Table A.3
The laboratory parameters and the intensity integrated over the width of each line , which is used for rotation diagrams in Fig. 9.
Mol. | Freq | I(300 K) | E L | S ul μ 2 | HC | mm2 | mm3a | mm3b | Notes |
(GHz) | Log10 | (cm-1) | (D2) | (K km s-1) | (K km s-1) | (K km s-1) | (K km s-1) | ||
HCOOCH3 (ν = 1) | 218.966 | −4.619 | 259.918 | 53.255 | 2.17± 0.92 | 2.25± 0.00 | 2.87± 0.75 | 6.32± 1.03 | 1, 2, 3, 4 |
219.155 | −4.543 | 249.175 | 60.055 | 6.26± 0.74 | 4.81± 0.43 | 6.26± 0.58 | 9.44± 0.55 | ||
219.479 | −4.813 | 283.781 | 38.005 | − | − | 0.82± 0.24 | 2.06± 0.39 | ||
219.584 | −4.704 | 271.154 | 45.955 | 3.18± 0.48 | 3.05± 0.63 | 7.04± 0.63 | 10.08± 0.77 | ||
219.623 | −4.615 | 259.539 | 53.333 | 4.81± 0.98 | 5.55± 0.30 | 8.12± 0.56 | 12.94± 0.94 | ||
219.642 | −4.703 | 271.148 | 46.014 | − | − | 1.90± 0.35 | 3.39± 0.42 | ||
219.696 | −4.540 | 248.860 | 60.113 | 6.14± 0.79 | 6.47± 1.07 | 9.24± 0.43 | 14.74± 0.62 | ||
219.705 | −4.262 | 200.469 | 90.462 | 28.88± 5.46 | 12.16± 0.89 | 9.88± 0.34 | 18.45± 0.46 | ||
219.764 | −4.424 | 230.499 | 71.907 | 6.03± 1.97 | 6.18± 0.49 | 6.27± 0.40 | 11.04± 0.34 | ||
219.822 | −4.477 | 239.119 | 66.281 | 3.61± 1.27 | 5.22± 0.64 | 9.10± 0.86 | 14.66± 1.09 | ||
219.827 | −4.613 | 259.457 | 53.422 | 1.80± 0.36 | 1.50± 0.45 | 2.70± 0.71 | 5.69± 0.92 | ||
220.030 | −4.423 | 230.319 | 71.871 | 5.86± 0.61 | 8.35± 0.70 | 12.28± 1.32 | 20.35± 1.32 | ||
220.043 | −4.537 | 248.708 | 60.241 | 1.41± 0.56 | 2.99± 0.93 | 2.73± 0.00 | 5.84± 0.81 | ||
220.258 | −4.376 | 222.578 | 76.973 | 7.52± 0.88 | 6.85± 0.70 | 10.65± 0.67 | 16.40± 1.02 | ||
220.307 | −4.473 | 238.906 | 66.458 | 3.04± 0.66 | 4.45± 0.47 | 4.91± 0.35 | 9.25± 0.40 | ||
220.368 | −4.376 | 222.466 | 76.856 | 12.33± 3.46 | 15.04± 2.53 | 19.00± 1.36 | 32.09± 1.55 | ||
220.914 | −4.335 | 215.570 | 81.244 | 7.70± 1.43 | 11.26± 0.80 | 13.42± 1.22 | 21.02± 1.34 | ||
220.946 | −4.335 | 215.571 | 81.239 | 9.18± 1.53 | 11.30± 1.40 | 18.88± 0.53 | 31.07± 0.91 | ||
220.985 | −4.334 | 215.616 | 81.434 | 11.98± 4.04 | 15.49± 5.21 | 14.17± 2.53 | 27.29± 4.45 | ||
221.111 | −4.371 | 222.159 | 77.098 | − | − | 12.95± 2.31 | 19.97± 1.96 | ||
230.879 | −4.218 | 201.531 | 91.238 | 4.79± 1.00 | 8.03± 1.53 | 11.76± 0.68 | 22.34± 0.71 | ||
HCOOCH3 (ν = 0) | 219.417 | −5.168 | 195.355 | 10.989 | − | − | 1.57± 0.30 | 3.66± 0.38 | 1, 2, 3, 4 |
219.484 | −5.168 | 195.354 | 10.980 | − | 1.32± 0.35 | 2.00± 0.44 | 3.32± 0.43 | ||
219.592 | −5.055 | 197.439 | 14.378 | 0.90± 0.39 | 1.32± 0.32 | 2.77± 0.85 | 5.16± 1.00 | ||
220.167 | −3.999 | 64.350 | 85.865 | 38.44± 2.34 | 36.01± 2.02 | 57.74± 1.44 | 78.96± 1.40 | ||
220.190 | −3.999 | 64.344 | 85.884 | 24.45± 1.42 | 35.99± 1.39 | 60.42± 2.36 | 78.54± 2.59 | ||
220.812 | −4.986 | 66.218 | 8.871 | 5.91± 0.00 | 6.77± 0.98 | 10.22± 0.36 | 15.57± 0.85 | ||
220.815 | −4.987 | 66.210 | 8.869 | 5.24± 0.00 | 4.09± 0.93 | 8.71± 0.33 | 18.34± 0.93 | ||
220.926 | −4.867 | 180.745 | 20.185 | 4.25± 0.75 | 7.14± 0.54 | 9.34± 1.30 | 14.46± 1.19 | ||
220.935 | −4.867 | 180.739 | 20.183 | 5.12± 0.93 | 2.69± 0.98 | 4.89± 0.44 | 9.68± 0.51 | ||
220.978 | −4.675 | 166.459 | 29.375 | − | 8.52± 5.18 | 11.64± 1.66 | 20.14± 2.81 | ||
220.998 | −4.674 | 166.446 | 29.374 | 4.31± 1.48 | 6.80± 1.04 | 11.86± 0.98 | 17.70± 0.82 | ||
221.048 | −4.535 | 153.092 | 37.964 | 15.11± 1.64 | 30.75± 0.98 | 45.62± 0.93 | 73.34± 1.07 | ||
221.067 | −4.535 | 153.081 | 37.964 | 2.59± 0.61 | 9.24± 1.28 | 11.91± 0.48 | 21.32± 0.47 | ||
221.086 | −5.051 | 209.447 | 15.138 | 1.75± 0.61 | 1.43± 0.35 | 3.45± 1.09 | 5.03± 0.81 | ||
221.140 | −4.426 | 140.647 | 45.951 | 11.28± 2.24 | 37.37± 2.28 | 50.30± 0.70 | 88.58± 0.99 | ||
229.224 | −5.027 | 143.199 | 10.854 | − | 2.25± 0.48 | 2.71± 0.60 | 5.09± 0.53 | ||
229.259 | −5.092 | 143.201 | 9.338 | − | − | − | 3.27± 0.90 | ||
229.389 | −5.026 | 143.193 | 10.851 | 8.04± 0.00 | 4.31± 0.80 | 2.99± 0.27 | 6.82± 0.46 | ||
229.405 | −3.943 | 69.316 | 92.251 | 20.44± 1.05 | 37.31± 0.80 | 47.60± 1.09 | 72.27± 2.26 | ||
229.420 | −3.943 | 69.310 | 92.257 | 25.89± 1.12 | 37.54± 1.04 | 47.68± 1.72 | 73.39± 1.86 | ||
230.377 | −5.031 | 133.656 | 10.167 | − | 1.52± 0.56 | 4.07± 0.47 | 7.19± 0.41 | ||
230.436 | −5.566 | 118.982 | 2.761 | 1.40± 0.01 | − | 1.79± 0.05 | 3.20± 0.01 | ||
230.441 | −5.566 | 118.983 | 2.761 | 2.90± 0.81 | 2.37± 0.16 | 1.99± 0.43 | 4.53± 0.19 | ||
231.019 | −5.268 | 31.810 | 3.599 | 1.69± 0.73 | 5.69± 0.83 | 8.45± 0.51 | 14.60± 0.91 | ||
231.046 | −5.268 | 31.801 | 3.599 | − | − | 4.90± 0.78 | 13.58± 1.24 | ||
231.188 | −5.043 | 124.543 | 9.415 | 2.81± 0.83 | − | 4.06± 0.84 | 5.91± 0.76 | ||
231.199 | −5.039 | 124.546 | 9.492 | 6.55± 1.13 | 5.42± 0.96 | 11.01± 0.48 | 21.05± 0.96 | ||
CH3OH | 219.984 | −4.527 | 550.204 | 12.441 | 23.44± 0.53 | 5.96± 0.96 | 9.44± 6.00 | 6.13± 1.28 | 3, 5, 6 |
219.994 | −4.591 | 531.938 | 9.844 | 18.37± 1.44 | 8.99± 3.00 | 6.88± 0.57 | 10.65± 2.33 | ||
220.078 | −3.892 | 59.809 | 5.111 | 175.00± 9.00 | 163.50± 16.00 | 285.56± 23.00 | 300.80± 6.77 | ||
229.589 | −4.132 | 252.591 | 6.806 | 106.85± 2.03 | 56.47± 0.95 | 94.80± 16.00 | 114.36± 3.63 | ||
229.759 | −3.678 | 54.266 | 7.483 | 193.14± 2.06 | 209.17± 2.45 | 326.94± 1.27 | 359.76± 1.47 | ||
229.939 | −4.332 | 394.477 | 8.463 | 38.47± 1.03 | 14.97± 0.68 | 27.50± 1.10 | 28.46± 0.71 | ||
230.027 | −4.442 | 20.009 | 1.089 | 106.32± 1.44 | 100.37± 1.57 | 162.28± 1.84 | 179.02± 2.06 | ||
230.293 | −5.130 | 415.980 | 1.487 | 7.48± 1.02 | 6.23± 1.70 | 8.19± 1.58 | 14.36± 1.60 | ||
230.368 | −4.418 | 466.848 | 9.772 | 29.52± 1.24 | 12.79± 1.32 | 12.78± 1.02 | 16.73± 1.69 | ||
34SO2 | 219.355 | −3.036 | 34.438 | 20.782 | 192.87± 6.47 | 177.38± 3.74 | 78.92± 1.48 | 103.15± 2.72 | 5, 7, 8, 9 |
221.115 | −3.089 | 164.876 | 33.785 | 77.29± 6.98 | 28.80± 4.13 | 27.83± 1.59 | 23.11± 2.11 | ||
229.858 | −3.595 | 5.311 | 4.548 | 145.14± 3.13 | 79.54± 2.07 | 32.57± 2.65 | 30.12± 3.15 | ||
229.888 | −4.951 | 104.865 | 0.322 | 10.12± 0.75 | ≤ 0.91 | ≤ 0.51 | ≤ 0.30 | ||
229.987 | −4.310 | 631.573 | 17.640 | 4.01± 0.85 | 1.78± 0.44 | ≤ 0.75 | ≤ 1.20 | ||
230.933 | −4.466 | 28.220 | 0.676 | 7.63± 1.72 | 19.26± 1.63 | 6.97± 1.02 | 8.70± 1.75 | ||
HNCO | 218.981 | −2.677 | 62.949 | 70.596 | 145.59± 1.40 | 49.86± 1.43 | 42.52± 1.70 | 47.57± 3.08 | 5, 8, 10, 11 |
219.657 | −3.232 | 293.597 | 59.063 | 45.60± 1.57 | 5.91± 2.20 | 4.01± 1.46 * | 7.13± 1.24 * | ||
219.734 | −2.887 | 151.337 | 66.112 | 155.14± 2.02 | 26.39± 0.78 | 13.81± 0.45 | 15.35± 0.42 | ||
219.737 | −2.887 | 151.337 | 66.110 | 44.49± 1.89 | 15.39± 0.91 | 13.81± 0.45 | 15.35± 0.42 | ||
219.798 | −2.602 | 32.994 | 72.127 | 263.86± 3.43 | 120.56± 4.15 | 105.66± 1.53 | 131.98± 2.02 | ||
220.585 | −2.671 | 63.190 | 70.599 | 141.92± 4.26 | 35.20± 4.03 | 29.29± 2.42 | 40.71± 1.98 | ||
CH3OCH3 | 220.848 | −4.939 | 199.405 | 21.418 | 4.77± 1.13 | 5.27± 1.55 | 7.41± 0.97 | 10.65± 1.63 | 2, 8, 12 |
220.893 | −4.372 | 183.375 | 73.169 | 31.48± 2.58 | 22.98± 2.95 | 36.87± 2.65 | 57.36± 4.60 | ||
230.141 | −4.374 | 214.188 | 77.819 | 11.12± 1.27 | 14.20± 1.01 | 21.92± 0.64 | 27.49± 0.85 | ||
230.234 | −4.675 | 94.945 | 21.945 | 37.39± 3.46 | 29.69± 1.98 | 38.29± 2.58 | 52.30± 2.45 | ||
230.476 | −5.794 | 89.617 | 1.622 | 5.79± 1.80 | 3.75± 0.88 | 3.88± 0.82 | 7.47± 0.95 | ||
CH3CH2OH | 220.155t | −4.109 | 175.464 | 25.923 | 2.91± 0.69 | ≤ 0.75 | 1.66± 0.36 | 1.15± 0.30 | 2, 3, 7, 13, 14 |
230.673g | −3.995 | 88.651 | 20.283 | 3.09± 0.71 | 2.23± 1.45 | 5.06± 0.74 | 4.41± 0.81 | ||
230.794g | −4.508 | 65.142 | 5.557 | 6.23± 1.71 | ≤ 0.75 | 6.93± 0.82 | 5.33± 1.36 | ||
230.954t | −4.098 | 93.618 | 16.339 | 5.74± 1.69 | 3.36± 0.98 | 11.65± 1.27 | 6.88± 1.35 | ||
230.991t | −4.081 | 51.739 | 13.896 | 5.63± 1.24 | 5.02± 0.81 | 12.93± 0.86 | 9.16± 1.15 |
Notes. Uncertainties on the measured intensities are typically ≤10% (written as the subscript), as determined from Gaussian or HFS fitting. 1) None detection is marked with “−”; 2) integrated intensities of multiplet (blending) are obtained by Gildas “HFS” fittings; 3) laboratory parameters are given from JPL; 4) Q(300 K, HCOOCH3) = 199 602.70; 5) Integrated intensities are obtained by Gildas “Gaussian” fittings; 6) Q(300 K, CH3OH) = 9473.1198; 7) none detection is given by an upper limit of 3σ rms; 8) laboratory parameters are given from CDMS; 9) Q(300 K, 34SO2) = 6020.754; 10) Lines marked with “*” are blended with HCOOCH3 lines; 11) Q(300 K, HNCO) = 7785.741; 12) Q(300 K, CH3OCH3) = 228 016; 13) lines marked with with 14) Q(300 K, CH3CH2OH) = 45 583.66.
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