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Table 3

Spectroscopic constants (MHz) of the mono- and bi-deuterated isotopologues of hydrogen sulfide.

HD33S HD34S DS DS


scaled scaled Exp.a scaled scaled Exp.a

A0 292 011.152 291 686.013 291 681.55(51) 164 077.862 163 554.600 163 555.62(66)
B0 147 608.625 147 409.260 147 448.29(30) 135 286.190 135 286.004 135 287.0(28)
C0 96 610.457 96 488.593 96 451.71(30) 73 162.176 73 057.235 73 057.77(36)
DJ 1.1593 1.1510 1.1300(22) 4.9895 4.9974 4.999(14)
DJK 37.3096 37.3126 37.4504(96) –18.0066 –18.0443 –18.018(95)
DK –18.5254 –18.6277 –18.8254(87) 29.9330 29.8564 29.839(36)
d1 –0.8417 –0.8371 –0.84249(102) –2.1589 –2.1593 –2.1636(69)
d2 –0.7202 –0.7190 –0.7294(126) 0.0940 0.0970 0.0949(102)
HJ × 103 –0.3255 –0.3239 1.1696 1.1679
HJK × 102 0.4440 0.4390 –1.0207 –1.0225
HKJ × 101 0.1536 0.1567 0.1664 0.1675
HK × 101 –0.1353 –0.1381 –0.0180 –0.0192
h1 × 103 –0.0521 –0.0520 0.3896 0.3878
h2 × 103 0.1701 0.1693 –0.1105 –0.1094
h3 × 103 0.0911 0.0910 0.1099 0.1117

Notes.

(a)

Camy-Peyret et al. (1985).

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