Table 7
Column densities of the isocyanide species and N(-CN)/N(-NC) ratios.
Molecule | NTOTAL (cm-2) | [N(-NC)/N(-CN)] | Isomerization energy | ||
|
|||||
Orion-KL | Sgr B2 | TMC-1 | (cm-1) | ||
CH2CHCN | (4 ± 1) ×1015 | ||||
CH2CHNC | ≤(4 ± 2) ×1014 | ≤(1.0 ± 0.5) × 10-1 | 5 × 10-3a | 8658a | |
CH3CN | (3.2 ± 0.9) ×1016 | ||||
CH3NC | (6.0 ± 3.0) ×1013 | (2 ± 1) × 10-3 | 2 × 10-2a | ≥9 × 10-2c | 9486a |
(3–5) × 10-2b | |||||
CH3CH2CN | (7 ± 2) ×1016 | ||||
CH3CH2NC | ≤(2.0 ± 0.6) × 1014 | ≤(3 ± 2) × 10-3 | ≤3 × 10-1a | 8697a | |
HCCCN | (4 ± 1) ×1015 | ||||
HCCNC | ≤(3 ± 1) ×1013 | ≤(8 ± 4) × 10-3 | (2–5) × 10-2d | 6614d | |
8 × 10-3e | |||||
HNCCC | ≤(3 ± 1) ×1013 | ≤(8 ± 4) × 10-3 | (2–6) × 10-3f | 17 745d | |
1 × 10-3e | |||||
NH2CN | ≤(3 ± 1) × 1013 | ||||
NH2NC | ≤(5 ± 2) × 1013 | ... | ... | ... | 18 537g |
Notes. Derived column densities for the cyanide and isocyanide species (Col. 2). Columns 3–5 show the ratio between the cyanide and its isocyanide isomer in this work and that derived from other authors in Sgr B2 and TMC-1. Column 6 gives the energy difference for the isomerization between the isocyanide species and its corresponding cyanide.
Reference. (2005). . .
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