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Table 7

Column densities of the isocyanide species and N(-CN)/N(-NC) ratios.

Molecule NTOTAL (cm-2) [N(-NC)/N(-CN)] Isomerization energy

Orion-KL Sgr B2 TMC-1 (cm-1)
CH2CHCN (4 ± 1) ×1015
CH2CHNC (4 ± 2) ×1014 (1.0 ± 0.5) × 10-1 5 × 10-3a 8658a
CH3CN (3.2 ± 0.9) ×1016
CH3NC (6.0 ± 3.0) ×1013 (2 ± 1) × 10-3 2 × 10-2a 9 × 10-2c 9486a
(3–5) × 10-2b
CH3CH2CN (7 ± 2) ×1016
CH3CH2NC (2.0 ± 0.6) × 1014 (3 ± 2) × 10-3 3 × 10-1a 8697a
HCCCN (4 ± 1) ×1015
HCCNC (3 ± 1) ×1013 (8 ± 4) × 10-3 (2–5) × 10-2d 6614d
8 × 10-3e
HNCCC (3 ± 1) ×1013 (8 ± 4) × 10-3 (2–6) × 10-3f 17 745d
1 × 10-3e
NH2CN (3 ± 1) × 1013
NH2NC (5 ± 2) × 1013 ... ... ... 18 537g

Notes. Derived column densities for the cyanide and isocyanide species (Col. 2). Columns 3–5 show the ratio between the cyanide and its isocyanide isomer in this work and that derived from other authors in Sgr B2 and TMC-1. Column 6 gives the energy difference for the isomerization between the isocyanide species and its corresponding cyanide.

Reference. (2005). . .

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