Table A.2
Spectroscopic constants in the off-diagonal blocks of the Hamiltonian for the ν10 ⇔ ν11ν15 and ν11ν10 ⇔ 2ν11ν15 dyads of vibrational states in vinyl cyanide.
| ν10 ⇔ ν11ν15 | ν11ν10 ⇔ 2ν11ν15 | ν10 ⇔ ν11ν15 | ν11ν10 ⇔ 2ν11ν15 | ||
|
|
|||||
| Ga/MHz | 1623.(13) | 1557.(34) | Gb/MHz | 643.32(46) | 929.1(30) |
 /MHz |
0.2192(48) | 0.4834(45) |  /MHz |
0.01663(17) | 0.00766(38) |
 /MHz |
6.432(76) | 3.67(10) | |||
 /MHz |
0.0001240(23) | ||||
| Fbc/MHz | 4.151(90) | 9.447(88) | Fac/MHz | -27.14(29) | −14.20(69) |
 /MHz |
-0.0001184(26) | ||||
Notes.
Round parentheses enclose standard errors in units of the last quoted digit of the value of the constant, and only the constants with non-zero values are listed.
These constants complement those in the diagonal blocks listed in Table 2.
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