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Table 3
Spectroscopic constants (MHz) of the mono- and bi-deuterated isotopologues of hydrogen sulfide.
HD33S | HD34S | D![]() |
D![]() |
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scaled | scaled | Exp.a | scaled | scaled | Exp.a | |||||||||||
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A0 | 292 011.152 | 291 686.013 | 291 681.55(51) | 164 077.862 | 163 554.600 | 163 555.62(66) | ||||||||||
B0 | 147 608.625 | 147 409.260 | 147 448.29(30) | 135 286.190 | 135 286.004 | 135 287.0(28) | ||||||||||
C0 | 96 610.457 | 96 488.593 | 96 451.71(30) | 73 162.176 | 73 057.235 | 73 057.77(36) | ||||||||||
DJ | 1.1593 | 1.1510 | 1.1300(22) | 4.9895 | 4.9974 | 4.999(14) | ||||||||||
DJK | 37.3096 | 37.3126 | 37.4504(96) | –18.0066 | –18.0443 | –18.018(95) | ||||||||||
DK | –18.5254 | –18.6277 | –18.8254(87) | 29.9330 | 29.8564 | 29.839(36) | ||||||||||
d1 | –0.8417 | –0.8371 | –0.84249(102) | –2.1589 | –2.1593 | –2.1636(69) | ||||||||||
d2 | –0.7202 | –0.7190 | –0.7294(126) | 0.0940 | 0.0970 | 0.0949(102) | ||||||||||
HJ × 103 | –0.3255 | –0.3239 | 1.1696 | 1.1679 | ||||||||||||
HJK × 102 | 0.4440 | 0.4390 | –1.0207 | –1.0225 | ||||||||||||
HKJ × 101 | 0.1536 | 0.1567 | 0.1664 | 0.1675 | ||||||||||||
HK × 101 | –0.1353 | –0.1381 | –0.0180 | –0.0192 | ||||||||||||
h1 × 103 | –0.0521 | –0.0520 | 0.3896 | 0.3878 | ||||||||||||
h2 × 103 | 0.1701 | 0.1693 | –0.1105 | –0.1094 | ||||||||||||
h3 × 103 | 0.0911 | 0.0910 | 0.1099 | 0.1117 |
Notes.
(a)
Camy-Peyret et al. (1985).
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