Free Access
Table A.1
Added reaction network for cyanomethyl radical and its related species.
Reaction | Reaction | Reaction pathways for different isotopomers of Cyanomethyl radical | Rate coefficient at |
number | type | T = 10 K AV = 10 | |
|
|||
R1 | IN |
![]() |
4.60 × 10-08 cm3 s-1 |
R2 | IN |
![]() |
5.58 × 10-08 cm3 s-1 |
R3 | IN | CHD2CN+ + CO (1.951,0.101a) → CD2CN + HCO+ | 1.04 × 10-09 cm3 s-1 |
R4 | IN | H+ + CHD2CN (4.315,3.932a) → CD2CN+ + H2 | 8.72 × 10-08 cm3 s-1 |
R5 | IN |
![]() |
2.08 × 10-08 cm3 s-1 |
R6 | IN | C2HD+ + ND (1.447,1.522a) → CD2CN+ + H | 1.07 × 10-08 cm3 s-1 |
R7 | IN |
![]() |
9.94 × 10-09 cm3 s-1 |
R8 | IN | C2D+ + NHD (1.782,1.768a) → CD2CN+ + H | 1.22 × 10-08 cm3 s-1 |
R9 | IN | C2D+ + NH2D (2.087,1.519a) → CD2CN+ + H2 | 1.05 × 10-08 cm3 s-1 |
R10 | IN | H+ + CH2DCN (4.315,3.932a) → CHDCN+ + H2 | 8.72 × 10-08 cm3 s-1 |
R11 | IN | H+ + CH2DCN (4.315,3.932a) → CH2D+ + HCN | 8.72 × 10-08 cm3 s-1 |
R12 | IN | H3 + + CH2DCN (4.315,3.932a) → CH2DCNH+ + H2 | 5.15 × 10-08 cm3 s-1 |
R13 | IN | He+ + CH2DCN (4.315,3.932a) → CN + CH2D+ + He | 6.24 × 10-08 cm3 s-1 |
R14 | IN | H3O+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + H2O | 2.38 × 10-08 cm3 s-1 |
R15 | IN |
![]() |
2.15 × 10-08 cm3 s-1 |
R16 | IN | HCNH+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + HCN | 2.10 × 10-08 cm3 s-1 |
R17 | IN | HCNH+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + HNC | 2.10 × 10-08 cm3 s-1 |
R18 | IN | HCO+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + CO | 2.08 × 10-08 cm3 s-1 |
R19 | IN |
![]() |
2.08 × 10-08 cm3 s-1 |
R20 | IN |
![]() |
2.08 × 10-08 cm3 s-1 |
R21 | IN |
![]() |
1.85 × 10-08 cm3 s-1 |
R22 | IN |
![]() |
1.83 × 10-08 cm3 s-1 |
R23 | IN | HC3NH+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + HC3N | 1.79 × 10-08 cm3 s-1 |
R24 | IN |
![]() |
4.61 × 10-08 cm3 s-1 |
R25 | IN | C2HD+ + NH2 (1.782,1.768a) → CH2DCN+ + H | 1.24 × 10-08 cm3 s-1 |
R26 | IN | CH2DCN+ + CO (1.951,0.101a) → CHDCN + HCO+ | 1.04 × 10-09 cm3 s-1 |
R27 | IN | CH2DCN+ + H2 (0.773,0a) → CH2DCNH+ + H | 1.48 × 10-09 cm3 s-1 |
R28 | IN |
![]() |
1.71 × 10-08 cm3 s-1 |
R29 | IN |
![]() |
1.69 × 10-08 cm3 s-1 |
R30 | IN |
![]() |
1.83 × 10-08 cm3 s-1 |
R31 | IN | HC3NH+ + CH2DCN (4.315,3.932a) → CH2DCNH+ + HC3N | 1.78 × 10-08 cm3 s-1 |
R32 | IN |
![]() |
8.72 × 10-08 cm3 s-1 |
R33 | IN | H3 + + CHD2CN (4.315,3.932a) → CHD2CNH+ + H2 | 5.14 × 10-08 cm3 s-1 |
R34 | IN |
![]() |
6.23 × 10-08 cm3 s-1 |
R35 | IN | H3O+ + CHD2CN (4.315,3.932a) → CHD2CNH+ + H2O | 2.37 × 10-08 cm3 s-1 |
R36 | IN |
![]() |
2.14 × 10-08 cm3 s-1 |
R37 | IN | HCNH+ + CHD2CN (4.315,3.932a) → CHD2CNH+ + HCN | 2.09 × 10-08 cm3 s-1 |
R38 | IN | HCNH+ + CHD2CN (4.315,3.932a) → CHD2CNH+ + HNC | 2.09 × 10-08 cm3 s-1 |
R39 | IN | HCO+ + CHD2CN (4.315,3.932a) → CHD2CNH+ + CO | 2.07 × 10-08 cm3 s-1 |
R40 | IN |
![]() |
2.07 × 10-08 cm3 s-1 |
R41 | IN |
![]() |
2.07 × 10-08 cm3 s-1 |
R42 | IN |
![]() |
1.83 × 10-08 cm3 s-1 |
R43 | IN | HCOOH2 + + CHD2CN (4.315,3.932a) → CHD2CNH+ + HCOOH | 1.81 × 10-08 cm3 s-1 |
R44 | IN | HC3NH+ + CHD2CN (4.315,3.932a) → CHD2CNH+ + HC3N | 1.78 × 10-08 cm3 s-1 |
R45 | IN |
![]() |
4.60 × 10-08 cm3 s-1 |
R46 | IN | C2HD+ + NHD (1.782,1.768a) → CHD2CN+ + H | 1.21 × 10-08 cm3 s-1 |
R47 | IN | CHD2CN+ + H2 (0.773,0a) → CHD2CNH+ + H | 1.48 × 10-09 cm3 s-1 |
R48 | IN |
![]() |
5.14 × 10-08 cm3 s-1 |
R49 | IN | CH3OHD+ + DCN (2.497,3.007a) → CHD2CNH+ + H2O | 1.68 × 10-08 cm3 s-1 |
R50 | IN | He+ + CHDCN (4.382,3.499a) → CN + CHD+ + He | 5.58 × 10-08 cm3 s-1 |
R51 | IN | CHD+ + HCN (2.497,3.007a) → CHDCN+ + H | 2.12 × 10-08 cm3 s-1 |
R52 | IN | C2HD+ + NH (1.447,1.522a) → CHDCN+ + H | 1.09 × 10-08 cm3 s-1 |
R53 | IN | CH2D+ + CN (2.884,1.390a) → CHDCN+ + H | 1.01 × 10-08 cm3 s-1 |
R54 | IN | C2D+ + NH2 (1.782,1.768a) → CHDCN+ + H | 1.25 × 10-08 cm3 s-1 |
R55 | IN | C2D + + NH3 (2.087,1.519a) → CHDCN+ + H2 | 1.06 × 10-08 cm3 s-1 |
|
|||
R56 | NN | C + CD2CN → DC3N + D | 1.00 × 10-10 cm3 s-1 |
R57 | NN | C + CHDCN → HC3N + D | 1.00 × 10-10 cm3 s-1 |
R58 | NN | N + C2H2D → CHDCN + H | 6.20 × 10-11 cm3 s-1 |
|
|||
R59 | CE | H+ + CD2CN → CD2CN+ + H | 6.30 × 10-09 cm3 s-1 |
R60 | CE | C+ + CD2CN → CD2CN+ + C | 2.00 × 10-09 cm3 s-1 |
|
|||
R61 | CE | H+ + CH2DCN → CH2DCN+ + H | 8.40 × 10-09 cm3 s-1 |
R62 | CE | O+ + CH2DCN → CH2DCN+ + O | 2.94 × 10-09 cm3 s-1 |
R63 | CE | H+ + CHD2CN → CHD2CN+ + H | 8.40 × 10-09 cm3 s-1 |
R64 | CE | O+ + CHD2CN → CHD2CN+ + O | 2.94 × 10-09 cm3 s-1 |
R65 | CE | H+ + CHDCN → CHDCN+ + H | 6.30 × 10-09 cm3 s-1 |
R66 | CE | C+ + CHDCN → CHDCN+ + C | 2.00 × 10-09 cm3 s-1 |
|
|||
R67 | DR | CHD2CN+ + e− → CD2CN + H | 8.22 × 10-07 cm3 s-1 |
R68 | DR | CHD2CNH+ + e− → CD2CN + H2 | 8.22 × 10-07 cm3 s-1 |
R69 | DR | CD2CN+ + e− → CN + CD2 | 8.22 × 10-07 cm3 s-1 |
R70 | DR | CD2CN+ + e− → DCN + CD | 8.22 × 10-07 cm3 s-1 |
R71 | DR | CH2DCNH+ + e− → CH2DCN + H | 8.22 × 10-07 cm3 s-1 |
R72 | DR | CH2DCN+ + e− → DCN + CH2 | 8.22 × 10-07 cm3 s-1 |
R73 | DR | CH2DCN+ + e− → CHDCN + H | 8.22 × 10-07 cm3 s-1 |
R74 | DR | CHD2CNH+ + e− → CHD2CN + H | 8.22 × 10-07 cm3 s-1 |
R75 | DR | CHD2CN+ + e− → DCN + CHD | 8.22 × 10-07 cm3 s-1 |
R76 | DR | CH2DCNH+ + e− → CHDCN + H2 | 8.22 × 10-07 cm3 s-1 |
R77 | DR | CHDCN+ + e− → CN + CHD | 8.22 × 10-07 cm3 s-1 |
R78 | DR | CHDCN+ + e− → DCN + CH | 8.22 × 10-07 cm3 s-1 |
|
|||
R79 | PH | CH2DCN + PHOTON → CH2DCN+ + e− | 2.13 × 10-23 s-1 |
R80 | PH | CH2DCN + PHOTON → CN + CH2D | 7.01 × 10-18 s-1 |
R81 | PH | CHD2CN + PHOTON → CHD2CN+ + e− | 2.13 × 10-23 s-1 |
R82 | PH | CHD2CN + PHOTON → CN + CHD2 | 7.01 × 10-18 s-1 |
|
|||
R83 | CRP | CH2DCN + CRPHOT → CH2DCN+ + e− | 3.65 × 10-14 s-1 |
R84 | CRP | CH2DCN + CRPHOT → CN + CH2D | 7.76 × 10-14 s-1 |
R85 | CRP | CHD2CN + CRPHOT → CHD2CN+ + e− | 3.65 × 14-17 s-1 |
R86 | CRP | CHD2CN + CRPHOT → CN + CHD2 | 7.76 × 10-14 s-1 |
|
|||
R87 | RA | CH2D + CN → CH2DCN + PHOTON | 1.00 × 10-16 cm3 s-1 |
R88 | RA | CH2D+ + HCN → CH2DCNH + + PHOTON | 4.93 × 10-08 cm3 s-1 |
R89 | RA | CHD2 + CN → CHD2CN + PHOTON | 1.00 × 10-16 cm3 s-1 |
R90 | RA |
![]() |
4.93 × 10-08 cm3 s-1 |
|
|||
R91 | AD | CH2D + CN− → CH2DCN + e− | 1.00 × 10-09 cm3 s-1 |
R92 | AD | CHD2 + CN− → CHD2CN + e− | 1.00 × 10-09 cm3 s-1 |
|
|||
R93 | REA | CH2CN + e− → CH2CN− + PHOTON | 6.85 × 10-7 cm3 s-1 |
R94 | REA | CD2CN + e− → CD2CN− + PHOTON | 6.85 × 10-7 cm3 s-1 |
R95 | REA | CHDCN + e− → CHDCN− + PHOTON | 6.85 × 10-7 cm3 s-1 |
|
|||
R96 | MN |
![]() |
4.11 × 10-7 cm3 s-1 |
R97 | MN | CH2CN− + C+ → CH2CN + C | 4.11 × 10-7 cm3 s-1 |
R98 | MN | CH2CN− + H3O + → CH2CN + H + H2O | 4.11 × 10-7 cm3 s-1 |
R99 | MN | CH2CN− + HCO+ → CH2CN + H + CO | 4.11 × 10-7 cm3 s-1 |
R100 | MN |
![]() |
4.11 × 10-7 cm3 s-1 |
R101 | MN | CH2CN− + O+ → CH2CN + O | 4.11 × 10-7 cm3 s-1 |
R102 | MN | CH2CN− + H+ → CH2CN + H | 4.11 × 10-7 cm3 s-1 |
R103 | MN | CHDCN− + H3 + → CHDCN + H2 + H | 4.11 × 10-7 cm3 s-1 |
R104 | MN | CHDCN− + C + → CHDCN + C | 4.11 × 10-7 cm3 s-1 |
R105 | MN | CHDCN− + H3O+ → CHDCN + H + H2O | 4.11 × 10-7 cm3 s-1 |
R106 | MN | CHDCN− + HCO+ → CHDCN + H + CO | 4.11 × 10-7 cm3 s-1 |
R107 | MN |
![]() |
4.11 × 10-7 cm3 s-1 |
R108 | MN | CHDCN− + O+ → CHDCN + O | 4.11 × 10-7 cm3 s-1 |
R109 | MN | CHDCN− + H+ → CHDCN + H | 4.11 × 10-7 cm3 s-1 |
R110 | MN |
![]() |
4.11 × 10-7 cm3 s-1 |
R111 | MN | CD2CN− + C+ → CD2CN + C | 4.11 × 10-7 cm3 s-1 |
R112 | MN | CD2CN− + H3O+ → CD2CN + H + H2O | 4.11 × 10-7 cm3 s-1 |
R113 | MN | CD2CN− + HCO+ → CD2CN + H + CO | 4.11 × 10-7 cm3 s-1 |
R114 | MN |
![]() |
4.11 × 10-7 cm3 s-1 |
R115 | MN | CD2CN− + O+ → CD2CN + O | 4.11 × 10-7 cm3 s-1 |
R116 | MN | CD2CN− + H+ → CD2CN + H | 4.11 × 10-7 cm3 s-1 |
Notes.
(a)
Polarizability of neutral reactants in units of Å3 and dipole moment in Debye (Woon & Herbst 2009).
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.