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Table 4

Comparison between experimental and calculated energy levels in Ga iv.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Even parity
0.0 0 0 0 99 3d101S
149 512.1 149 518 −6 3 99 3d94s 3D
150 967.0 150 959 8 2 85 3d94s 3D + 14 3d94s 1D
153 085.9 153 087 −1 1 99 3d94s 3D
156 024.7 156 026 −1 2 85 3d94s 1D + 14 3d94s 3D
328 763.7 328 928 −164 1 91 3d94d 3S + 6 3d94d 3P
332 554.3 332 406 149 5 99 3d94d 3G
332 730.5 332 582 149 4 58 3d94d 3G + 41 3d94d 1G
332 757.5 332 749 8 2 76 3d94d 3P + 19 3d94d 3D
332 826.8 332 899 −72 1 46 3d94d 1P + 31 3d94d 3P + 22 3d94d 3D
333 964.2 333 770 194 3 90 3d94d 3D
334 403.3 334 393 10 0 98 3d94d 3P
334 527.6 334 931 −403 4 45 3d94d 3F + 33 3d94d 1G + 18 3d94d 3G
334 532.0 334 514 18 3 58 3d94d 3G + 24 3d94d 1F + 14 3d94d 3F
334 851.3 334 842 9 2 50 3d94d 3D + 25 3d94d 1D + 11 3d94d 3P
335 199.3 335 215 −16 1 54 3d94d 3P + 37 3d94d 1P + 8 3d94d 3S
336 581.6 336 527 54 3 41 3d94d 3G + 39 3d94d 1F + 17 3d94d 3F
336 790.0 336 893 −103 4 49 3d94d 3F + 25 3d94d 1G + 24 3d94d 3G
336 933.8 336 632 301 1 77 3d94d 3D + 15 3d94d 1P + 7 3d94d 3P
337 833.8 337 720 113 2 54 3d94d 1D + 25 3d94d 3D + 10 3d94d 3P
338 504.4 338 655 −150 3 56 3d94d 3F + 32 3d94d 1F + 8 3d94d 3D
338 719.6 338 835 −115 2 76 3d94d 3F + 15 3d94d 1D + 5 3d84s23F
343 319.9 343 325 −5 3 99 3d95s 3D
343 912.7 343 908 5 2 55 3d95s 3D + 44 3d95s 1D
346 887.6 346 885 3 1 99 3d95s 3D
347 402.8 347 407 −4 2 55 3d95s 1D + 44 3d95s 3D
355 225.3 355 225 0 0 79 3d94d 1S + 9 3d95d 1S + 8 3d84s23P
407 846.0 407 914 −68 1 79 3d95d 3S + 15 3d95d 3P + 6 3d95d 1P
409 158.0 409 134 24 5 100 3d95d 3G
409 280.0 409 177 103 4 50 3d95d 1G + 50 3d95d 3G
409 303.0 409 342 −39 1 50 3d95d 1P + 25 3d95d 3D + 24 3d95d 3P
409 319.0 409 327 −8 2 72 3d95d 3P + 26 3d95d 3D
409 716.0 409 775 −59 3 84 3d95d 3D + 12 3d95d 3F
410 107.0 410 192 −85 3 48 3d95d 1F + 31 3d95d 3F + 21 3d95d 3G
410 220.0 410 268 −48 4 80 3d95d 3F + 12 3d95d 1G + 8 3d95d 3G
410 264.0 410 084 180 2 51 3d95d 1D + 27 3d95d 3D + 16 3d95d 3F
411 044.0 411 050 −6 0 97 3d95d 3P
412 243.0 412 255 −12 1 51 3d95d 3P + 28 3d95d 1P + 21 3d95d 3S
412 803.0 412 812 −9 3 79 3d95d 3G + 13 3d95d 1F + 8 3d95d 3F
413 010.0 413 054 −44 1 74 3d95d 3D + 16 3d95d 1P + 9 3d95d 3P
413 074.0 412 978 96 4 42 3d95d 3G + 38 3d95d 1G + 19 3d95d 3F
413 187.0 413 203 −16 3 96 3d96s 3D
413 198.0 413 174 24 2 30 3d95d 3D + 23 3d95d 1D + 17 3d95d 3P
413 661.0 413 645 16 2 39 3d96s 1D + 33 3d96s 3D + 14 3d95d 3D
413 832.0 413 905 −73 3 47 3d95d 3F + 34 3d95d 1F + 15 3d95d 3D
413 902.0 413 871 31 2 81 3d95d 3F + 16 3d95d 1D
416 796.0 416 776 20 1 99 3d96s 3D
416 982.0 417 002 −20 2 52 3d96s 3D + 47 3d96s 1D
419 737.0 419 746 −9 0 72 3d95d 1S + 17 3d96d 1S
444 089.0 444 188 −99 1 66 3d96d 3S + 25 3d96d 3P + 8 3d96d 1P
444 706.0 444 674 32 5 100 3d96d 3G
444 765.0 444 688 77 1 53 3d96d 1P + 25 3d96d 3D + 22 3d96d 3P
444 767.0 444 663 104 4 53 3d96d 1G + 46 3d96d 3G
444 783.0 444 674 109 2 74 3d96d 3P + 21 3d96d 3D
444 979.0 445 069 −90 3 80 3d96d 3D + 15 3d96d 3F
445 193.0 445 243 −50 3 53 3d96d 1F + 31 3d96d 3F + 14 3d96d 3G
445 234.0 445 156 78 2 52 3d96d 1D + 28 3d96d 3D + 18 3d96d 3F
445 236.0 445 269 −33 4 86 3d96d 3F + 8 3d96d 1G + 6 3d96d 3G
446 071.0 446 283 −212 0 90 3d96d 3P + 6 3d96d 1S
446 732.0 446 731 1 3 99 3d97s 3D
446 852.0 446 853 −1 2 56 3d97s 1D + 43 3d97s 3D
448 059.0 448 029 30 1 43 3d96d 3P + 33 3d96d 3S + 23 3d96d 1P
448 347.0 448 388 −41 3 86 3d96d 3G + 9 3d96d 1F + 5 3d96d 3F
448 482.0 448 540 −58 1 74 3d96d 3D + 16 3d96d 1P + 9 3d96d 3P
448 527.0 448 453 74 4 47 3d96d 3G + 39 3d96d 1G + 14 3d96d 3F
448 734.0 448 631 103 2 45 3d96d 3D + 30 3d96d 1D + 24 3d96d 3P
448 913.0 448 973 −60 3 47 3d96d 3F + 35 3d96d 1F + 17 3d96d 3D
448 964.0 448 946 18 2 81 3d96d 3F + 13 3d96d 1D + 6 3d96d 3D
450 316.0 450 315 1 1 99 3d97s 3D
450 405.0 450 406 −1 2 57 3d97s 3D + 43 3d97s 1D
450 795.0 450 781 14 0 52 3d96d 1S + 32 3d97d 1S + 10 3d96d 3P
Odd parity
224 243.3 224 311 −67 2 96 3d94p 3P
227 320.4 227 340 −20 1 96 3d94p 3P
227 681.2 227 655 27 3 68 3d94p 3F + 27 3d94p 1F
228 952.8 228 891 62 4 99 3d94p 3F
229 140.3 229 131 10 0 99 3d94p 3P
230 040.0 230 003 37 2 94 3d94p 3F
233 192.3 233 213 −21 3 62 3d94p 1F + 23 3d94p 3D + 15 3d94p 3F
233 824.7 233 857 −33 2 62 3d94p 1D + 33 3d94p 3D
234 939.5 234 889 50 3 73 3d94p 3D + 16 3d94p 3F + 10 3d94p 1F
236 311.9 236 303 9 1 66 3d94p 1P + 33 3d94p 3D
236 906.5 236 923 −17 1 64 3d94p 3D + 32 3d94p 1P
237 458.0 237 494 −36 2 59 3d94p 3D + 37 3d94p 1D
368 684.0 368 705 −21 2 94 3d95p 3P + 6 3d95p 3D
369 718.0 369 714 4 3 57 3d95p 3F + 38 3d95p 1F + 5 3d95p 3D
370 123.0 370 092 31 4 100 3d95p 3F
370 458.0 370 465 −7 1 72 3d95p 3P + 22 3d95p 1P + 6 3d95p 3D
371 295.0 371 306 −11 2 43 3d95p 1D + 30 3d95p 3D + 24 3d95p 3F
371 636.0 371 636 0 3 81 3d95p 3D + 18 3d95p 1F
372 649.0 372 647 2 0 100 3d95p 3P
373 171.0 373 160 11 2 74 3d95p 3F + 23 3d95p 1D
373 824.0 373 822 2 1 76 3d95p 1P + 24 3d95p 3P
374 167.0 374 171 −4 3 44 3d95p 1F + 42 3d95p 3F + 14 3d95p 3D
374 883.0 374 870 13 1 94 3d95p 3D
375 134.0 375 154 −20 2 60 3d95p 3D + 34 3d95p 1D
397 883.9 397 877 7 0 100 3d94f 3P
398 043.0 398 036 7 1 86 3d94f 3P + 11 3d94f 3D
398 319.7 398 317 3 2 51 3d94f 3P + 30 3d94f 3D + 18 3d94f 1D
398 486.2 398 502 −15 6 100 3d94f 3H
398 489.8 398 513 −23 5 54 3d94f 1H + 46 3d94f 3H
398 851.5 398 848 3 2 40 3d94f 1D + 34 3d94f 3F + 25 3d94f 3D
398 866.0 398 850 16 3 66 3d94f 3D + 24 3d94f 3F + 10 3d94f 1F
398 927.7 398 925 3 1 52 3d94f 3D + 46 3d94f 1P
399 165.8 399 158 7 4 65 3d94f 3F + 32 3d94f 3G
399 175.9 399 178 −2 5 82 3d94f 3G + 9 3d94f 3H + 9 3d94f 1H
399 181.0 399 186 −5 4 55 3d94f 1G + 18 3d94f 3G + 16 3d94f 3H
399 205.0 399 207 −2 3 47 3d94f 1F + 29 3d94f 3F + 24 3d94f 3G
401 836.6 401 828 9 2 49 3d94f 3P + 31 3d94f 3D + 20 3d94f 1D
402 191.0 402 208 −17 5 44 3d94f 3H + 38 3d94f 1H + 18 3d94f 3G
402 196.0 402 197 −1 4 82 3d94f 3H + 10 3d94f 1G + 8 3d94f 3G
402 353.4 402 355 −2 1 50 3d94f 1P + 37 3d94f 3D + 13 3d94f 3P
402 546.1 402 537 9 2 65 3d94f 3F + 21 3d94f 1D + 13 3d94f 3D
402 567.4 402 564 4 3 40 3d94f 3F + 33 3d94f 3D + 26 3d94f 1F
402 838.6 402 844 −5 4 42 3d94f 3G + 35 3d94f 1G + 23 3d94f 3F
402 844.6 402 841 3 3 75 3d94f 3G + 17 3d94f 1F + 8 3d94f 3F
403 072.0 403 051 21 4 90 3d8(3F)4s4p 5D + 5 3d8(3P)4s4p 5D
405 366.0 405 403 −37 3 87 3d8(3F)4s4p 5D + 6 3d8(3P)4s4p 5D
407 383.0 407 365 18 2 87 3d8(3F)4s4p 5D + 7 3d8(3P)4s4p 5D
408 135.0 408 137 −2 4 78 3d8(3F)4s4p 5G + 11 3d8(3F)4s4p 5F
412 166.0 412 133 33 4 79 3d8(3F)4s4p 5F + 10 3d8(3F)4s4p 5G
413 211.0 413 183 28 3 81 3d8(3F)4s4p 5F + 8 3d8(3F)4s4p 5G
413 850.0 413 845 5 2 87 3d8(3F)4s4p 5F
414 099.0 414 131 −32 1 92 3d8(3F)4s4p 5F
414 379.0 414 428 −49 4 40 3d8(3F)4s4p 3G + 25 3d8(3F)4s4p 1G + 21 3d8(3F)4s4p 3G
415 296.0 415 349 −53 3 52 3d8(3F)4s4p 3D + 18 3d8(3F)4s4p 3D + 10 3d8(3F)4s4p 3F
416 606.0 416 638 −32 3 56 3d8(3F)4s4p 3G + 29 3d8(3F)4s4p 3G + 6 3d8(3F)4s4p 3D
416 647.0 416 676 −29 2 51 3d8(3F)4s4p 3D + 21 3d8(3F)4s4p 3D + 8 3d8(3F)4s4p 3F
418 395.0 418 394 1 1 56 3d8(3F)4s4p 3D + 25 3d8(3F)4s4p 3D + 9 3d8(1D)4s4p 3D
418 405.0 418 507 −102 4 54 3d8(3F)4s4p 3F + 34 3d8(3F)4s4p 3F + 5 3d8(3F)4s4p 5F
419 057.0 419 107 −50 3 36 3d8(3F)4s4p 3F + 22 3d8(3F)4s4p 3F + 19 3d8(3F)4s4p 1F
420 572.0 420 614 −42 2 51 3d8(3F)4s4p 3F + 29 3d8(3F)4s4p 3F + 8 3d8(3F)4s4p 3D
420 623.0 420 636 −13 4 69 3d8(3F)4s4p 1G + 15 3d8(3F)4s4p 3G + 11 3d8(3F)4s4p 3G
423 151.0 423 149 2 2 82 3d8(3F)4s4p 1D
423 434.0 423 496 −62 3 70 3d8(3F)4s4p 1F + 9 3d8(3F)4s4p 3F + 7 3d8(3F)4s4p 3F
424 901.0 424 934 −33 2 91 3d96p 3P + 8 3d96p 3D
425 253.0 425 229 24 2 82 3d8(3P)4s4p 5P + 5 3d8(3F)4s4p 1D
425 368.0 425 393 −25 3 51 3d96p 3F + 42 3d96p 1F + 5 3d96p 3D
425 552.0 425 522 30 4 100 3d96p 3F
425 604.0 425 561 43 3 83 3d8(3P)4s4p 5P + 6 3d8(1D)4s4p 3D
425 702.0 425 624 78 1 93 3d8(3P)4s4p 5P
425 853.0 425 849 4 1 48 3d96p 3P + 43 3d96p 1P + 8 3d96p 3D
426 175.0 426 178 −3 3 85 3d96p 3D + 14 3d96p 1F
426 180.0 426 163 17 2 52 3d96p 1D + 33 3d96p 3D + 11 3d96p 3F
428 648.0 428 635 13 0 100 3d96p 3P
428 828.0 428 831 −3 2 84 3d96p 3F + 11 3d96p 1D
429 003.0 429 015 −12 1 51 3d96p 1P + 49 3d96p 3P
429 305.0 429 281 24 3 47 3d96p 3F + 43 3d96p 1F + 9 3d96p 3D
429 594.0 429 591 3 1 90 3d96p 3D + 6 3d96p 1P
429 685.0 429 707 −22 2 52 3d96p 3D + 34 3d96p 1D + 5 3d96p 3P
429 866.0 429 879 −13 2 69 3d8(1D)4s4p 3F + 6 3d8(1D)4s4p 3D + 5 3d96p 3D
430 492.0 430 454 38 3 69 3d8(1D)4s4p 3F + 7 3d8(3P)4s4p 5D + 5 3d8(1G)4s4p 3F
430 682.0 430 791 −109 1 49 3d8(1D)4s4p 3D + 15 3d8(1D)4s4p 3P + 11 3d8(3F)4s4p 3D
431 242.0 431 358 −116 2 58 3d8(1D)4s4p 3D + 8 3d8(1D)4s4p 3F + 7 3d8(3F)4s4p 3D
431 353.0 431 214 139 4 64 3d8(1D)4s4p 3F + 22 3d8(3P)4s4p 5D + 9 3d8(1G)4s4p 3F
431 957.0 432 142 −185 3 72 3d8(1D)4s4p 3D + 7 3d8(3P)4s4p 5P + 5 3d8(1D)4s4p 3F
432 846.0 432 714 132 1 43 3d8(1D)4s4p 3P + 30 3d8(1D)4s4p 3D + 11 3d8(3P)4s4p 3P
433 778.0 433 683 95 2 67 3d8(1D)4s4p 3P + 14 3d8(1D)4s4p 3D + 5 3d8(3P)4s4p 3P
434 722.0 434 587 135 2 84 3d8(3P)4s4p 5D + 7 3d8(3F)4s4p 5D
434 846.0 434 911 −65 3 79 3d8(3P)4s4p 5D + 8 3d8(1D)4s4p 3F + 5 3d8(3F)4s4p 5D
435 419.0 435 414 5 4 69 3d8(3P)4s4p 5D + 14 3d8(1D)4s4p 3F + 12 3d8(1G)4s4p 3F
437 787.0 437 649 138 2 30 3d8(3P)4s4p 3P + 17 3d95f 3P + 15 3d95f 3D
439 390.0 439 207 183 1 31 3d8(3P)4s4p 3P + 19 3d8(1D)4s4p 3P + 12 3d8(3P)4s4p 3D
440 111.0 440 153 −42 2 34 3d8(3P)4s4p 3D + 18 3d8(3P)4s4p 3D + 11 3d8(3P)4s4p 3P
440 188.0 440 281 −93 3 40 3d8(3P)4s4p 3D + 23 3d8(3P)4s4p 3D + 12 3d8(3F)4s4p 3D
440 229.0 440 237 −8 1 39 3d8(3P)4s4p 3D + 19 3d8(3P)4s4p 3D + 11 3d8(3P)4s4p 1P
440 723.0 440 581 142 0 46 3d8(3P)4s4p 3P + 37 3d8(1D)4s4p 3P + 11 3d8(3P)4s4p 3P
441 367.0 441 414 −47 4 51 3d8(1G)4s4p 3F + 14 3d8(1D)4s4p 3F + 13 3d8(3F)4s4p 3F
442 220.0 442 672 −452 3 47 3d8(1G)4s4p 3F + 10 3d8(1D)4s4p 3F + 9 3d95f 3F
442 837.0 442 870 −33 2 95 3d8(3P)4s4p 5S
443 344.0 443 090 254 1 74 3d8(3P)4s4p 1P + 6 3d8(3P)4s4p 3P + 5 3d8(1D)4s4p 3P
443 322.0 443 193 129 2 67 3d8(1G)4s4p 3F + 7 3d8(1D)4s4p 3F + 7 3d8(3F)4s4p 3F
444 074.0 444 163 −89 3 54 3d8(3F)4s4p 3D + 20 3d8(3F)4s4p 3D + 9 3d8(3P)4s4p 3D
444 348.0 444 392 −44 2 79 3d8(3P)4s4p 1D
444 968.0 444 768 200 4 39 3d8(3F)4s4p 3G + 24 3d8(3F)4s4p 3G + 12 3d8(3F)4s4p 3F
446 456.0 446 332 124 4 38 3d8(3F)4s4p 3F + 19 3d8(3F)4s4p 3F + 14 3d8(3F)4s4p 3G
446 917.0 446 948 −31 2 55 3d8(3F)4s4p 3D + 22 3d8(3F)4s4p 3D + 8 3d8(3P)4s4p 3D
447 014.0 446 771 243 3 52 3d8(3F)4s4p 3G + 29 3d8(3F)4s4p 3G + 5 3d8(3F)4s4p 3F
448 614.0 448 611 3 1 58 3d8(3F)4s4p 3D + 25 3d8(3F)4s4p 3D + 7 3d8(3P)4s4p 3D
448 773.0 448 704 69 3 49 3d8(3F)4s4p 3F + 25 3d8(3F)4s4p 3F + 8 3d8(1G)4s4p 3F
450 162.0 450 142 20 2 55 3d8(3F)4s4p 3F + 27 3d8(3F)4s4p 3F + 7 3d8(1G)4s4p 3F
462 491.0 462 616 −125 2 48 3d8(1D)4s4p 1D + 25 3d8(3P)4s4p 3P + 10 3d8(3P)4s4p 3P
463 246.0 463 067 179 3 64 3d8(1D)4s4p 1F + 12 3d96f 3G + 6 3d96f 3D
464 221.0 464 310 −89 1 43 3d8(3P)4s4p 3P + 28 3d8(1D)4s4p 1P + 15 3d8(3P)4s4p 3P
465 833.0 466 138 −305 0 70 3d8(3P)4s4p 3P + 24 3d8(3P)4s4p 3P
466 359.0 466 457 −98 2 38 3d8(3P)4s4p 3P + 37 3d8(1D)4s4p 1D + 16 3d8(3P)4s4p 3P
467 778.0 467 884 −106 1 55 3d8(1D)4s4p 1P + 25 3d8(3P)4s4p 3P + 9 3d8(3P)4s4p 3P
475 514.0 475 390 124 3 89 3d8(1G)4s4p 1F

Notes. Energies are given in cm-1.

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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