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Fig. 2

image

Temperature dependent infrared spectra (recorded in reflection mode, resulting in twice the path length and twice the absorption or double absorption) taken during warm-up period of HC5N with a ramping rate of 1 K / min, 10 K (bottom), 35 K (middle bottom) after the first phase transition, 120 K (middle top) after the end of the second transition and 300 K (top).

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