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Table 3

Summary of properties of selected transitions of TiO2.

ν Au,ℓ Au,ℓ n0 Trad ρrad
or vibrational band (GHz) (s-1) (s-1) (cm-3) (K) (s-1)

7(5,3)−6(4,2) 312.248 4.34 × 10-3 5.04 × 10-3 5 × 107 26.2 5.7 × 10-3
7(5,3)−7(4,4) 206.094 6.95 × 10-4 ... ... 15.3 7.6 × 10-4
7(5,3)−8(4,4) 84.567 7.31 × 10-6 ... ... 7.15 9.6 × 10-6
37(8,30)−37(7,31) 324.966 4.76 × 10-3 4.63 × 10-2 5 × 108 27.7 6.3 × 10-3
37(8,30)−36(9,27) 205.259 2.62 × 10-4 ... ... 15.2 2.9 × 10-4
37(8,30)−36(7,29) 821.811 2.96 × 10-2 ... ... 94.3 5.7 × 10-2
37(8,30)−36(5,31) 1235.577 1.17 × 10-2 ... ... 132.4 2.0 × 10-2
ν1 = 1−0 28 840 3.6 3.6 a 350 7.2 × 10-2
ν2 = 1−0 9863 7.2 × 10-2 7.2 × 10-2 a 300 2.0 × 10-2
ν3 = 1−0 28 030 42 42 a 350 9.0 × 10-1

Notes. Columns list the transitions (rotational and vibrational), the frequency ν at which these transitions occur, their transition probability Au,ℓ, inverse lifetime Au,ℓ, critical density n0, radiative temperature Trad and the calculated pumping rate ρrad.

(a)

Appropriate collision rates are unknown; therefore, no critical density is tabulated for the vibrational transitions.

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