Table 3
Predicted rest frequencies, estimated accuracies, and lines strengths for the ground vibrational state of ketenimine.
| J ′ |
|
|
F ′ | J | K a | K c | F | Rest freq. | Error | Line strength | E u | A |
| (1) | (2) | (3) | (4) | (5) | (6) | (7) | (8) | (9) | (10) | (11) | (12) | (13) |
|
|
||||||||||||
| 6 | 1 | 6 | 5 | 5 | 1 | 5 | 5 | 114 213.390 | 2 | 3.052e-02 | 19.734 | 5.822e-06 |
| 6 | 1 | 6 | 5 | 5 | 1 | 5 | 6 | 114 213.923 | 1 | 2.134e-04 | 19.734 | 4.072e-08 |
| 6 | 1 | 6 | 7 | 5 | 1 | 5 | 6 | 114 214.025 | 0 | 1.268e+00 | 19.734 | 3.298e-04 |
| 6 | 1 | 6 | 6 | 5 | 1 | 5 | 5 | 114 214.032 | 0 | 1.068e+00 | 19.734 | 2.408e-04 |
| 6 | 1 | 6 | 5 | 5 | 1 | 5 | 4 | 114 214.044 | 0 | 8.990e-01 | 19.734 | 1.715e-04 |
| ... | ||||||||||||
Notes. Column content: (1–3) upper state rotational quantum numbers
; (4)
upper state total quantum number F′; (5–7) lower state rotational
quantum numbers JKa,Kc; (8) lower
state total quantum number F; (9) rest frequency (MHz) evaluated from the
spectroscopic constants of the 2nd column of Table 2; (10) estimated error (kHz) of the prediction at 1σ level; (11)
transition strength (Debye2); (12) upper state energy (cm-1); (13) Einstein’s
A
coefficient (s-1). The full table is available in electronic form at
the CDS.
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