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Table 2

HFS and isotopic splitting data for the lines retained in this analysis.

Lower level Upper level


λ Iso. J A B HFS J A B HFS
(nm) (MHz) (MHz) Ref. (MHz) (MHz) Ref.

Cu i : 69.2% 63Cu (), 30.8% 65Cu ()
Isotopic separation for 510.6 nm from Ref. 1
510.5541 63Cu 5/2 749.781 188.270 1 3/2 194.595 28.480 2
510.5560 65Cu 5/2 804.043 172.980 1 3/2 208.464 26.356 2
521.8201 63Cu 3/2 194.595 28.480 2 5/2
521.8201 65Cu 3/2 208.464 26.356 2 5/2
522.0070 63Cu 3/2 194.595 28.480 2 3/2
522.0070 65Cu 3/2 208.464 26.356 2 3/2
Rb i : 72.2% 85Rb (), 27.8% 87Rb ()
780.0268 85Rb 1/2 1011.911 3 3/2 25.009 25.039 4
780.0268 87Rb 1/2 3417.341 5 3/2 84.718 12.497 6
794.7603 85Rb 1/2 1011.911 3 1/2 120.720 7
794.7603 87Rb 1/2 3417.341 5 1/2 406.200 7
Y ii : 100% 89Y ()
412.4909 89Y 2 15.500 8 3 64.400 8
439.8015 89Y 2 222.900 8 1 108.000 8
490.0124 89Y 3 2 22.800 8
508.7425 89Y 4 4 29.000 8
511.9119 89Y 2 149.940 9 3 64.400 8
520.0414 89Y 2 149.940 9 2 79.300 8
528.9821 89Y 3 2 79.300 8
547.3385 89Y 1 46.560 10 2 67.000 8
572.8876 89Y 2 26.400 10 2 67.000 8
Nb ii : 100% 93Nb ()
319.4974 93Nb 2 513.245 11 3 614.275 11
321.5593 93Nb 4 989.915 11 4 358.552 11
371.7060 93Nb 4 76.147 11 4 160.389 11
374.0725 93Nb 3 554.616 11 3 220.347 11
Rh i : 100% 103Rh ()
343.4889 103Rh 9/2 175.574 12 11/2
369.2361 103Rh 9/2 175.574 12 7/2
Ag i : 51.8% 107Ag (), 48.2% 109Ag ()
Isotopic separations calculated from the data of Crawford et al. (1949) and Jackson &
Kuhn (1937), but using component identifications of Brix et al. (1951) and Ref. 13
328.06810 107Ag 1/2 1712.560 13 3/2 31.700 14
328.06827 109Ag 1/2 1976.940 13 3/2 36.700 14
338.29000 107Ag 1/2 1712.560 13 1/2 175.400 14
338.29018 109Ag 1/2 1976.940 13 1/2 201.600 14
Ba ii : 0.1% 130Ba (I = 0), 0.1% 132Ba (I = 0), 2.4% 134Ba (I = 0),
6.6% 135Ba (), 7.9% 136Ba (I = 0), 11.2% 137Ba (), 71.7% 138Ba (I = 0)
Isotopic separations from Wendt et al. (1984; 455.4 nm), van Hove et al. (1982; 585.4 nm), and Ref. 17 (649.7 nm)
455.40334 130Ba 1/2 0.000 0.000 N 3/2 0.000 0.000 N
455.40335 135Ba 1/2 3591.670 15 3/2 113.000 59.000 16
455.40340 132Ba 1/2 0.000 0.000 N 3/2 0.000 0.000 N
455.40341 137Ba 1/2 4018.871 15 3/2 127.200 92.500 16
455.40344 134Ba 1/2 0.000 0.000 N 3/2 0.000 0.000 N
455.40347 136Ba 1/2 0.000 0.000 N 3/2 0.000 0.000 N
455.40360 138Ba 1/2 0.000 0.000 N 3/2 0.000 0.000 N
585.36879 137Ba 3/2 189.730 44.541 17 3/2 127.200 92.500 16
585.36880 138Ba 3/2 0.000 0.000 N 3/2 0.000 0.000 N
585.36889 136Ba 3/2 0.000 0.000 N 3/2 0.000 0.000 N
585.36891 135Ba 3/2 169.590 28.953 17 3/2 113.000 59.000 16
585.36902 134Ba 3/2 0.000 0.000 N 3/2 0.000 0.000 N
585.36914 132Ba 3/2 0.000 0.000 N 3/2 0.000 0.000 N
585.36927 130Ba 3/2 0.000 0.000 N 3/2 0.000 0.000 N
649.69078 137Ba 3/2 189.730 44.541 17 1/2 743.700 16
649.69080 138Ba 3/2 0.000 0.000 N 1/2 0.000 0.000 N
649.69090 136Ba 3/2 0.000 0.000 N 1/2 0.000 0.000 N
649.69091 135Ba 3/2 169.590 28.953 17 1/2 664.600 16
649.69105 134Ba 3/2 0.000 0.000 N 1/2 0.000 0.000 N

Reference. 1. Fischer et al. (1967); 2. Hannaford & McDonald (1978); 3. Nez et al. (1993); 4. Rapol et al. (2003); 5. Bize et al. (1999); 6. Ye et al. (1996); 7. Beacham & Andrew (1971); 8. Wännström et al. (1988); 9. Beck (1992); 10. Dinneen et al. (1991); 11. Nilsson & Ivarsson (2008); 12. Chan et al. (1968); 13. Wessel & Lew (1953); 14. Carlsson et al. (1990); 15. Trapp et al. (2000); 16. Villemoes et al. (1993); 17. van Hove et al. (1985); N) no HFS because J = 0 or I = 0.

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