54d2(3F)4F + 31 4p54d2(3F)2G + 11 4p54d2(3F)4G
314 953.00 314 784 169 1.5 50 4p54d2(3F)4F + 20 4p54d2(1D)2P + 11 4p54d2(1D)2D
315 155.49 315 212 −57 2.5 21 4p54d2(1G)2F + 31 4p54d2(3F)4F + 17 4p54d2(3F)2F
315 795.00 316 117 −322 0.5 68 4p54d2(1D)2P + 19 4p54d2(3P)2P + 6 4p54d2(3P)4P
316 476.56 316 845 −368 3.5 25 4p54d2(3F)2F + 25 4p54d2(1G)2F + 23 4p54d2(3P)4D
318 528.00 318 313 215 2.5 47 4p54d2(3F)4G + 28 4p54d2(3F)4F + 11 4p54d2(1G)2F
320 088.00 319 864 224 3.5 90 4p54d2(1D)2F + 5 4f 2F
329 873.00 329 987 −114 2.5 50 4p54d2(3P)4D + 26 4p54d2(3F)4D + 14 4p54d2(3P)2D
331 208.00 331 187 21 3.5 41 4p54d2(3P)4D + 39 4p54d2(3F)4D + 8 4p54d2(3F)4F
331 693.00 331 458 235 1.5 47 4p54d2(3P)4D + 29 4p54d2(3P)2D + 12 4p54d2(3F)4D
337 018.00 336 961 57 0.5 82 4p54d2(3P)4D + 12 4p54d2(3F)4D
337 071.03 337 150 −79 2.5 81 4p54d2(1D)2F
340 570.78 340 571 0 0.5 99 6p 2P
342 562.44 342 544 18 1.5 88 6p 2P + 5 4p54d2(3P)2D
343 114.50 343 261 −146 1.5 45 4p54d2(3P)2D + 24 4p54d2(3P)4D + 11 6p 2P
346 888.80 346 902 −13 1.5 77 4p54d2(3P)4S + 6 4p54d2(3P)2D + 5 4p54d2(3P)4P
348 702.28 348 602 100 3.5 84 4p54d2(1G)2G + 9 4p54d2(3F)2F
349 283.97 349 427 −143 2.5 65 4p54d2(3P)2D + 14 4p54d2(3P)4D + 6 4p54d2(3F)2D
355 442.00 355 442 0 1.5 69 4p54d2(1S)2P + 26 4p54d2(1D)2P
365 103.41 365 240 −137 2.5 51 5f 2F + 26 4p54d2(3F)2F + 14 4p54d2(1G)2F
368 203.16 368 087 116 3.5 65 5f 2F + 16 4p54d2(3F)2F + 11 4p54d2(1G)2F
394 045.41 394 049 −4 2.5 23 4p54d2(3F)2F + 45 5f 2F + 21 4p54d2(1G)2F
398 931.69 398 943 −11 3.5 28 4p54d2(1G)2F + 33 5f 2F + 25 4p54d2(3F)2F
403 120.00 403 201 −81 0.5 68 4p54d2(3P)2P + 16 4p54d2(1S)2P + 11 4p54d2(1D)2P
407 906.00 407 574 332 1.5 71 4p54d2(3P)2P + 16 4p54d2(1D)2P + 6 4p54d2(1S)2P
412 799.00 412 832 −33 2.5 68 4p54d2(3F)2D + 15 4p54d2(1D)2D + 11 4p54d2(3P)2D
413 282.00 413 433 −151 1.5 70 4p54d2(3F)2D + 17 4p54d2(1D)2D + 9 4p54d2(3P)2D
414 853.81 414 849 5 0.5 95 7p 2P
416 068.59 416 079 −10 1.5 95 7p 2P
417 695.00 417 842 −147 0.5 97 4p54d5s(3P)4P
420 665.00 420 788 −123 1.5 93 4p54d5s(3P)4P
426 499.00 426 529 −30 2.5 88 4p54d5s(3P)4P + 8 4p54d5s(3D)4D
427 009.00 427 117 −108 0.5 91 4p54d5s(3P)2P
431 560.00 431 267 293 3.5 87 4p54d5s(3F)4F
433 184.00 433 248 −64 1.5 82 4p54d5s(3P)2P + 6 4p54d5s(3D)2D + 5 4p54d5s(3D)4D
434 125.00 433 861 264 2.5 74 4p54d5s(3F)4F + 8 4p54d5s(1F)2F + 8 4p54d5s(3F)2F
436 181.50 436 073 109 2.5 93 6f 2F
436 548.31 436 660 −112 3.5 90 6f 2F
437 890.00 437 793 97 1.5 69 4p54d5s(3F)4F + 19 4p54d5s(1D)2D + 7 4p54d5s(3D)4D
437 978.00 437 737 241 3.5 89 4p54d5s(3F)2F + 6 4p54d5s(3D)4D
441 562.00 441 598 −36 2.5 54 4p54d5s(3F)2F + 22 4p54d5s(1D)2D + 13 4p54d5s(3D)4D
445 102.50 445 103 0 4.5 100 6h 2H
445 106.20 445 106 0 5.5 100 6h 2H
448 052.00 448 205 −153 3.5 68 4p54d5s(3D)4D + 30 4p54d5s(1F)2F
451 836.00 451 995 −159 2.5 38 4p54d5s(3D)2D + 32 4p54d5s(1F)2F + 24 4p54d5s(3D)4D
454 862.00 454 942 −80 0.5 72 4p54d5s(3D)4D + 24 8p 2P
455 807.00 455 769 38 1.5 57 4p54d5s(3D)4D + 18 4p54d5s(3F)4F + 12 4p54d5s(1D)2D
456 494.90 456 469 26 0.5 75 8p 2P + 22 4p54d5s(3D)4D
456 718.34 456 722 −4 1.5 86 8p 2P + 7 4p54d5s(1D)2D
458 214.00 458 360 −146 2.5 33 4p54d5s(1D)2D + 19 4p54d5s(3F)2F + 18 4p54d5s(3F)4F
458 942.00 458 974 −32 1.5 42 4p54d5s(1D)2D + 24 4p54d5s(3D)2D + 19 4p54d5s(3D)4D
462 578.00 462 592 −14 2.5 34 4p54d5s(3D)4D + 39 4p54d5s(1D)2D + 11 4p54d5s(3D)2D
466 403.00 466 383 20 1.5 65 4p54d5s(3D)2D + 17 4p54d5s(1D)2D + 11 4p54d5s(3P)2P
466 410.00 466 382 28 3.5 61 4p54d5s(1F)2F + 22 4p54d5s(3D)4D + 11 4p54d5s(3F)4F
467 829.78 467 813 16 2.5 98 7f 2F
467 944.41 467 961 −17 3.5 98 7f 2F
469 446.00 469 357 89 2.5 42 4p54d5s(1F)2F + 39 4p54d5s(3D)2D + 14 4p54d5s(3F)2F
474 295.97 474 295 1 4.5 100 7h 2H
474 296.78 474 297 0 5.5 100 7h 2H
481 343.00 481 343 0 0.5 100 9p 2P
481 768.00 481 768 0 1.5 100 9p 2P
488 713.00 488 701 12 2.5 99 8f 2F
488 752.00 488 764 −12 3.5 99 8f 2F
493 245.00 493 246 −1 4.5 100 8h 2H
493 248.34 493 247 1 5.5 100 8h 2H
493 377.60 493 378 0 6.5 100 8k 2K
493 381.30 493 378 3 7.5 100 8k 2K
498 038.00 498 038 0 0.5 100 10p 2P
498 300.00 498 300 0 1.5 100 10p 2P
502 976.00 502 977 −1 2.5 100 9f 2F
503 014.00 503 013 1 3.5 100 9f 2F
509 596.00 509 596 0 0.5 100 11p 2P
509 786.00 509 786 0 1.5 100 11p 2P

Notes.

(a)

From Reader (2010).

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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