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Table 2

Oscillator strengths and transition assignments of the neutral and cation transitions of coronene and pyrene considered here.

Coronene Pyrene

Neutral Cation Neutral Cation

Transition & peak 1E1u: 301 nma, 1B1u: 337 nma 2B1,2g: 463 nma 1B2u: 334 nmb 2Au: 446 nmc
Absolute f f = 1.166a f = 0.0278d f = 0.33b f = 0.104d
Feature range 275–350 nm 456–469 nm 285–349 nm 409–460 nm

Notes.

(d)

derived here as described in Sect. 3.

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