Free Access
Table 2
Computed, scaled, and experimental spectroscopic constants (MHz) of H
S.
| Calc. | Scal. | Experiment | |||||||
|
|
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| this work | Azzam et al. (2013) | ||||||||
|
|
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| A0 | 309 074.383 | 308 541.281 | 308 539.7387(185) | 308 559.2(34) | |||||
| B0 | 269 794.977 | 270 366.305 | 270 366.3105(219) | 270 354.74(174) | |||||
| C0 | 141 447.383 | 141 388.422 | 141 387.9835(110) | 141 395.80(93) | |||||
| DJ | 19.7797 | 20.9504 | 20.94889(138) | 20.6197(151) | |||||
| DJK | –72.5016 | –76.7028 | –76.6729(31) | –73.937(98) | |||||
| DK | 108.9900 | 117.3101 | 117.2531(24) | 115.559(126) | |||||
| d1 | –8.1067 | –8.8693 | –8.86715(56) | –8.5716(195) | |||||
| d2 | 0.8841 | 0.6760 | 0.689911(131) | 0.7067(38) | |||||
| HJ × 103 | 7.4100 | 10.0957 | 10.261(45) | ||||||
| HJK × 102 | –7.0974 | –9.0165 | –8.9609(182) | ||||||
| HKJ | 0.1315 | 0.1574 | 0.15524(28) | 0.0576(33) | |||||
| HK × 102 | –3.4487 | –3.5868 | –3.4864(144) | ||||||
| h1 × 103 | 2.3305 | 2.8417 | 2.8403(192) | –3.639(194) | |||||
| h2 × 103 | –0.3271 | –0.8386 | –1.0262(54) | –1.185(29) | |||||
| h3 × 103 | 1.0401 | 1.2935 | 1.2844(27) | 1.1179(110) | |||||
| LJ × 106 | –5.22(36) | 104.0(29) | |||||||
| LKJJ × 103 | 0.0485(34) | –0.974(22) | |||||||
| LJK × 103 | –0.1664(78) | 1.173(42) | |||||||
| LKKJ × 103 | 0.2161(88) | –0.5454(194) | |||||||
| LK × 103 | –0.1338(37) | 0.05795(177) | |||||||
| l1 × 106 | –1.046(161) | ||||||||
| l3 × 106 | –1.516(44) | ||||||||
| l4 × 106 | 0.2176(170) | ||||||||
| PJ × 106 | [0.fix] | –0.3644(167) | |||||||
| PJJK × 106 | 0.0303(54) | 3.847(148) | |||||||
| PJK × 106 | –3.98(21) | ||||||||
| PKJ × 106 | 1.756(130) | ||||||||
| p1 × 106 | –0.1878(86) | ||||||||
| p4 × 109 | 4.07(30) | ||||||||
| SJK × 109 | –2.857(188) | ||||||||
a
|
0.97 | 1.02 | |||||||
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