Table A.3
Spectroscopic constants in the off-diagonal blocks of the Hamiltonian for the 2ν15 ⇔ ν14 ⇔ 3ν11 triad of vibrational states in vinyl cyanide.
| 2ν15 ⇔ ν14 | ν14 ⇔ 3ν11 | 2ν15 ⇔ 3ν11 | ||
|
|
||||
| Ga/MHz | 5852.21(58) | 223.63(15) | Gc/MHz | 25.8(27) |
 /MHz |
0.01958(32) | |||
 /MHz |
–2.790(18) | −0.1703(17) | Fab/MHz | 3.59(22) |
 /MHz |
–0.000000324(61) | |||
 /MHz |
–0.0000335(23) | W | 14179.2(17) | |
 /MHz |
0.001503(51) | |||
| W±/MHz | 0.8521(24) | |||
| Fbc/MHz | 0.4557(30) |  /MHz |
0.00000540(82) | |
 /MHz |
0.00847(15) | |||
| Gb/MHz | –9.50(21) | 18.180(61) |  /kHz |
–0.000000700(44) |
 /MHz |
–0.4173(94) |  /kHz |
0.00000523(16) | |
Notes.
Round parentheses enclose standard errors in units of the last quoted digit of the value of the constant, and only the constants with non-zero values are listed.
These constants complement those in the diagonal blocks listed in Table A.1.
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