© ESO, 2015

1. Introduction

The active coronae of cool stars can be up to five orders of magnitude more luminous and an order of magnitude hotter than our own solar corona. Like the Sun, they emit both extreme UV (EUV) and soft X-rays. X-ray spectroscopy allows for particularly deep insights into the hot thermal content and elemental abundances of the corona. For comprehensive reviews see Güdel & Naze (2009) and Testa (2010). Solar coronal abundances are different from the solar photospheric composition. The abundance patterns depend on the first ionization potential (FIP; Meyer 1985; Feldman 1992). Elements with FIP < 10 eV (low FIP) are enriched in the corona relative to elements with FIP > 10 eV (high FIP). Averaging over the entire solar disk, the enrichment factor is about 4 (Feldman & Widing 2002,and references therein). Currently, there is no generally accepted model that explains the FIP bias (but see Laming 2004; Telleschi et al. 2005; Laming 2012). Nevertheless, the observed reality of abundance fractionation is undisputed, although the absolute normalization of the solar coronal abundances is still being debated (cf., Schmelz et al. 2012).

The FIP effect became even more puzzling when high-resolution X-ray spectra from XMM-Newton and Chandra revealed that active stellar coronae do not follow the solar FIP pattern. In some cases, the high-FIP elements are even enriched compared to the low-FIP ones, an effect labeled inverse-FIP (IFIP) effect (Brinkman et al. 2001). Later studies revealed that FIP and IFIP biases are correlated with coronal activity (e.g., X-ray luminosity) and age: highly active stars show an IFIP effect, while less active coronae have a solar FIP bias (Audard et al. 2003; Telleschi et al. 2005), implying a transition on stellar evolution time-scales of Gyr. Intervening intermediate-activity stars seem to exhibit a relatively flat dependence on FIP. Ball et al. (2005) even suggested a U-shaped dependence, although such subtleties depend on one or two elements at most. Some more recent observations of stellar coronae have found that there are deviations from this behavior for some stars, however, and that there could be additional factors that determine coronal abundances, for example, spectral type (Güdel et al. 2007; Wood & Linsky 2010). In particular, the influence of stellar metallicity on stellar coronal properties is still unclear, since most of the stars with well-studied X-ray spectra have photospheric abundances similar (or assumed to be) to the solar photospheric values.

Moreover, as is the case on the Sun, different parts of a single corona may exhibit different abundances (Sanz-Forcada et al. 2004; Nordon et al. 2013). Wood & Linsky (2006) found that even though two stars may have very similar properties and activity levels (and being visual binary companions), 70 Oph A and 70 Oph B did not exhibit the same coronal abundance patterns.

Given the importance of the heavy elements in the cooling of plasmas with temperatures in the range from 10⁶ to 10^7.5 K, it is expected that metallicity could play a significant role in determining the thermal structure (the emission measure distribution, or EMD) of the coronae of such stars. For example, one might expect that in the absence of fractionization mechanisms, coronae with enhanced (depleted) heavy elements would be significantly cooler (hotter) than coronae with solar abundances. It is thus of considerable interest to study the coronal spectra of stars whose photospheric abundances differ the most from solar, so as to study how varying the source plasma abundances affects the properties of the coronal plasma that ultimately must originate from the underlying photosphere. In the present analysis we select several stars that are metal enriched with respect to solar from a mean factor of 1.5 to 2.7. We seek to determine whether coronal abundances behave in a FIP or IFIP behavior, and whether this behavior is a result of depletion or enrichment in either low-FIP or high-FIP elements.

The present study aims to test whether the FIP (or IFIP) effect can be accurately determined relative to stellar abundances. While the standard assumption of solar photospheric abundances may be valid in many cases, a true FIP trend requires the knowledge of true photospheric abundances, which was stressed by Sanz-Forcada et al. (2004). Photospheric abundances are difficult to measure and to some extent are model dependent, while coronal abundances are comparatively easily measured by counting X-ray photons in emission lines. The result is that a surprisingly small number of bright coronal sources also have reliable photospheric abundances. We proposed to observe 11 LMi after searching the literature for bright X-ray sources that have reliable photospheric abundances that are markedly different than solar. High-precision photospheric abundances of stars bright enough in X-ray such that well-exposed high-dispersion X-ray spectra can be obtained are few and far between in the literature.

Since different references for solar abundances are used by different authors, it is important to normalize all measurements to a standard solar reference. Abundances presented in this paper are normalized to the solar reference of Asplund et al. (2009).

2. Sample

2.1. Object selection

Objects for this study were chosen according to two criteria − high photospheric metallicity, and high-statistics X-ray spectra. Sources were filtered from Gonzalez & Laws (2007) and Allende Prieto et al. (2004). First, objects with supersolar abundances of C, O, Mg, Si, Fi, and Ni were selected if at least four of these sustained A_Z/H> 1.1. From these, all objects with X-ray grating observations of at least 1000 photon counts were selected, leaving five stars, two of which are in a binary system. In addition, 11 LMi was observed specifically in preperation for this analysis (see Drake et al. 2010). A summary of objects, their references, and some of their properties is given in Table 1.

The sample includes six nearby (<27 pc) stars with supersolar metallicities ranging from approximately 1.5 to 2.5 solar. Spectral types of the sample are between K1 and G8. X-ray luminosities span two orders of magnitude, from 10²⁷ to 10²⁹ erg s^-1. Although different photospheric abundance measurements for these object exist in the literature, they are predominantly supersolar.

The coronal abundances of 11 Leonis Minoris (11 LMi), ι Horologii (ι Hor), and HR 7291 are presented here for the first time, while measurements for the other three, τ Bootis (τ Boo) as well as α Centauri (α Cen) A and B, are already available in the literature. The coronal abundances of τ Boo and α Cen A, B were extensively analyzed by Maggio et al. (2011) and by Raassen et al. (2003) respectively. Maggio et al. (2011) found a flat FIP dependence, while Raassen et al. (2003) measured a solar-like FIP behavior.

2.2. Additional notes on objects

2.2.1. 11 LMi

A nearby moderately X-ray active star, 11 LMi has been erroneously classified as an RS CVn binary by Simbad – probably on the basis of its detection as a rotationally modulated (18.0 days) variable star (Skiff & Lockwood 1986). In fact, 11 LMi is not a spectroscopic binary according to Duquennoy & Mayor (1991), with an X-ray luminosity much lower than that of the RS CVn class of close binaries that usually exhibit L_X = 10³⁰⁻³² erg s^-1. According to Simbad, this star has usually been spectrally classified as a G8 IV-V or G8 V star. There is a much fainter (ΔV = 7.7 mag) visual binary companion 5′′ away from the G star, probably a mid-M dwarf with a binary orbit of 201 yr (see Malkov et al 2012). This companion is not the X-ray source since the ROSAT HRI source lies within 1′′ of the position of the G star. Soubiran & Girard (2005) considered 11 LMi to probably be a (95%) thin-disk star, consistent with its enhanced rotation rate and activity level compared to the Sun.

2.2.2. ι Hor

ι Hor (HD 17051) is a planet-hosting star that is dim in X-rays. The orbit of the exoplanet is approximately 311 days (Sanz-Forcada et al. 2013). In addition, it has a 1.6 yr magnetic activity cycle (Metcalfe et al. 2010). X-ray observations are detailed in Sanz-Forcada et al. (2013) where a XMM-Newton campaign was used to observe the activity cycle.

2.2.3. HR 7291

HR 7291 is an F8V star with a planet with an orbital period of 3 days. X-ray observations in this case are detailed in Scandariato et al. (2013), as part of a campaign to search for a planet-induced activity cycle.

2.2.4. τ Boo

This X-ray bright star hosts a planet with a 3.3-day period. Maggio et al. (2011) analyzed the FIP behavior of this object. No clear FIP (or IFIP) trend was observed. Instead, a flat dependence relative to both solar and actual photospheric abundances was found. In addition, there is a factor 4 of depletion across all elements observed in the corona relative to the photosphere.

2.2.5. α Cen binary

This spectroscopic binary is part of the nearest stellar system to the Sun (1.34 pc). Both stars are bright X-ray sources. Raassen et al. (2003) observed a FIP effect for both stars, relative to solar abundances.

2.3. Observations

The log of observations for the present sample is listed in Table 2. Count rates were averaged and exposure durations were summed. Four of these stars were observed in X-rays by XMM-Newton, while α Cen A and B were observed using Chandra.

The observations of 11 LMi, τ Boo, α Cen A, and B have sufficiently long exposures that result in high-quality grating spectra (see Maggio et al. 2011; Drake et al. 2010; Raassen et al. 2003, for details), making for reliable abundance measurements. On the other hand, ι Hor and HR 7291 were both observed intermittently during long observation sequences. As such, the photon count in each individual observation is low (around 200), and many observations exist (Sanz-Forcada et al. 2013; Scandariato et al. 2013). This makes the high-resolution spectra of the Refleciton Grating Spectrometer (RGS) noisy, and it is difficult to determine lines. Thus for these two objects the CCD-based European Photon Imaging Camera (EPIC) is more reliable for an abundance analysis (see Sect. 3.2.2).

3. Coronal abundance measurements

We measured the coronal abundances for three of the targets: 11 LMi, ι Hor, and HR 7291. These targets do not have published detailed X-ray abundances.

3.1. Methodology

We used the collisional ionization equilibrium (CIE) code VApec (Smith et al. 2001) within the standard XSPEC11¹ software package. Models were selected according to the best-fitting reduced χ² goodness test, and when several models were considered, the F-Test was used to determine the statistical robustness of the model selection. All fitting results, reduced χ², F-test, and uncertainty values were computed using XSPEC. All spectral plots in the paper show data rebinned to a minimal significance of 3σ for each data point, but not more than three bins, so as to retain the high resolution in the figures. However, the spectral fits use the original non-binned higher resolution.

In general, the RGS spectra would be preferred because of the high spectral resolution and the ability to visually inspect emission lines. However, meaningful results can only be obtained for 11 LMi (see Sect. 3.2.2). When no constraint could be obtained using the RGS, the abundances were measured using the EPIC-pn spectra. EPIC-pn is also advantageous for observing Mg and Si, which are visibly discernable and are generally lacking in the RGS spectra. We concentrated on the well-exposed EPIC-pn spectrum since it has more than enough counts, and hence we did not use data from the other EPIC-MOS detectors on XMM-Newton. For ι Hor and HR 7291 none of the RGS data were found useful (again, see Sect. 3.2.2).

Joint fits between RGS and EPIC-pn were considered but discarded. Since the EPIC-pn provides such a high photon count, the fit is dominated by the EPIC-pn alone and the high spectral resolution of the RGS is lost. Since both ι Hor and HR 7291 have multiple low-count observations, RGS data are highly noisy and only Fe/O ratios can be constrained. Therefore only EPIC-pn was used for these targets. A joint fit of all observations was attempted, but significant differences in flux levels between observations rules out a single model that fits all data well (reduced χ²> 2). Instead, each observation was fit seperately and results were averaged (see Sect. 3.2.2).

3.1.1. RGS analysis

When modeling the RGS spectrum (11 LMi only), we used wavelengths between 7−37 Å where the signal-to-noise ratio (S/N) is high enough to visibly detect lines. The free parameters of each thermal component are the temperature T and the elemental abundances A_Z of the plasma, as well as the emission measure (). Testing for multiple T components, for 1T,2T,3T, and 4T the reduced χ² is minimal for the 3T model with a value of 1.08. In addition, we conducted an F-test to check for statistical advantage of adding components. As expected, the model with 3T model is statistically advantageous (null hypothesis probability of <10^-3 when compared to any other model). We thus deem the 3T model to be the most appropriate approximation of what is probably a continuous EMD. All models with two or more temperatures yield consistent relative abundances to within the errors, which increases our confidence in the derived values.

Abundances were held constant between temperature components assuming abundance dispersion does not change along the EMD. Since no hydrogen lines are available in X-ray spectra, it is necessary to freeze the abundance of one of the observed elements to avoid the inherent degeneracy between the overall metal abundances and the EM. This limits the measurement to relative abundances of the observed elements. We chose to fix the Fe abundance to its solar value (again, Asplund et al. 2009), as Fe-L lines originate from a wide range of T. Hence, we were able to fit for the abundances of C, N, O, Ne, and Ni while all other elements were set to their solar values. Indeed, the attempt to fit for the Mg and Si abundances failed, which forced us to completely freeze their values to solar as well. Nevertheless, the 3T collisional ionization model reproduces all featured RGS spectral lines well, providing robust results for our free abundance parameters and their uncertainties. Moreover, setting the Mg and Si values to arbitrarily high or low values has little to no effect on the fit, and no meaningful constraint on these abundances could be derived from the data.

3.1.2. EPIC-pn

Since the absolute coronal abundances (relative to H) are key to this study because of the supersolar abundances in the photosphere (Sect. 1) and since the RGS falls short in providing absolute values, we must constrain absolute abundances with the EPIC-pn camera. While not as accurate as the RGS in determining line positions, the high sensitivity of the EPIC-pn is advantageous for measuring the bremsstrahlung continuum, which is mostly due to H. We thus fit the EPIC-pn spectrum without fixing any of the observable elements to check wether we could obtain absolute abundances that are not degenerate with the normalization (EM). Since the effective area curve of EPIC-pn covers the band of ~1.5−30 Å (0.4−10 keV), which is somewhat different from that of the RGS, the model for fitting its spectrum may have a less detailed thermal structure. We tested both 2T and 3T models, as suggested by the RGS fits, (for ι Hor and HR 7291 as well). The third T component does not improve the fit (reduced χ²), nor does it reduce the uncertainties on the model parameter values. Consequently, we preferred the simpler 2T model, and all EPIC-pn results are given for this model. The Mg and Si emission lines, which are usually lacking in most RGS spectra, are clearly seen around 9 Å and 6.6 Å in all EPIC-pn spectra we analyzed.

3.2. Results

3.2.1. 11 LMi

The full RGS spectrum of 11 LMi is presented in Fig. 1, along with the residual plot beneath. An inspection of the spectrum clearly indicates the presence of the usual main coronal emission lines (e.g., Behar et al. 2001), with the Fe L-shell dominating between 12−18 Å, O K-shell at 19−23 Å, and C K-shell at ~34 Å being strong as well. The Ne–K (12−14 Å) and N–K (~25 Å) lines are weaker. Still, they are easily seen. At lower wavelengths, Mg–K is just barely detected around 8−9 Å, while Si–K (6−7 Å) is not detected at all and is not included in Fig. 1. The best-fit parameters of the model are presented in Table 3. along with their 1σ uncertainties. All of the abundance ratios of Fe are consistent with solar values at the 1σ level.

	Fig. 1 RGS spectrum of 11 LMi between 7−37 Å (data points) and best-fit model (red solid line). Residuals are plotted in the bottom panel. The data in the figure are rebinned to 3σ, but not more than three bins.
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	Fig. 2 EPIC-pn spectrum of 11 LMi with best-fit model (in red). Mg and Si emission lines are seen around 9 Å and 6.6 Å. The high statistics allows us to obtain absolute abundances by constraining the line emission (metals) with respect to the continuum (mostly H). Residuals are plotted in the bottom panel. The data in the figures are rebinned to 3σ, but not more than three bins.
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The EPIC-pn spectrum and best-fit model are presented in Fig. 2 and are included in Table 3. For the most part, all values are consistent between RGS and EPIC-pn to within the 1σ level (except Ni/H at 2σ), but clearly, some abundance measurements are not very constraining. Certainly, the low spectral resolution available with EPIC-pn and the low S/N available with the RGS could be blamed for this. We used the RGS absolute abundances of C, N, O, Ne, and Ni, and the EPIC-pn for Mg, Si, and Fe.

	Fig. 3 Contours for 11 LMi of overall normalization representing EM (ratio of two thermal components tied) and Fe abundance, while ratios of all other metal abundances to Fe (AZ/AFe) are set to their EPIC-pn best-fit values. The ability to obtain absolute metal abundances with confidence to the level of 3σ is demonstrated.
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We next wish to ensure that the best-fit solution is not degenerate between its overall metal abundances (metallicity) and the total EM. To obtain a confidence contour for the metallicity in the corona of 11 LMi, we tied all best-fit abundance ratios to Fe and also tied the EM ratio of the two components (temperatures were fixed), effectively leaving only two free parameters − namely the metallicity and EM. The resulting confidence contours are presented in Fig. 3. The Fe abundance (with all metals tied to their EPIC-pn fitted ratio to Fe) is tightly constrained between 0.8−1.1 to 3σ. This result gives a tighter constraint, yet is fully consistent with the 0.8−1.5 (1σ) Fe abundance of the full model, where all abundances were allowed to vary.

3.2.2. ι Hor and HR 7291

For ι Hor and HR 7291 only the EPIC-pn spectra were used. Temperature variability between observations was the goal and is indeed present during these campaigns. Consequently, a simultaneous fit to all observations with a single 2T CIE model yields an unacceptable fit (reduced χ²> 3). Therefore, each of the 14 (15) observations of ι Hor Hor (HR 7291) were fitted separately. Since we do not find significant variations of the abundances to within 2σ and the vast majority are consistent to 1σ, we averaged the best-fit abundance values across observations. Admittedly, a few observations are clearly of poor quality, as evident by their reduced χ²> 2 fits or their very large parameter uncertainties. Hence, we cannot rule out abundance variability. Nevertheless, to avoid outliers due to low statistics, the few observations with abundances that are more than 1σ different from the average were discarded (two for ι Hor, four for HR 7291). If the abundances are truly constant, we significantly improve the constraints on the fitted abundances by averaging the results. The standard error was calculated for each elemental abundance and is consistently lower than the statistical errors of each fit (by a factor of 2 at most). Of course, this result is only valid if CIE is prevalent in the plasma for each individual observation.

The results are presented in Table 4 for the best-fitting models with average reduced χ² = 1.0 for both ι Hor and HR 7291, including observations with both high and low reduced χ² (>1.2 and <1). Clearly, abundances averaged from all fits provide well-constrained values for all elements, although some could not be resolved by EPIC-pn or are missing completely, for example, N. The same method as described in Sect. 3.2.1 was used to obtain contour plots between metallicity and EM. We present here a single contour plot for example, since most enclose similar values in parameter space and our final constraints are much better than that of a single observation. Spectra and contour plots are presented in Figs. 4 and 5. The fact that the Fe abundance (representing metallicity) is tightly constrained to 3σ in all three analyzed objects to a range of 0.3−0.8 in solar units boosts our confidence in the absolute abundances with respect to H of all elements.

	Fig. 4 ι Hor (top) and HR 7921 (bottom) EPIC-pn spectra, model, and residuals.
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	Fig. 5 Example contours of overall normalization representing EM and Fe abundance (metallicity, as in Fig. 3) for ι Hor (top) and HR 7291 (bottom). Abundances were constrained much more by averaging across multiple observations.
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4. Coronal abundances from the literature

Coronal abundances of τ Boo and α Cen A and B are only quoted here and not measured again, since high-quality measurements are already available. In Table 5 we list these and the above measured abundances and compare them with their respective photospheric abundances taken from the literature (see Table 1). Since N and Ne are only measured in the coronae and not in the photospheres, an effective comparison can only be made for five elements − C, O, Mg, Si, and Fe. All abundances are given relative to Asplund et al. (2009). Note that photospheric ranges represent those values found in the literature, whereas coronal ranges are the measured 1σ uncertainties. Overall, coronal abundances are significantly lower than their supersolar photospheric counterparts. In the next section the FIP trends of all these stars are discussed.

5. Discussion

5.1. FIP effect

The dependence of abundances on FIP is plotted in Fig. 7. Abundances are normalized to solar (Asplund et al. 2009), and photospheric values are shown for comparison. The FIP behavior may thus be compared to both solar and actual abundances. While the uncertainties of the coronal abundances in the figure are those measured in the present analysis or referenced in Sect. 2.1, the uncertainties of the photospheric data only reflect the range of values in the literature. The lack of real errors on the photospheric values somewhat hinders a meaningful comparison, although by combining several literary sources we obtain a sense of the constraint on these abundances.

The first obvious result observed is that depletion of elements differs significantly when comparing to solar abundances instead of using actual photospheric abundances. Furthermore, high-FIP elements are strongly depleted in all stars in the sample. Thus, objects displaying a FIP effect show little to no depletion of low-FIP elements (unlike the solar corona, which displays an increase of low-FIP elements), and objects displaying no FIP effect show a more even depletion (11 LMi, τ Boo). For α Cen, a comparison with solar and actual photospheric abundances leads to the same FIP behavior, but to differing conclusions regarding the origin of the effect.

11 LMi shows no FIP dependence with respect to solar abundances. When comparing with the supersolar photospheric abundances, most significantly Si, but also Ni and possibly Mg are depleted, which may give the impression of an inverse FIP (IFIP) effect. However, Fe, which is a low-FIP element, is not significantly depleted, while O, a typical high-FIP element, is depleted, both of which argue against an IFIP effect.

In ι Hor the low-FIP elements do not significantly deplete with respect to the photosphere, although they appear to be supersolar. O in the corona is significantly depleted with respect to the supersolar photosperic value, producing a solar-like FIP effect.

HR 7291 shows a rather flat depletion across the FIP axis. There seems to be an enhanced depletion with increasing FIP that creates a solar-like FIP trend as in ι Hor. In this case, the depletion of Ne reinforces this effect. τ Boo is similar to 11 LMi as all elements are depleted relative to the photosphere with no I/FIP effect evident. Depeletion in this case is much stronger than in the actual photospheric abundances.

	Fig. 6 FIP bias values for the current sample plotted against spectral type, using only C, N, O, Ne, Fe as defined in Wood & Linsky (2010), only negative. Objects marked with an X were already included in Wood & Laming (2013). Solid lines bound all of the stars in Wood et al. (2012) except for one.
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Fig. 7 Elemental abundances in solar units of the six coronae (black symbols) as a function of the first ionization potential (FIP) compared with the photospheric values (red). Line at 1 represents solar (Asplund et al. 2009). Note photospheric abundance ranges represent literature ranges and not actual uncertainties. A FIP effect is observed for ι Hor, HR 7291, α Cen A and B, which is not true for 11 LMi and τ Boo. Clearly, abundance trends relative to solar and relative to actual photospheric values are not always consistent.

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The two α Cen stars exhibit a stronger FIP effect in their coronae when compared relative to their actual photospheric abundances rather than to solar photospheric abundances, and this is the result of the depletion of high-FIP elements rather than the enrichment of low-FIP elements. When comparing their coronal abundances to solar photospheric abundances, the FIP effect persists, but now would be due to the enrichment of low-FIP elements, while high-FIP elements remain essentially unchanged.

5.2. FIP bias and dependence on spectral type

Continuing our discussion in a more quantitative manner, one can define a FIP bias, for instance, in Nordon & Behar (2008), (1)where are the average abundances of low-(<10 eV)/high-(>10 eV) FIP elements. Hence, positive/negative FB values reflect a FIP/IFIP bias. FIP biases are summarized in Table 6. Errors are calculated assuming Gaussian distribution and symmetrizing the errors (average of errors if not originally symmetric). We provide three measures here − relative to solar values (using all coronal measurments), relative to existing photospheric values (using only elements measured in both corona and photosphere) and a measure used by Wood & Linsky (2010; with a negative sign) restricting the FB to the ratio of C, N, O, and Ne (or the available subset) over Fe (solar reference). 11 LMi and τ Boo are consistent with FB = 0 in all measures. On the other hand, ι Hor, HR 7291, and α Cen A and B exhibit significant FIP bias with FB> 0 consistent with Fig. 7. The FIP bias with respect to photospheric abundances introduces more uncertainties coming from the photospheric uncertainties, while the other two measures generally have smaller uncertainties because no error on the solar abundances is assumed. Photospheric measurments with only one reference suffer from the same shortcoming.

The present FIP biases from Col. 3 in Table 6 are compared with the trend reported by Wood & Linsky (2010) in Fig. 6. Note the definition here is the negative of the one defined there. In that paper a striking correlation of FIP bias with spectral type (Fig. 9 therein) is observed for main-sequence G, K, M dwarfs, which was later extended in Wood et al. (2012) and Wood & Laming (2013). In the present paper spectral types fall within the range studied in those papers, which have already included τ Boo, and α Cen A and B. Though no obvious trend is apparent for the present sample, five of six (at least marginally) fall within the FIP bias-spectral type correlation band (see Fig. 6). The outlier is τ Boo (spectral type F6), as already noted in Wood & Laming (2013) along with Procyon (F5), which lies even farther away (FB = −0.1). On the other hand, HR 7291, which is of similar spectral type as Procyon and τ Boo (F8), falls nicely on the correlation (Fig. 6).

6. Conclusions

We compared the coronal abundances of six stars with their supersolar photospheric abundances. For three of them, 11 LMi, ι Hor, and HR7291, we measured absolute coronal abundances from their X-ray spectra.

• Coronal abundances of all stars are depleted compared to their respective photospheres. Since photospheric abundances are significantly higher than solar, depletion is much greater than when comparing to solar abundance values.

• Four of six stars show a positive FIP bias, while the other two have no FIP bias. When a FIP effect is present, it is different from the solar FIP effect. In the present sample it appears that the high-FIP elements are depleted, while in the solar corona it is generally accepted that the low-FIP elements are enriched (but this is still disputed, e.g., Schmelz et al. 2012).

• Five of the stars (all but τ Boo) are consistent with a correlation of FIP bias with spectral type (Wood & Linsky 2010; Wood & Laming 2013).

• The importance of knowing the actual photospheric abudances was exemplified by α Cen A and B. In these two, the FIP bias is the same regardless of photospheric reference. Solar assumptions misleadingly imply enrichement of low-FIP elements, while in fact the high-FIP elements are depleted. This would lead to different fractionation trends despite the similarity in FIP bias.

In conclusion, high-fidelity measurements of photospheric abundances for additional stars with well-determined coronal abundances would be highly desirable. Coronal abundance models should try to explain the phenomena of FIP-independent overall coronal metal depletion in stars with supersolar abundances, as well as a more significant high FIP element depletion.

Acknowledgments

The authors are grateful to an anonymous referee for useful comments that led us to broaden the sample of the paper. This research is supported by the I-CORE program of the Planning and Budgeting Committee and the Israel Science Foundation (grant numbers 1937/12 and 1163/10), and by a grant from Israel’s Ministry of Science and Technology. This work was supported in part by the National Science Foundation under Grant No. PHYS-1066293 and the hospitality of the Aspen Center for Physics.

References

All Tables

All Figures

	Fig. 1 RGS spectrum of 11 LMi between 7−37 Å (data points) and best-fit model (red solid line). Residuals are plotted in the bottom panel. The data in the figure are rebinned to 3σ, but not more than three bins.
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In the text

	Fig. 2 EPIC-pn spectrum of 11 LMi with best-fit model (in red). Mg and Si emission lines are seen around 9 Å and 6.6 Å. The high statistics allows us to obtain absolute abundances by constraining the line emission (metals) with respect to the continuum (mostly H). Residuals are plotted in the bottom panel. The data in the figures are rebinned to 3σ, but not more than three bins.
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In the text

	Fig. 3 Contours for 11 LMi of overall normalization representing EM (ratio of two thermal components tied) and Fe abundance, while ratios of all other metal abundances to Fe (AZ/AFe) are set to their EPIC-pn best-fit values. The ability to obtain absolute metal abundances with confidence to the level of 3σ is demonstrated.
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In the text

	Fig. 4 ι Hor (top) and HR 7921 (bottom) EPIC-pn spectra, model, and residuals.
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In the text

	Fig. 5 Example contours of overall normalization representing EM and Fe abundance (metallicity, as in Fig. 3) for ι Hor (top) and HR 7291 (bottom). Abundances were constrained much more by averaging across multiple observations.
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In the text

	Fig. 6 FIP bias values for the current sample plotted against spectral type, using only C, N, O, Ne, Fe as defined in Wood & Linsky (2010), only negative. Objects marked with an X were already included in Wood & Laming (2013). Solid lines bound all of the stars in Wood et al. (2012) except for one.
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In the text

	Fig. 7 Elemental abundances in solar units of the six coronae (black symbols) as a function of the first ionization potential (FIP) compared with the photospheric values (red). Line at 1 represents solar (Asplund et al. 2009). Note photospheric abundance ranges represent literature ranges and not actual uncertainties. A FIP effect is observed for ι Hor, HR 7291, α Cen A and B, which is not true for 11 LMi and τ Boo. Clearly, abundance trends relative to solar and relative to actual photospheric values are not always consistent.
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In the text