Free Access
Table 1
Computed, scaled, and experimental spectroscopic constants (MHz) of H
S, H
S, and H
S.
| HS |
HS |
HS |
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|
|
|
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| Calc. | Exp.a | Calc. | Scal. | Exp.a | Calc. | Scal. | Exp.b | ||||||||||||
|
|
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| A0 | 311 120.208 | 310 583.57681(33) | 310 561.940 | 310 026.271 | 310 025.8404(11) | 310 038.031 | 309 503.266 | 309 502.3997(103) | |||||||||||
| B0 | 269 796.351 | 270 367.68173(51) | 269 795.978 | 270 367.308 | 270 367.3005(16) | 269 795.628 | 270 366.957 | 270 366.9368(98) | |||||||||||
| C0 | 141 879.166 | 141 820.025852(31) | 141 761.640 | 141 702.549 | 141 702.4195(10) | 141 651.143 | 141 592.098 | 141 591.8242(93) | |||||||||||
| DJ | 19.6957 | 20.861454(35) | 19.7183 | 20.8854 | 20.88408(10) | 19.7397 | 20.9081 | 20.90496(56) | |||||||||||
| DJK | –72.0562 | –76.231602(67) | –72.1755 | –76.3578 | –76.35264(35) | –72.2890 | –76.4779 | –76.48005(180) | |||||||||||
| D K | 109.3770 | 117.726650(67) | 109.2690 | 117.6104 | 117.59920(33) | 109.1690 | 117.5028 | 117.49020(147) | |||||||||||
| d1 | –8.1039 | –8.8662557(94) | –8.1047 | –8.8671 | –8.866638(68) | –8.1054 | –8.8679 | –8.866950(141) | |||||||||||
| d2 | 0.8393 | 0.6417890(32) | 0.8513 | 0.6510 | 0.654498(24) | 0.8627 | 0.6597 | 0.666993(74) | |||||||||||
| HJ × 103 | 7.5012 | 10.21992(80) | 7.4775 | 10.1876 | 10.2205(50) | 7.4545 | 10.1563 | 10.2278(111) | |||||||||||
| HJK × 102 | –7.1018 | –9.02210(32) | –7.1011 | –9.0213 | –9.0420(15) | –7.1001 | –9.0200 | –9.1210(55) | |||||||||||
| HKJ | 0.1299 | 0.1556075(83) | 0.1304 | 0.1561 | 0.156141(39) | 0.1308 | 0.1566 | 0.157519(49) | |||||||||||
| HK × 102 | –3.2328 | –3.36226(69) | –3.2915 | –3.4232 | –3.4203(34) | –3.3467 | –3.4807 | –3.5149(42) | |||||||||||
| h1 × 103 | 2.3691 | 2.888706(268) | 2.3588 | 2.8761 | 2.8845(25) | 2.3490 | 2.8642 | 2.8646(35) | |||||||||||
| h2 × 103 | –0.3727 | –0.955353(154) | –0.3608 | –0.9250 | –0.9624(14) | –0.3493 | –0.8955 | –0.98017(188) | |||||||||||
| h3 × 103 | 1.0016 | 1.245524(48) | 1.0119 | 1.2584 | 1.25768(52) | 1.0217 | 1.2706 | 1.26596(65) | |||||||||||
 c
|
1.02 | 0.92 | 0.95 | ||||||||||||||||
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