Induced rotational excitation of the fluoromethylidynium 12CF+ and 13CF+ through collision with helium

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Table 5

Comparison between ¹²CF⁺-He and ¹³CF⁺-He cross sections.

	E = 100 cm^-1			E = 500 cm^-1

J − J′	¹²CF⁺^a	¹³CF⁺^b	¹³CF⁺^c	¹²CF⁺^a	¹³CF⁺^b	¹³CF⁺^c

1–0	13.497	13.950	12.584	7.342	7.370	6.317
2–0	19.584	18.900	18.528	7.819	7.784	7.581
0–1	4.659	4.807	4.337	2.464	2.472	2.119
2–1	12.754	12.485	11.500	5.926	5.950	5.204
3–1	21.101	20.504	20.297	7.502	7.452	7.209
5–0	7.706	7.510	7.339	2.032	2.028	2.009
7–0	1.916	3.380	3.349	1.431	1.408	1.408
0–5	1.447	1.343	1.313	0.206	0.204	0.202
1–5	8.722	8.630	8.643	1.688	1.677	1.660
4–5	17.359	15.706	15.227	4.620	4.618	4.12
0–7	3.474	2.747	2.721	0.118	0.115	0.114
1–7	16.285	11.914	12.529	0.894	0.886	0.938
5–7	87.532	53.921	52.993	4.887	4.830	4.824
6–7	45.576	36.979	36.588	5.024	5.030	4.472

Notes.The cross sections are in Å².

^(a)

Cross sections of ¹²CF⁺-He system calculated with ¹²CF⁺-He PES and ¹²CF⁺ rotational structure.

^(b)

Cross sections of ¹³CF⁺-He system calculated with ¹²CF⁺-He PES and ¹³CF⁺ rotational structure.

^(c)

Cross sections of ¹³CF⁺-He system calculated with ¹³CF⁺-He PES and ¹³CF⁺ rotational structure.

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