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Table 10
Isotopic variants of the ionic complex OCH+··· CO.
| Quantity | 16-12-H+13-16 | 18-12-H+13-18 | 16-12-H+12-18 | 16-13-H+13-18 | 16-12-H+13-18 | 18-12-H+13-16 |
| reaction F1 | reaction F2 | reaction F3 | reaction F4 | reaction F5 | reaction F6 | |
|
|
||||||
| ω1 (cm-1) | 2464 | 2426 | 2464 | 2409 | 2464 | 2426 |
| ω2 (cm-1) | 2187 | 2133 | 2185 | 2133 | 2133 | 2187 |
| ω3 (cm-1) | 1730 | 1712 | 1731 | 1728 | 1730 | 1712 |
| ω4,5 (cm-1) | 1145 | 1144 | 1147 | 1141 | 1149 | 1144 |
| ω6,7 (cm-1) | 267 | 264 | 271 | 261 | 266 | 265 |
| ω8 (cm-1) | 198 | 191 | 197 | 193 | 194 | 195 |
| ω9,10 (cm-1) | 129 | 126 | 131 | 126 | 127 | 128 |
| Be (MHz) | 1901 | 1728 | 1826 | 1799 | 1814 | 1812 |
| E0 (cm-1) | 4830 | 4765 | 4836 | 4760 | 4798 | 4796 |
 (cm-1) |
4594 | 4537 | 4592 | 4531 | 4568 | 4563 |
 (cm-1) |
4581 | 4524 | 4587 | 4526 | 4550 | 4555 |
| ΔEh/kB (K) | 18.3 | 18.3 | 6.6 | 6.6 | 24.7 | 11.7 |
 (cm-1) |
4640 | 4648 | 4632 | 4647 | 4645 | 4643 |
 (cm-1) |
4627 | 4635 | 4627 | 4642 | 4628 | 4635 |
Notes.Here, a-b-H+c-d stands for aObCH+··· cCdO. Vibrational modes (ω4,ω5), (ω6,ω7), and (ω9,ω10) are doubly degenerate.
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